#------------------------------------------------------------------------------ #$Date: 2016-04-03 06:42:55 +0300 (Sun, 03 Apr 2016) $ #$Revision: 181280 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/23/58/2235842.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2235842_Fobs loop_ _publ_author_name 'Kammer, Michael N.' 'Mague, Joel T.' 'Koplitz, Lynn V.' _publ_section_title ; 4-Cyano-1-methylpyridinium bromide ; _journal_coeditor_code HB6887 _journal_issue 8 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first o2409 _journal_volume 68 _journal_year 2012 _space_group_IT_number 14 _symmetry_space_group_name_Hall '-P 2ybc' _symmetry_space_group_name_H-M 'P 1 21/c 1' _cell_angle_alpha 90.000 _cell_angle_beta 96.455 _cell_angle_gamma 90.000 _cell_length_a 4.5447 _cell_length_b 11.2849 _cell_length_c 15.5508 _exptl_crystal_F_000 392.00 _reflns_d_resolution_high 0.7298 _cod_data_source_file hb6887Isup2.hkl _cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' LK108_0m in P2(1)/c' _shelx_refln_list_code 4 _shelx_f_calc_maximum 207.88 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y-1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 1 0 0 208.59 256.93 10.08 o 2 0 0 3.77 -0.07 1.01 o 3 0 0 2271.17 2143.50 78.04 o 4 0 0 2297.89 2250.73 108.85 o 5 0 0 1978.35 1849.01 92.14 o 6 0 0 117.74 154.69 22.98 o 1 1 0 19.55 22.58 1.02 o 2 1 0 3950.75 3968.60 100.65 o 3 1 0 4922.75 4953.80 118.05 o 4 1 0 42.67 40.28 3.31 o 5 1 0 64.87 68.61 5.98 o 6 1 0 428.99 442.11 21.99 o 0 2 0 1814.89 1607.81 116.45 o 1 2 0 1394.03 1561.56 44.44 o 2 2 0 1.45 -0.62 0.76 o 3 2 0 83.57 90.12 2.93 o 4 2 0 95.10 96.17 4.86 o 5 2 0 92.66 92.79 7.58 o 6 2 0 32.12 37.18 8.66 o 1 3 0 5857.54 6150.74 162.84 o 2 3 0 550.46 517.44 12.64 o 3 3 0 3482.49 3443.63 96.18 o 4 3 0 602.16 608.74 21.89 o 5 3 0 277.18 282.20 14.71 o 6 3 0 393.97 381.07 40.47 o 0 4 0 19120.83 17509.96 670.77 o 1 4 0 4236.84 4362.46 121.81 o 2 4 0 680.20 757.21 18.81 o 3 4 0 2368.74 2444.83 77.68 o 4 4 0 2111.24 2029.66 69.33 o 5 4 0 1152.98 1164.79 44.60 o 1 5 0 2526.68 2450.20 65.68 o 2 5 0 1962.96 1983.09 50.89 o 3 5 0 2463.36 2492.65 70.74 o 4 5 0 143.05 144.21 7.64 o 5 5 0 194.53 199.53 10.13 o 0 6 0 70.92 68.35 5.62 o 1 6 0 187.71 211.29 6.08 o 2 6 0 183.19 191.65 5.63 o 3 6 0 194.93 184.83 7.97 o 4 6 0 546.42 542.01 19.50 o 5 6 0 8.93 9.62 4.46 o 1 7 0 2103.17 2061.27 66.85 o 2 7 0 2946.34 2869.81 74.49 o 3 7 0 1672.59 1695.41 46.34 o 4 7 0 27.50 30.05 3.93 o 5 7 0 49.95 51.28 5.67 o 0 8 0 4652.61 4353.35 185.60 o 1 8 0 2848.08 2813.20 83.82 o 2 8 0 161.51 173.60 5.76 o 3 8 0 270.73 263.33 8.91 o 4 8 0 2174.93 2115.61 79.74 o 5 8 0 894.28 893.51 46.64 o 1 9 0 612.75 597.83 18.27 o 2 9 0 1638.33 1501.30 40.94 o 3 9 0 778.15 799.80 22.17 o 4 9 0 26.40 31.49 4.10 o 0 10 0 20.27 22.88 3.32 o 1 10 0 32.45 29.95 2.59 o 2 10 0 0.00 -1.17 2.06 o 3 10 0 0.43 0.98 2.54 o 4 10 0 35.28 35.01 4.30 o 1 11 0 842.25 791.12 24.32 o 2 11 0 1712.43 1650.90 46.81 o 3 11 0 989.06 999.95 28.01 o 4 11 0 40.12 42.61 7.13 o 0 12 0 2539.80 2311.23 105.80 o 1 12 0 1495.99 1454.06 43.68 o 2 12 0 25.13 25.11 2.97 o 3 12 0 398.13 407.39 13.75 o 1 13 0 138.36 132.16 5.82 o 2 13 0 334.10 330.56 10.95 o 3 13 0 416.01 416.41 19.38 o 0 14 0 38.26 33.82 4.85 o 1 14 0 37.97 37.95 4.08 o 2 14 0 3.06 2.34 2.88 o 1 15 0 103.15 110.66 11.75 o -6 1 1 601.03 623.95 50.13 o -5 1 1 984.88 1021.32 41.16 o -4 1 1 190.41 187.10 9.25 o -3 1 1 357.25 331.73 7.91 o -2 1 1 13308.66 12517.39 493.51 o -1 1 1 1373.12 1517.44 37.16 o 0 1 1 1191.12 1350.69 70.30 o 1 1 1 256.27 285.50 7.62 o 2 1 1 1396.76 1310.63 30.45 o 3 1 1 2065.07 2005.87 46.39 o 4 1 1 1379.45 1392.72 58.90 o 5 1 1 142.99 143.33 8.00 o 6 1 1 104.90 102.73 8.85 o -6 2 1 4.17 2.99 5.95 o -5 2 1 954.74 968.75 38.77 o -4 2 1 2437.85 2381.32 104.26 o -3 2 1 3387.93 3186.85 79.84 o -2 2 1 3282.13 3337.36 87.04 o -1 2 1 222.11 218.46 5.53 o 0 2 1 2279.67 2607.10 68.58 o 1 2 1 43215.00 30658.42 750.99 o 2 2 1 2543.11 2486.99 60.05 o 3 2 1 82.74 83.50 3.03 o 4 2 1 1383.66 1458.31 43.01 o 5 2 1 1417.10 1519.41 66.21 o 6 2 1 894.98 877.69 58.48 o -6 3 1 291.99 356.70 24.45 o -5 3 1 879.51 884.75 34.57 o -4 3 1 45.89 47.97 5.15 o -3 3 1 41.20 33.22 1.91 o -2 3 1 9346.96 9251.79 222.91 o -1 3 1 770.68 806.86 20.97 o 0 3 1 2744.36 2961.13 79.07 o 1 3 1 96.75 92.59 2.40 o 2 3 1 185.16 167.26 4.35 o 3 3 1 3925.87 3677.97 111.22 o 4 3 1 1431.70 1518.44 47.21 o 5 3 1 55.11 58.92 6.39 o -5 4 1 30.89 38.05 5.05 o -4 4 1 80.33 101.47 8.18 o -3 4 1 211.48 236.84 7.23 o -2 4 1 37.87 36.23 1.61 o -1 4 1 0.20 -0.77 0.77 o 0 4 1 410.04 423.85 10.44 o 1 4 1 41.70 50.76 1.95 o 2 4 1 1317.13 1493.44 34.14 o 3 4 1 9.55 9.74 1.76 o 4 4 1 13.20 15.59 3.20 o 5 4 1 126.57 109.67 8.41 o -5 5 1 431.15 431.09 17.87 o -4 5 1 309.88 288.21 12.13 o -3 5 1 521.97 505.72 15.03 o -2 5 1 3310.00 3200.06 84.38 o -1 5 1 5255.75 5167.02 130.54 o 0 5 1 1838.93 1913.57 48.94 o 1 5 1 48.58 58.97 2.27 o 2 5 1 4061.20 3945.47 106.19 o 3 5 1 665.26 644.44 18.22 o 4 5 1 1514.54 1498.49 51.23 o 5 5 1 81.42 84.25 6.25 o -5 6 1 838.90 881.32 36.00 o -4 6 1 2070.20 1902.08 75.30 o -3 6 1 4305.07 4059.28 120.50 o -2 6 1 973.17 1027.81 26.99 o -1 6 1 1404.45 1494.26 36.09 o 0 6 1 3903.50 3703.78 105.11 o 1 6 1 8104.84 8168.67 201.45 o 2 6 1 2622.93 2767.58 71.17 o 3 6 1 120.64 138.55 4.97 o 4 6 1 1210.63 1157.88 43.71 o 5 6 1 881.80 992.32 38.39 o -5 7 1 428.17 467.11 21.58 o -4 7 1 71.14 73.32 5.16 o -3 7 1 295.15 304.99 9.38 o -2 7 1 1194.68 1286.33 33.71 o -1 7 1 2225.62 2234.79 67.11 o 0 7 1 1999.79 2187.77 59.06 o 1 7 1 67.21 80.31 3.55 o 2 7 1 700.60 722.33 19.98 o 3 7 1 1090.05 1110.98 30.38 o 4 7 1 1338.35 1141.79 43.81 o 5 7 1 20.12 23.08 5.07 o -5 8 1 6.43 7.76 8.42 o -4 8 1 5.73 8.84 3.83 o -3 8 1 213.31 208.08 7.38 o -2 8 1 26.77 24.96 2.17 o -1 8 1 16.82 22.24 1.93 o 0 8 1 132.50 133.35 4.81 o 1 8 1 22.66 23.42 1.97 o 2 8 1 56.34 57.43 2.97 o 3 8 1 64.11 69.16 3.80 o 4 8 1 57.27 51.09 4.50 o 5 8 1 146.10 146.69 13.99 o -4 9 1 143.45 145.24 8.10 o -3 9 1 80.99 86.02 4.01 o -2 9 1 1658.50 1622.21 44.01 o -1 9 1 2928.22 2858.97 84.58 o 0 9 1 1061.82 1070.94 40.78 o 1 9 1 4.66 6.11 1.84 o 2 9 1 1210.88 1226.31 39.63 o 3 9 1 1672.23 1597.54 43.71 o 4 9 1 865.83 887.94 31.32 o -4 10 1 1611.38 1440.51 54.82 o -3 10 1 1942.29 1844.94 50.45 o -2 10 1 165.10 168.83 5.91 o -1 10 1 89.21 98.59 4.38 o 0 10 1 2542.61 2301.60 78.25 o 1 10 1 3626.92 3622.59 106.98 o 2 10 1 1230.96 1215.86 33.43 o 3 10 1 75.02 78.00 4.32 o 4 10 1 503.71 516.92 21.60 o -4 11 1 50.95 46.71 10.84 o -3 11 1 131.63 135.24 5.60 o -2 11 1 713.28 692.08 20.43 o -1 11 1 1417.98 1315.77 42.77 o 0 11 1 252.59 244.52 8.50 o 1 11 1 64.44 69.99 3.89 o 2 11 1 315.49 305.54 9.95 o 3 11 1 317.47 302.58 10.20 o 4 11 1 426.90 500.70 29.49 o -3 12 1 86.00 93.51 4.89 o -2 12 1 14.96 16.76 2.93 o -1 12 1 1.23 0.34 2.31 o 0 12 1 245.92 237.99 8.46 o 1 12 1 19.24 19.06 2.73 o 2 12 1 2.15 2.16 2.61 o 3 12 1 40.92 39.19 3.76 o -3 13 1 132.97 132.22 14.42 o -2 13 1 1050.93 1054.05 30.38 o -1 13 1 918.74 889.54 27.28 o 0 13 1 468.21 462.93 15.73 o 1 13 1 24.95 27.21 2.96 o 2 13 1 183.44 189.04 7.30 o 3 13 1 1023.54 1104.34 43.26 o -2 14 1 143.36 140.50 6.43 o -1 14 1 18.66 16.31 2.93 o 0 14 1 1214.71 1187.75 36.10 o 1 14 1 1779.27 1746.01 56.11 o 2 14 1 617.02 559.84 26.07 o -1 15 1 214.67 217.67 15.09 o 0 15 1 55.60 49.70 7.75 o 1 15 1 15.30 15.09 11.32 o -6 0 2 549.44 560.31 83.35 o -5 0 2 18.91 15.67 7.75 o -4 0 2 3936.68 4003.27 189.76 o -3 0 2 3054.44 2935.37 118.94 o -2 0 2 4748.29 4464.42 148.83 o -1 0 2 4616.99 4346.87 185.22 o 0 0 2 797.22 688.97 39.11 o 1 0 2 8448.51 8068.84 390.11 o 2 0 2 9995.36 9783.29 392.20 o 3 0 2 2722.67 2470.18 170.44 o 4 0 2 57.12 54.44 5.72 o 5 0 2 797.60 837.46 63.45 o 6 0 2 763.98 874.98 69.63 o -6 1 2 423.69 512.51 37.99 o -5 1 2 651.22 689.25 49.68 o -4 1 2 1646.27 1648.31 47.29 o -3 1 2 274.47 309.26 8.90 o -2 1 2 730.27 756.48 17.09 o -1 1 2 19384.81 17504.21 464.73 o 0 1 2 375.45 463.99 17.89 o 1 1 2 3720.88 3570.50 105.78 o 2 1 2 160.72 154.90 4.02 o 3 1 2 1215.32 1177.32 35.12 o 4 1 2 1844.28 1742.37 68.40 o 5 1 2 525.69 554.18 39.36 o 6 1 2 40.55 43.12 9.11 o -6 2 2 6.23 15.78 9.94 o -5 2 2 18.62 19.13 4.32 o -4 2 2 5.63 3.88 2.63 o -3 2 2 83.75 89.85 4.00 o -2 2 2 10.57 10.66 0.94 o -1 2 2 499.10 565.04 13.14 o 0 2 2 136.09 141.34 4.22 o 1 2 2 2477.60 2732.06 65.98 o 2 2 2 163.76 168.38 4.62 o 3 2 2 75.16 88.37 3.55 o 4 2 2 0.08 -1.53 2.56 o 5 2 2 1.21 4.33 4.09 o -6 3 2 61.43 61.84 8.11 o -5 3 2 1372.39 1424.81 53.85 o -4 3 2 1278.00 1349.74 42.28 o -3 3 2 166.46 160.07 4.95 o -2 3 2 51.66 42.01 1.66 o -1 3 2 12535.24 13431.20 343.42 o 0 3 2 12224.46 12353.73 299.98 o 1 3 2 297.96 287.85 6.82 o 2 3 2 497.76 518.28 12.91 o 3 3 2 1377.21 1306.55 33.62 o 4 3 2 1465.08 1398.42 44.30 o 5 3 2 499.20 566.76 26.36 o -6 4 2 571.19 588.92 48.71 o -5 4 2 7.70 5.54 4.05 o -4 4 2 1431.93 1475.51 48.94 o -3 4 2 4519.54 4511.46 118.99 o -2 4 2 6201.58 6021.20 147.96 o -1 4 2 972.18 999.55 24.01 o 0 4 2 634.04 697.76 16.49 o 1 4 2 3825.37 3696.69 94.03 o 2 4 2 12766.25 12487.71 304.26 o 3 4 2 1459.46 1421.51 36.81 o 4 4 2 14.52 16.35 3.19 o 5 4 2 767.57 757.01 44.56 o -5 5 2 728.54 705.36 30.95 o -4 5 2 877.58 908.00 37.84 o -3 5 2 15.18 17.56 2.17 o -2 5 2 180.11 157.29 4.50 o -1 5 2 4857.16 4770.09 114.88 o 0 5 2 1288.66 1274.96 28.66 o 1 5 2 1346.34 1403.46 38.80 o 2 5 2 86.32 97.93 3.46 o 3 5 2 116.06 114.47 3.98 o 4 5 2 1666.54 1674.91 57.97 o 5 5 2 719.23 650.23 31.29 o -5 6 2 30.49 43.37 5.79 o -4 6 2 161.68 157.68 6.58 o -3 6 2 0.53 3.44 2.17 o -2 6 2 0.76 1.94 1.33 o -1 6 2 31.88 35.47 1.56 o 0 6 2 223.62 264.49 6.88 o 1 6 2 110.68 124.46 5.62 o 2 6 2 56.35 65.90 2.70 o 3 6 2 443.01 463.84 13.31 o 4 6 2 6.29 4.89 3.21 o 5 6 2 25.15 27.63 5.41 o -5 7 2 879.22 871.71 38.05 o -4 7 2 432.67 470.40 14.83 o -3 7 2 328.88 319.82 9.83 o -2 7 2 667.96 687.29 18.17 o -1 7 2 2750.23 2676.21 72.67 o 0 7 2 4014.99 3939.58 111.90 o 1 7 2 1235.94 1262.50 33.62 o 2 7 2 157.73 158.09 5.23 o 3 7 2 1377.28 1357.39 44.13 o 4 7 2 553.66 559.30 22.45 o 5 7 2 684.40 680.96 27.99 o -5 8 2 2.15 3.01 5.14 o -4 8 2 998.69 1012.00 30.13 o -3 8 2 3154.50 2992.11 83.76 o -2 8 2 3644.03 3539.52 91.69 o -1 8 2 882.79 892.59 27.22 o 0 8 2 1034.07 1084.81 40.08 o 1 8 2 2562.44 2459.71 69.85 o 2 8 2 5281.38 5026.53 135.58 o 3 8 2 1244.68 1221.13 38.68 o 4 8 2 41.17 37.45 5.35 o 5 8 2 1093.30 1169.82 68.61 o -4 9 2 320.92 339.64 12.04 o -3 9 2 184.01 170.35 5.98 o -2 9 2 537.45 491.41 13.55 o -1 9 2 1256.36 1256.34 37.36 o 0 9 2 1360.59 1398.96 41.78 o 1 9 2 1252.99 1256.48 36.21 o 2 9 2 519.48 522.28 14.99 o 3 9 2 264.34 294.32 11.72 o 4 9 2 152.98 159.93 7.84 o -4 10 2 5.52 2.88 3.90 o -3 10 2 14.78 15.76 2.71 o -2 10 2 268.88 264.76 9.60 o -1 10 2 3.14 0.42 1.91 o 0 10 2 73.14 75.57 3.68 o 1 10 2 662.98 650.63 20.12 o 2 10 2 15.70 17.31 2.46 o 3 10 2 0.42 -0.05 2.78 o 4 10 2 87.81 86.98 5.96 o -4 11 2 154.84 165.93 10.86 o -3 11 2 136.89 134.45 5.86 o -2 11 2 269.42 272.33 9.45 o -1 11 2 1837.09 1783.39 53.00 o 0 11 2 1516.57 1385.32 44.52 o 1 11 2 246.21 246.85 8.57 o 2 11 2 1.20 0.27 2.37 o 3 11 2 375.16 360.23 12.39 o 4 11 2 896.71 898.97 40.05 o -3 12 2 1683.44 1634.54 56.72 o -2 12 2 1484.16 1348.25 40.70 o -1 12 2 7.71 8.97 2.45 o 0 12 2 38.18 39.37 3.13 o 1 12 2 1890.14 1797.69 53.38 o 2 12 2 2482.06 2462.92 69.62 o 3 12 2 364.87 361.03 13.09 o -3 13 2 117.89 114.34 11.77 o -2 13 2 21.84 23.29 3.47 o -1 13 2 1187.20 1207.77 40.15 o 0 13 2 807.42 810.84 27.39 o 1 13 2 71.66 65.44 4.90 o 2 13 2 48.90 59.46 5.17 o 3 13 2 131.06 118.56 10.03 o -2 14 2 211.46 203.84 10.58 o -1 14 2 45.46 49.30 5.10 o 0 14 2 30.99 35.50 4.26 o 1 14 2 198.96 194.79 8.88 o 2 14 2 2.02 2.99 5.65 o -1 15 2 479.36 528.21 52.48 o 0 15 2 554.84 668.16 64.14 o -6 1 3 66.39 78.20 19.21 o -5 1 3 523.16 508.54 25.28 o -4 1 3 1388.91 1433.84 46.12 o -3 1 3 1739.73 1773.57 45.57 o -2 1 3 388.04 410.14 11.70 o -1 1 3 272.41 279.56 7.47 o 0 1 3 10018.52 10330.14 532.59 o 1 1 3 7645.58 7624.12 217.10 o 2 1 3 1582.92 1490.77 36.12 o 3 1 3 238.40 224.90 7.02 o 4 1 3 1024.74 1048.78 34.64 o 5 1 3 1159.07 1244.67 49.01 o -6 2 3 1056.49 1186.83 73.76 o -5 2 3 863.36 764.09 34.40 o -4 2 3 14.95 17.69 2.43 o -3 2 3 5067.17 4714.50 119.97 o -2 2 3 8604.90 8206.82 202.45 o -1 2 3 6889.06 7269.65 192.36 o 0 2 3 1120.84 1159.25 33.47 o 1 2 3 1336.95 1373.91 39.24 o 2 2 3 6283.42 6341.31 172.41 o 3 2 3 4530.48 4655.37 151.47 o 4 2 3 958.66 896.38 31.58 o 5 2 3 44.23 48.46 5.16 o -6 3 3 4.99 0.03 7.75 o -5 3 3 743.15 805.35 34.50 o -4 3 3 1709.41 1771.21 54.16 o -3 3 3 1424.00 1442.86 39.56 o -2 3 3 43.11 49.30 1.76 o -1 3 3 2181.46 2287.48 53.24 o 0 3 3 7353.13 7830.25 207.75 o 1 3 3 1120.63 1083.65 24.71 o 2 3 3 1203.82 1209.07 27.38 o 3 3 3 46.18 46.97 2.65 o 4 3 3 678.15 675.61 23.82 o 5 3 3 792.18 860.33 55.57 o -6 4 3 13.87 16.81 14.06 o -5 4 3 57.60 56.90 5.81 o -4 4 3 2.76 -0.18 2.60 o -3 4 3 61.58 57.96 2.64 o -2 4 3 431.79 489.09 14.14 o -1 4 3 134.37 152.97 3.77 o 0 4 3 286.95 329.41 8.32 o 1 4 3 168.09 177.61 4.26 o 2 4 3 291.99 332.10 9.34 o 3 4 3 0.28 2.28 1.96 o 4 4 3 111.39 110.52 5.88 o 5 4 3 22.48 18.20 5.34 o -5 5 3 348.19 375.16 17.62 o -4 5 3 1343.80 1346.00 41.62 o -3 5 3 1776.31 1812.01 51.41 o -2 5 3 27.33 32.46 1.56 o -1 5 3 120.85 101.61 2.65 o 0 5 3 6704.70 6847.77 169.62 o 1 5 3 6141.17 6539.44 148.81 o 2 5 3 666.62 688.21 17.74 o 3 5 3 747.81 733.20 25.43 o 4 5 3 306.21 314.69 12.73 o 5 5 3 842.16 862.49 58.33 o -5 6 3 971.47 930.90 59.16 o -4 6 3 54.59 53.31 3.78 o -3 6 3 1747.22 1755.94 49.96 o -2 6 3 5437.25 5315.20 133.87 o -1 6 3 5821.03 5558.59 131.91 o 0 6 3 390.25 388.02 10.38 o 1 6 3 383.21 360.95 9.03 o 2 6 3 2549.03 2389.37 62.84 o 3 6 3 5968.71 5933.85 201.49 o 4 6 3 953.58 926.34 33.98 o 5 6 3 4.21 3.37 5.02 o -5 7 3 474.70 510.19 23.19 o -4 7 3 905.96 952.14 31.65 o -3 7 3 978.97 952.22 26.34 o -2 7 3 10.65 11.38 1.76 o -1 7 3 399.78 369.02 9.84 o 0 7 3 3997.93 4157.05 113.36 o 1 7 3 886.16 891.69 22.67 o 2 7 3 902.92 870.84 23.90 o 3 7 3 620.60 634.96 22.54 o 4 7 3 43.88 50.43 4.36 o 5 7 3 350.52 337.86 17.38 o -5 8 3 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