#------------------------------------------------------------------------------ #$Date: 2016-04-03 06:46:20 +0300 (Sun, 03 Apr 2016) $ #$Revision: 181288 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/23/66/2236670.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2236670_Fobs loop_ _publ_author_name 'Elder, Philip J. W.' 'Vargas-Baca, Ignacio' _publ_section_title ; 2,2'-Diiodoazobenzene ; _journal_coeditor_code TK5154 _journal_issue 11 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first o3127 _journal_volume 68 _journal_year 2012 _space_group_IT_number 14 _symmetry_space_group_name_Hall '-P 2ybc' _symmetry_space_group_name_H-M 'P 1 21/c 1' _cell_angle_alpha 90.000 _cell_angle_beta 98.532 _cell_angle_gamma 90.000 _cell_length_a 4.6306 _cell_length_b 18.1105 _cell_length_c 15.3748 _exptl_crystal_F_000 800.00 _reflns_d_resolution_high 0.7484 _cod_data_source_file tk5154Isup2.hkl _cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' diiodo_0m in P2(1)/c' _shelx_refln_list_code 4 _shelx_f_calc_maximum 326.83 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y-1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 1 0 0 0.91 3.17 3.33 o 2 0 0 0.78 -4.73 5.13 o 3 0 0 0.42 -5.43 6.98 o 4 0 0 6217.32 6237.69 105.70 o 5 0 0 24.62 16.41 12.58 o 6 0 0 92.73 61.91 24.27 o 1 1 0 5045.98 5251.65 58.02 o 2 1 0 23028.28 22774.78 174.79 o 3 1 0 498.76 453.80 13.18 o 4 1 0 19.82 5.66 7.50 o 5 1 0 26.02 13.91 9.42 o 6 1 0 24.75 23.11 24.12 o 0 2 0 729.89 847.49 18.94 o 1 2 0 31694.10 32191.51 212.00 o 2 2 0 6.44 7.14 4.00 o 3 2 0 2889.80 2874.95 40.01 o 4 2 0 169.75 173.86 13.35 o 5 2 0 87.50 81.65 13.97 o 6 2 0 8.54 12.01 15.28 o 1 3 0 64103.91 66120.56 506.98 o 2 3 0 8309.61 8313.04 64.25 o 3 3 0 6139.58 6036.62 55.59 o 4 3 0 0.52 -3.91 6.22 o 5 3 0 546.54 566.65 29.27 o 6 3 0 19.87 34.25 13.99 o 0 4 0 11461.16 11828.23 128.23 o 1 4 0 4826.71 5490.49 49.21 o 2 4 0 14.13 16.70 4.76 o 3 4 0 3.72 1.80 4.49 o 4 4 0 277.32 280.45 23.96 o 5 4 0 255.06 257.05 20.97 o 6 4 0 0.30 15.86 11.62 o 1 5 0 27820.21 29295.42 245.07 o 2 5 0 354.65 368.71 12.83 o 3 5 0 982.03 937.90 18.10 o 4 5 0 30.12 32.22 9.41 o 5 5 0 164.64 203.51 20.05 o 0 6 0 1670.34 1603.12 31.48 o 1 6 0 23817.50 24249.56 206.39 o 2 6 0 7.45 14.89 4.62 o 3 6 0 8214.04 8243.78 78.75 o 4 6 0 247.70 253.78 17.13 o 5 6 0 446.66 465.38 26.59 o 1 7 0 13782.29 13871.27 113.16 o 2 7 0 8247.60 8414.72 67.59 o 3 7 0 2798.96 2730.38 39.53 o 4 7 0 317.25 354.62 27.20 o 5 7 0 244.91 245.79 21.70 o 0 8 0 37728.29 39341.55 406.34 o 1 8 0 204.83 210.20 10.24 o 2 8 0 1467.11 1561.61 30.16 o 3 8 0 38.06 56.84 7.84 o 4 8 0 2795.88 2768.34 50.69 o 5 8 0 3.76 9.91 11.01 o 1 9 0 53.42 70.57 6.69 o 2 9 0 17232.99 17086.38 133.19 o 3 9 0 4.63 16.46 7.00 o 4 9 0 78.44 86.73 13.23 o 5 9 0 0.75 7.35 10.07 o 0 10 0 7866.43 8020.56 83.57 o 1 10 0 573.78 618.82 15.42 o 2 10 0 1236.89 1150.69 25.90 o 3 10 0 71.16 72.10 9.51 o 4 10 0 426.35 479.69 23.83 o 5 10 0 10.63 16.41 10.99 o 1 11 0 2368.29 2341.52 31.61 o 2 11 0 1893.97 1811.98 35.25 o 3 11 0 1015.04 1004.16 25.67 o 4 11 0 280.65 268.54 19.75 o 5 11 0 24.96 29.83 12.10 o 0 12 0 6120.80 6196.71 73.38 o 1 12 0 2858.29 2937.69 39.77 o 2 12 0 331.93 319.29 22.74 o 3 12 0 36.11 18.57 8.28 o 4 12 0 399.59 393.31 24.68 o 5 12 0 107.82 130.48 17.22 o 1 13 0 875.01 819.53 21.24 o 2 13 0 2484.35 2533.74 42.97 o 3 13 0 86.05 116.84 16.82 o 4 13 0 24.71 44.49 13.59 o 5 13 0 84.20 136.09 25.20 o 0 14 0 1.41 -7.47 9.97 o 1 14 0 5025.29 5038.00 58.93 o 2 14 0 32.84 32.44 9.48 o 3 14 0 1762.27 1678.37 35.57 o 4 14 0 10.57 -2.43 10.13 o 1 15 0 3075.43 2933.76 64.78 o 2 15 0 4.59 4.56 9.45 o 3 15 0 1022.52 1073.77 29.31 o 4 15 0 22.11 35.96 13.09 o 0 16 0 1613.89 1691.88 51.94 o 1 16 0 2133.71 2349.75 49.06 o 2 16 0 0.05 6.53 11.04 o 3 16 0 131.52 149.77 18.82 o 4 16 0 84.81 117.87 19.99 o 1 17 0 538.27 514.96 25.35 o 2 17 0 2153.18 2125.92 54.08 o 3 17 0 11.12 13.67 11.45 o 4 17 0 18.58 34.34 17.76 o 0 18 0 794.06 948.77 48.97 o 1 18 0 226.65 210.50 21.84 o 2 18 0 90.89 115.76 19.30 o 3 18 0 20.31 18.25 29.25 o 4 18 0 77.45 72.40 20.97 o 1 19 0 8.39 -2.66 11.58 o 2 19 0 11.43 23.80 18.49 o 3 19 0 8.47 1.00 14.26 o 0 20 0 2093.50 2072.08 71.62 o 1 20 0 88.26 84.02 21.55 o 2 20 0 55.51 63.47 32.49 o 3 20 0 3.67 -0.78 14.86 o 1 21 0 5.93 -8.89 21.07 o 2 21 0 276.36 321.72 28.22 o 3 21 0 9.48 -3.82 26.11 o 0 22 0 19.16 -2.79 17.33 o 1 22 0 25.15 12.25 13.63 o 2 22 0 0.34 -2.79 13.43 o 1 23 0 311.71 340.49 30.45 o 0 24 0 0.06 -10.03 27.85 o -6 1 1 0.36 12.80 12.53 o -5 1 1 133.51 125.49 15.48 o -4 1 1 507.18 499.99 18.14 o -3 1 1 13048.30 12802.13 90.62 o -2 1 1 499.94 504.85 9.31 o -1 1 1 293.19 260.38 7.49 o 1 1 1 51869.13 52302.95 368.58 o 2 1 1 1244.77 1271.36 22.68 o 3 1 1 312.23 336.88 16.05 o 4 1 1 220.05 214.25 15.07 o 5 1 1 560.38 593.30 25.46 o 6 1 1 3.97 17.28 13.51 o -6 2 1 21.72 18.58 13.58 o -5 2 1 350.16 319.88 21.04 o -4 2 1 80.74 73.55 9.51 o -3 2 1 2411.80 2317.83 29.62 o -2 2 1 352.35 347.81 7.96 o -1 2 1 64375.53 64138.79 365.23 o 0 2 1 215.55 234.72 6.12 o 1 2 1 126.20 95.48 6.26 o 2 2 1 214.63 222.83 8.33 o 3 2 1 9970.80 9540.07 93.37 o 4 2 1 315.29 331.19 17.61 o 5 2 1 310.71 305.72 21.92 o 6 2 1 7.35 -11.08 11.08 o -6 3 1 7.09 11.51 12.06 o -5 3 1 0.37 8.00 9.78 o -4 3 1 1642.66 1559.15 30.50 o -3 3 1 2983.05 2918.92 37.65 o -2 3 1 5251.75 5350.47 40.12 o -1 3 1 7.15 44.68 4.18 o 0 3 1 18319.83 18951.90 137.52 o 1 3 1 43449.43 44173.81 270.69 o 2 3 1 3743.61 3835.91 33.40 o 3 3 1 169.10 191.98 11.78 o 4 3 1 1337.22 1335.05 31.99 o 5 3 1 463.46 496.28 26.56 o 6 3 1 0.03 4.89 11.75 o -6 4 1 157.76 138.58 20.47 o -5 4 1 0.54 6.39 9.80 o -4 4 1 1217.54 1214.55 30.45 o -3 4 1 15.05 10.63 5.66 o -2 4 1 36559.36 36026.01 229.60 o -1 4 1 335.88 359.12 8.36 o 0 4 1 46407.16 49286.91 319.92 o 1 4 1 2630.09 2726.68 28.42 o 2 4 1 35766.63 35737.09 265.94 o 3 4 1 5.91 4.73 5.35 o 4 4 1 1529.79 1456.23 33.43 o 5 4 1 3.20 24.23 11.56 o -6 5 1 1.51 -1.74 11.32 o -5 5 1 0.52 -2.68 9.73 o -4 5 1 1740.08 1678.57 36.46 o -3 5 1 8.93 14.72 5.24 o -2 5 1 2063.46 2074.12 25.66 o -1 5 1 44.60 36.14 4.13 o 0 5 1 57265.13 58708.99 413.91 o 1 5 1 112.05 116.78 7.24 o 2 5 1 10217.13 10146.27 69.39 o 3 5 1 66.16 70.72 8.43 o 4 5 1 2725.17 2687.80 47.07 o 5 5 1 0.92 5.59 9.66 o -5 6 1 204.20 189.69 17.06 o -4 6 1 241.20 241.07 18.91 o -3 6 1 304.12 328.10 11.48 o -2 6 1 748.75 649.65 13.87 o -1 6 1 8940.38 8913.18 69.55 o 0 6 1 3168.45 3243.49 29.67 o 1 6 1 1102.47 1095.96 19.43 o 2 6 1 5246.90 5418.81 44.31 o 3 6 1 2744.56 2660.98 38.13 o 4 6 1 1317.68 1266.31 33.81 o 5 6 1 2.40 -9.36 10.22 o -5 7 1 27.71 47.58 11.83 o -4 7 1 56.46 54.69 10.88 o -3 7 1 4214.06 4180.08 45.73 o -2 7 1 4563.48 4690.68 51.73 o -1 7 1 2990.06 3062.35 30.91 o 0 7 1 5614.22 5720.39 46.67 o 1 7 1 26818.01 27004.44 221.09 o 2 7 1 5727.04 5880.35 50.67 o 3 7 1 36.48 41.25 10.14 o 4 7 1 1558.12 1484.45 36.99 o 5 7 1 494.42 488.77 28.34 o -5 8 1 2.18 6.74 9.75 o -4 8 1 230.09 227.30 18.27 o -3 8 1 522.75 502.80 17.77 o -2 8 1 1554.10 1497.53 32.88 o -1 8 1 2506.49 2416.59 27.70 o 0 8 1 1583.03 1617.45 21.36 o 1 8 1 166.01 221.03 10.52 o 2 8 1 6781.37 6685.47 57.41 o 3 8 1 1093.36 1106.38 25.45 o 4 8 1 293.93 273.41 20.37 o 5 8 1 30.85 20.91 12.47 o -5 9 1 4.17 22.55 10.67 o -4 9 1 7.18 15.20 9.45 o -3 9 1 405.81 390.57 24.72 o -2 9 1 100.04 123.24 9.79 o -1 9 1 749.44 758.51 16.55 o 0 9 1 742.36 781.99 15.98 o 1 9 1 3840.80 3947.76 46.26 o 2 9 1 8.18 15.05 6.33 o 3 9 1 1199.84 1144.35 28.28 o 4 9 1 31.27 57.40 13.79 o 5 9 1 22.31 18.44 11.91 o -5 10 1 517.59 488.70 26.12 o -4 10 1 1.09 -3.36 8.39 o -3 10 1 237.25 230.07 15.16 o -2 10 1 175.15 177.75 12.30 o -1 10 1 25676.17 25420.48 182.98 o 0 10 1 275.08 291.03 10.53 o 1 10 1 1337.33 1292.65 23.23 o 2 10 1 15.84 6.34 5.96 o 3 10 1 14947.17 14234.21 136.57 o 4 10 1 82.73 68.19 12.53 o 5 10 1 56.70 29.12 13.41 o -5 11 1 74.74 86.50 15.08 o -4 11 1 7.26 14.24 9.63 o -3 11 1 3551.75 3522.70 53.85 o -2 11 1 159.11 173.18 13.90 o -1 11 1 1839.11 1992.04 29.77 o 0 11 1 872.29 890.64 16.89 o 1 11 1 13378.76 13366.19 105.49 o 2 11 1 0.08 5.64 6.69 o 3 11 1 179.00 170.60 14.36 o 4 11 1 139.65 108.48 14.33 o 5 11 1 216.07 248.29 23.75 o -5 12 1 14.37 25.78 11.85 o -4 12 1 161.97 162.49 18.13 o -3 12 1 621.16 622.84 23.94 o -2 12 1 2964.16 2917.62 49.41 o -1 12 1 3013.07 3062.12 39.60 o 0 12 1 1590.88 1674.44 24.61 o 1 12 1 17.21 13.94 6.43 o 2 12 1 4869.47 4776.50 60.33 o 3 12 1 4.55 5.59 8.39 o 4 12 1 59.00 89.32 14.73 o 5 12 1 0.34 6.94 13.40 o -5 13 1 12.58 14.01 12.18 o -4 13 1 752.15 823.48 33.89 o -3 13 1 2.63 9.81 9.01 o -2 13 1 3505.09 3419.27 56.02 o -1 13 1 39.67 52.19 9.37 o 0 13 1 10735.46 11100.87 89.89 o 1 13 1 163.43 147.89 11.04 o 2 13 1 4566.98 4660.46 61.06 o 3 13 1 23.80 23.03 9.31 o 4 13 1 1035.62 1007.59 37.74 o 5 13 1 6.53 -0.45 13.54 o -5 14 1 5.74 1.29 11.87 o -4 14 1 61.23 62.97 14.00 o -3 14 1 20.99 8.54 8.73 o -2 14 1 4387.44 4579.80 68.58 o -1 14 1 62.61 66.89 10.57 o 0 14 1 718.81 788.64 21.60 o 1 14 1 8.45 10.64 8.14 o 2 14 1 83.94 101.66 12.06 o 3 14 1 14.94 7.10 9.01 o 4 14 1 48.74 91.34 15.39 o -4 15 1 25.66 15.59 11.31 o -3 15 1 150.94 173.31 14.72 o -2 15 1 536.95 498.07 22.34 o -1 15 1 88.85 79.34 12.34 o 0 15 1 38.74 24.61 7.74 o 1 15 1 765.55 795.97 28.39 o 2 15 1 34.91 37.12 12.07 o 3 15 1 0.06 -6.37 8.21 o 4 15 1 269.89 236.23 25.75 o -4 16 1 89.82 116.24 22.14 o -3 16 1 99.06 110.06 13.71 o -2 16 1 1185.98 1152.53 33.77 o -1 16 1 987.95 1077.43 34.96 o 0 16 1 1135.72 1164.71 27.72 o 1 16 1 22.93 21.72 13.87 o 2 16 1 649.89 610.16 30.64 o 3 16 1 367.43 426.78 29.52 o 4 16 1 11.31 20.28 16.33 o -4 17 1 181.08 217.61 29.79 o -3 17 1 35.35 32.64 12.54 o -2 17 1 572.31 553.55 35.38 o -1 17 1 256.27 293.75 22.76 o 0 17 1 1345.64 1322.79 38.28 o 1 17 1 115.62 97.74 14.78 o 2 17 1 197.35 223.94 21.96 o 3 17 1 159.72 188.60 24.92 o 4 17 1 102.59 94.37 23.89 o -4 18 1 4.25 -3.75 15.78 o -3 18 1 0.69 32.14 13.07 o -2 18 1 63.15 65.06 18.46 o -1 18 1 2150.00 2077.14 54.59 o 0 18 1 6.24 10.92 8.93 o 1 18 1 10.95 7.70 10.09 o 2 18 1 27.70 33.88 13.61 o 3 18 1 254.07 266.30 28.79 o 4 18 1 2.37 -14.44 17.34 o -3 19 1 615.35 643.71 34.80 o -2 19 1 0.72 -11.27 11.27 o -1 19 1 336.25 325.88 30.07 o 0 19 1 12.24 23.47 9.45 o 1 19 1 1244.18 1395.43 46.04 o 2 19 1 3.37 29.42 13.47 o 3 19 1 45.14 49.99 18.10 o -3 20 1 32.39 49.24 15.76 o -2 20 1 32.63 36.32 14.16 o -1 20 1 552.72 653.66 35.15 o 0 20 1 10.72 9.37 9.47 o 1 20 1 147.58 154.29 20.75 o 2 20 1 73.46 82.12 17.95 o 3 20 1 356.77 366.59 34.48 o -3 21 1 38.72 26.58 31.55 o -2 21 1 45.49 35.82 15.70 o -1 21 1 106.09 122.69 26.21 o 0 21 1 352.65 355.13 29.99 o 1 21 1 5.22 0.31 12.92 o 2 21 1 74.04 110.46 19.81 o -2 22 1 171.30 205.01 25.73 o -1 22 1 35.69 40.71 15.16 o 0 22 1 0.76 20.73 17.08 o 1 22 1 18.43 2.33 12.53 o 2 22 1 118.51 137.25 21.49 o -1 23 1 2.46 6.35 13.35 o 0 23 1 20.61 46.80 20.24 o 1 23 1 53.63 51.24 17.16 o 0 24 1 17.94 -10.58 20.48 o -6 0 2 53.25 69.86 23.96 o -5 0 2 4.62 27.56 15.66 o -4 0 2 1868.16 1676.02 67.22 o -3 0 2 12.10 14.13 6.65 o -2 0 2 44197.93 43580.07 342.10 o -1 0 2 515.96 472.36 8.96 o 0 0 2 289.02 317.51 12.61 o 1 0 2 21.70 -2.55 14.37 o 2 0 2 38656.56 37527.25 483.10 o 3 0 2 298.60 296.18 21.42 o 4 0 2 817.26 797.80 36.31 o 5 0 2 4.41 9.06 12.61 o 6 0 2 822.88 658.06 54.33 o -6 1 2 60.69 78.03 16.08 o -5 1 2 44.37 27.26 11.42 o -4 1 2 2282.03 2288.49 36.47 o -3 1 2 74.84 106.58 6.83 o -2 1 2 14369.89 14337.05 86.78 o -1 1 2 4730.48 4830.51 30.94 o 0 1 2 26789.69 27529.49 324.35 o 1 1 2 126.24 134.77 6.88 o 2 1 2 10032.69 9986.82 98.10 o 3 1 2 851.34 872.48 23.16 o 4 1 2 1758.85 1708.06 36.75 o 5 1 2 0.02 -4.68 8.77 o -6 2 2 2.15 -10.00 10.53 o -5 2 2 0.49 -0.47 10.43 o -4 2 2 0.33 -0.92 5.86 o -3 2 2 9043.30 8934.11 61.27 o -2 2 2 288.80 292.19 7.77 o -1 2 2 524.97 554.60 9.22 o 0 2 2 3092.25 3175.11 31.95 o 1 2 2 25909.94 25605.90 162.41 o 2 2 2 483.36 499.19 14.42 o 3 2 2 260.20 229.61 13.71 o 4 2 2 23.19 10.23 9.52 o 5 2 2 686.79 696.02 27.85 o -6 3 2 4.49 -2.56 11.29 o -5 3 2 366.40 379.93 20.90 o -4 3 2 1060.45 1019.36 24.12 o -3 3 2 256.80 280.55 11.24 o -2 3 2 402.08 411.31 8.44 o -1 3 2 30362.86 30016.59 176.11 o 0 3 2 5443.72 5542.57 46.66 o 1 3 2 21696.24 22328.50 135.47 o 2 3 2 834.05 778.71 13.13 o 3 3 2 6058.43 5848.92 91.64 o 4 3 2 757.52 733.55 25.16 o 5 3 2 490.93 476.26 27.02 o -6 4 2 13.98 17.72 12.82 o -5 4 2 6.01 5.99 8.40 o -4 4 2 104.25 107.84 14.49 o -3 4 2 802.87 794.97 15.29 o -2 4 2 3230.64 3253.74 38.83 o -1 4 2 3232.55 3400.24 29.65 o 0 4 2 1065.43 1070.46 14.78 o 1 4 2 13515.39 14199.90 96.74 o 2 4 2 1522.11 1427.73 19.58 o 3 4 2 206.94 207.64 16.42 o 4 4 2 29.46 29.87 9.67 o 5 4 2 57.69 46.02 19.80 o -6 5 2 2.06 9.53 13.09 o -5 5 2 393.85 393.16 21.85 o -4 5 2 33.96 27.45 8.73 o -3 5 2 323.50 330.16 10.75 o -2 5 2 17.14 17.39 4.00 o -1 5 2 12632.57 12814.33 93.38 o 0 5 2 1169.61 1188.70 23.38 o 1 5 2 143.09 139.56 6.90 o 2 5 2 3.21 -3.93 3.99 o 3 5 2 4344.95 4183.99 56.67 o 4 5 2 134.05 172.16 14.99 o 5 5 2 21.90 10.41 10.55 o -5 6 2 135.08 93.94 13.51 o -4 6 2 35.15 38.45 9.27 o -3 6 2 12323.26 12155.59 96.28 o -2 6 2 328.14 304.50 9.46 o -1 6 2 1301.25 1275.06 18.56 o 0 6 2 196.88 220.41 8.38 o 1 6 2 48004.16 47683.46 315.99 o 2 6 2 2109.84 2136.57 26.26 o 3 6 2 1374.21 1383.64 32.02 o 4 6 2 149.58 158.03 14.80 o 5 6 2 464.50 465.07 32.02 o -5 7 2 249.14 238.38 18.67 o -4 7 2 232.24 196.51 15.21 o -3 7 2 24.58 30.33 6.69 o -2 7 2 349.41 365.02 10.08 o -1 7 2 31680.21 31613.12 202.27 o 0 7 2 4156.42 4203.56 36.94 o 1 7 2 3285.36 3362.02 36.58 o 2 7 2 237.36 222.00 9.79 o 3 7 2 3458.27 3444.33 46.14 o 4 7 2 451.06 400.91 23.76 o 5 7 2 63.66 78.40 16.08 o -5 8 2 47.69 32.42 11.19 o -4 8 2 661.79 663.88 24.90 o -3 8 2 73.73 79.92 9.32 o -2 8 2 9555.17 9368.42 88.04 o -1 8 2 549.35 583.63 12.25 o 0 8 2 17311.43 17973.02 121.74 o 1 8 2 1394.82 1439.04 26.35 o 2 8 2 16120.69 16069.00 111.61 o 3 8 2 0.63 -4.51 6.30 o 4 8 2 206.60 208.54 19.07 o 5 8 2 0.64 1.18 11.28 o -5 9 2 14.35 13.42 10.10 o -4 9 2 1374.78 1381.99 41.83 o -3 9 2 2.71 8.80 7.34 o -2 9 2 8538.13 8658.85 70.64 o -1 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