#------------------------------------------------------------------------------ #$Date: 2016-04-03 06:48:33 +0300 (Sun, 03 Apr 2016) $ #$Revision: 181294 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/23/72/2237247.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2237247_Fobs loop_ _publ_author_name 'Werner, Julia' 'Jess, Inke' 'N\"ather, Christian' _publ_section_title ; Bis(4,4'-sulfanediyldipyridinium) tetrachloridonickelate(II) dichloride ; _journal_coeditor_code WM2703 _journal_issue 1 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first m59 _journal_volume 69 _journal_year 2013 _space_group_IT_number 15 _symmetry_space_group_name_Hall '-C 2yc' _symmetry_space_group_name_H-M 'C 1 2/c 1' _cell_angle_alpha 90.000 _cell_angle_beta 92.368 _cell_angle_gamma 90.000 _cell_length_a 19.0497 _cell_length_b 8.0534 _cell_length_c 17.7883 _exptl_crystal_F_000 1320.00 _reflns_d_resolution_high 0.7592 _cod_data_source_file wm2703Isup2.hkl _cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' NiCl4(Dipyridiniumthiolate)2-dichloride at 200 K in C2/c' _shelx_refln_list_code 4 _shelx_f_calc_maximum 283.06 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y, -z+1/2' 'x+1/2, y+1/2, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y, z-1/2' '-x+1/2, -y+1/2, -z' 'x+1/2, -y+1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 10 0 0 248.97 242.47 346.33 o 1 1 0 1834.33 1850.15 103.96 o 3 1 0 7442.44 6957.03 166.41 o 5 1 0 10514.11 9502.44 181.40 o 7 1 0 22.70 -3.02 93.40 o 9 1 0 735.77 738.24 162.09 o 11 1 0 6058.89 5947.00 174.56 o 13 1 0 144.00 134.34 115.13 o 15 1 0 221.17 287.14 134.58 o 17 1 0 4911.79 5184.26 191.63 o 2 2 0 514.68 401.89 99.58 o 4 2 0 34726.65 36536.08 218.09 o 6 2 0 5489.93 5386.04 179.34 o 8 2 0 28928.16 29890.75 1062.57 o 10 2 0 30084.65 30807.16 240.94 o 12 2 0 1698.41 2084.53 138.94 o 14 2 0 485.75 475.63 124.07 o 16 2 0 1459.56 1448.61 118.84 o 18 2 0 20.99 5.19 98.92 o 20 2 0 1448.73 1388.69 134.90 o 1 3 0 6876.01 7283.83 80.59 o 3 3 0 4822.17 4881.56 78.94 o 5 3 0 18065.74 18363.75 309.86 o 7 3 0 24693.40 25433.04 678.79 o 9 3 0 7160.33 7220.51 146.83 o 11 3 0 2533.36 2434.13 82.42 o 13 3 0 2232.93 2051.36 180.71 o 15 3 0 6083.39 6080.17 154.74 o 17 3 0 1037.72 1187.67 120.65 o 19 3 0 78.09 134.77 100.20 o 21 3 0 106.66 183.94 107.10 o 23 3 0 9.60 -24.53 157.82 o 0 4 0 1342.72 1425.05 123.05 o 2 4 0 7146.03 7945.13 89.93 o 4 4 0 29449.95 32062.77 214.12 o 6 4 0 474.85 549.72 72.02 o 8 4 0 9683.09 9836.19 230.06 o 10 4 0 2323.90 2413.14 72.33 o 12 4 0 12261.38 12491.07 158.49 o 14 4 0 2296.27 2151.34 100.72 o 16 4 0 99.45 40.33 96.27 o 18 4 0 157.86 199.36 106.07 o 20 4 0 252.52 207.94 95.99 o 22 4 0 380.79 448.27 115.73 o 1 5 0 6038.53 6699.53 161.24 o 3 5 0 8851.64 9943.26 143.54 o 5 5 0 896.76 979.86 72.08 o 7 5 0 1902.16 1951.55 60.63 o 9 5 0 1054.19 1089.27 67.03 o 11 5 0 216.99 82.97 76.78 o 13 5 0 782.80 765.66 62.64 o 15 5 0 8013.66 8574.96 109.58 o 17 5 0 1283.46 1390.58 79.21 o 19 5 0 2662.24 2578.17 145.37 o 21 5 0 93.74 182.14 102.01 o 0 6 0 1365.11 1355.01 105.34 o 2 6 0 10479.48 10594.94 155.07 o 4 6 0 2589.78 2802.02 71.79 o 6 6 0 184.95 265.42 69.64 o 8 6 0 485.92 432.54 63.17 o 10 6 0 2023.03 2024.56 67.45 o 12 6 0 370.22 344.37 57.90 o 14 6 0 2036.26 2004.10 84.27 o 16 6 0 130.88 155.62 76.05 o 18 6 0 1275.76 1226.60 79.88 o 20 6 0 1411.29 1391.88 151.35 o 1 7 0 2688.30 2757.51 111.26 o 3 7 0 3257.28 3469.38 94.90 o 5 7 0 1280.60 1358.35 102.39 o 7 7 0 2.11 27.98 55.85 o 9 7 0 2340.51 2328.32 55.51 o 11 7 0 69.40 60.21 67.12 o 13 7 0 119.93 123.28 65.20 o 15 7 0 382.48 505.70 133.32 o 17 7 0 144.70 129.35 92.69 o 0 8 0 427.78 223.52 154.45 o 2 8 0 3.55 69.16 78.70 o 4 8 0 338.16 339.13 79.62 o 6 8 0 3.13 -34.76 73.06 o 8 8 0 282.94 458.35 94.67 o 10 8 0 701.13 535.95 70.08 o 12 8 0 1613.69 1579.18 71.62 o 14 8 0 28.56 -87.78 87.78 o 16 8 0 138.98 129.35 102.82 o 1 9 0 16.83 69.09 73.27 o 3 9 0 1004.93 1046.02 56.98 o 5 9 0 3336.44 3454.23 95.02 o 7 9 0 3132.42 2972.59 78.58 o 9 9 0 261.48 185.60 66.01 o 11 9 0 1805.66 1524.60 83.63 o 13 9 0 616.77 623.45 86.61 o 0 10 0 5.50 30.82 340.80 o 2 10 0 45.33 17.93 95.90 o 4 10 0 156.70 288.25 110.92 o 6 10 0 206.55 225.87 83.17 o 8 10 0 426.20 355.16 80.70 o -15 1 1 244.23 277.14 137.60 o -13 1 1 424.96 480.60 180.41 o -11 1 1 27166.52 24677.72 433.53 o -9 1 1 25783.76 27041.96 235.46 o -7 1 1 9.07 -14.66 112.29 o -5 1 1 12957.16 13744.91 710.51 o -3 1 1 26173.28 28113.93 248.37 o -1 1 1 10187.23 10803.24 141.36 o 1 1 1 339.08 614.79 86.93 o 3 1 1 23027.00 21299.64 637.21 o 5 1 1 7274.15 6337.30 126.78 o 7 1 1 987.51 1133.34 87.49 o 9 1 1 3873.21 3589.22 115.71 o 11 1 1 2763.37 2677.00 125.79 o 13 1 1 10553.16 10582.00 150.33 o 15 1 1 1108.06 1045.00 139.73 o 17 1 1 75.46 42.14 129.16 o -20 2 1 1304.39 1443.24 134.23 o -18 2 1 336.21 147.62 100.84 o -16 2 1 6994.33 7037.72 162.23 o -14 2 1 253.20 281.34 122.07 o -12 2 1 9535.41 9485.55 409.38 o -10 2 1 4407.83 4473.43 90.89 o -8 2 1 13032.00 12713.51 210.47 o -6 2 1 1188.55 1319.93 83.72 o -2 2 1 262.74 352.76 100.10 o 0 2 1 42601.79 44189.62 337.46 o 2 2 1 13803.58 13549.51 188.23 o 4 2 1 47012.10 47922.15 920.22 o 6 2 1 19238.38 18411.82 567.36 o 8 2 1 31019.52 33899.24 336.27 o 10 2 1 476.63 467.66 88.31 o 12 2 1 1389.78 1644.47 137.38 o 14 2 1 5999.09 4978.97 651.73 o 16 2 1 5522.36 5660.34 118.63 o 18 2 1 4450.29 4164.00 247.62 o 20 2 1 95.05 127.65 119.35 o -23 3 1 650.46 743.79 157.85 o -21 3 1 366.09 362.71 126.14 o -19 3 1 2148.58 2104.32 178.59 o -17 3 1 206.05 277.42 117.48 o -15 3 1 3342.97 3271.48 122.53 o -13 3 1 343.83 395.75 70.05 o -11 3 1 247.46 213.65 80.15 o -9 3 1 4542.85 4661.23 84.87 o -7 3 1 10484.85 10912.29 94.31 o -5 3 1 1382.98 1454.43 77.55 o -3 3 1 11505.20 11684.94 99.30 o -1 3 1 17315.38 17490.94 350.93 o 1 3 1 12777.31 13355.88 91.37 o 3 3 1 5324.24 5611.86 80.17 o 5 3 1 1851.26 1803.57 83.05 o 7 3 1 1725.97 1653.96 80.68 o 9 3 1 6327.89 5904.69 100.48 o 11 3 1 1201.05 1323.97 78.12 o 13 3 1 285.08 294.49 78.32 o 15 3 1 9508.54 8902.14 139.05 o 17 3 1 1105.14 1146.23 84.24 o 19 3 1 271.98 233.85 90.86 o 21 3 1 544.17 506.51 113.57 o 23 3 1 2108.36 2345.60 160.41 o -22 4 1 477.72 600.73 116.92 o -20 4 1 91.77 116.05 95.74 o -18 4 1 2859.02 2759.83 114.29 o -16 4 1 38.43 26.17 95.96 o -14 4 1 1050.70 1212.71 73.74 o -12 4 1 3.47 -36.76 88.27 o -10 4 1 428.17 398.05 67.39 o -8 4 1 224.54 248.10 68.81 o -6 4 1 5598.09 5381.71 79.15 o -4 4 1 11398.60 12216.57 148.24 o -2 4 1 3194.88 3096.19 95.15 o 0 4 1 12.32 91.64 70.18 o 2 4 1 128.00 165.46 83.75 o 4 4 1 11073.72 12044.35 229.96 o 6 4 1 25951.95 27277.30 459.75 o 8 4 1 8051.92 8547.28 75.44 o 10 4 1 245.13 308.13 66.04 o 12 4 1 22.69 59.10 73.49 o 14 4 1 1829.52 1920.40 93.12 o 16 4 1 4604.12 4838.93 105.10 o 18 4 1 1923.84 1827.79 86.84 o 20 4 1 170.99 147.65 107.55 o 22 4 1 125.83 83.85 113.06 o -21 5 1 280.13 239.93 122.07 o -19 5 1 3.15 203.25 138.36 o -17 5 1 587.17 572.46 77.67 o -15 5 1 2292.87 2241.10 77.08 o -13 5 1 1361.95 1377.85 67.75 o -11 5 1 6.39 63.87 74.23 o -9 5 1 195.35 133.90 52.85 o -7 5 1 4292.66 4578.32 67.18 o -5 5 1 10532.91 11188.28 154.94 o -3 5 1 598.21 687.25 73.19 o -1 5 1 11730.69 13633.30 119.33 o 1 5 1 15846.67 17162.38 312.01 o 3 5 1 10278.39 11105.66 213.62 o 5 5 1 2638.49 2729.10 73.48 o 7 5 1 413.62 479.55 76.75 o 9 5 1 638.51 597.24 60.65 o 11 5 1 11422.11 11504.71 161.83 o 13 5 1 457.64 432.48 72.75 o 15 5 1 4.70 68.70 92.04 o 17 5 1 39.88 -45.00 82.99 o 19 5 1 2062.25 2171.66 186.88 o 21 5 1 824.51 748.70 95.38 o -20 6 1 114.89 150.38 120.99 o -18 6 1 0.69 -45.51 77.35 o -16 6 1 29.65 76.95 59.03 o -14 6 1 92.83 102.31 75.42 o -12 6 1 26.31 -4.01 67.48 o -10 6 1 64.00 57.49 63.35 o -8 6 1 3412.00 3386.77 81.66 o -6 6 1 7.25 -33.57 108.91 o -4 6 1 228.20 365.48 68.33 o -2 6 1 195.52 282.21 58.08 o 0 6 1 3194.32 3268.91 71.09 o 2 6 1 141.88 232.65 66.02 o 4 6 1 31.05 25.45 68.04 o 6 6 1 3082.32 3159.56 87.73 o 8 6 1 340.68 345.15 63.84 o 10 6 1 184.62 204.64 64.31 o 12 6 1 56.98 11.82 61.07 o 14 6 1 62.06 84.41 72.09 o 16 6 1 39.20 90.87 81.17 o 18 6 1 237.92 218.07 77.13 o 20 6 1 130.01 41.64 94.14 o -17 7 1 7.05 57.18 84.23 o -15 7 1 1284.76 1199.17 81.23 o -13 7 1 1158.82 1101.24 74.36 o -11 7 1 1731.34 1800.04 69.03 o -9 7 1 924.66 853.05 67.89 o -7 7 1 2008.96 2133.14 67.28 o -5 7 1 750.22 751.98 59.26 o -3 7 1 412.73 496.14 77.74 o -1 7 1 3025.83 3254.26 77.76 o 1 7 1 5138.51 5429.01 136.44 o 3 7 1 3078.07 3089.38 75.05 o 5 7 1 450.93 457.92 79.04 o 7 7 1 1496.80 1494.56 69.66 o 9 7 1 2044.29 2155.51 119.16 o 11 7 1 11331.91 11246.43 115.86 o 13 7 1 219.42 188.81 72.18 o 15 7 1 106.38 108.27 78.86 o 17 7 1 104.22 155.61 92.41 o -16 8 1 438.86 396.43 70.41 o -14 8 1 3116.16 2856.75 83.23 o -12 8 1 289.25 274.79 76.50 o -10 8 1 2102.70 1997.61 111.12 o -8 8 1 2994.15 2943.88 85.27 o -6 8 1 2331.30 2350.05 76.24 o -4 8 1 225.50 205.71 65.04 o -2 8 1 264.67 232.54 79.33 o 0 8 1 8.33 104.13 61.10 o 2 8 1 340.50 456.65 77.64 o 4 8 1 649.75 748.04 69.80 o 6 8 1 665.40 708.85 73.44 o 8 8 1 928.15 824.83 59.87 o 10 8 1 659.57 717.93 62.77 o 12 8 1 16.21 -86.33 108.58 o 14 8 1 4.27 0.68 86.12 o 16 8 1 190.28 83.58 114.14 o -13 9 1 90.72 -28.79 81.80 o -11 9 1 6.09 100.67 84.88 o -9 9 1 181.88 281.82 70.34 o -7 9 1 144.52 169.53 65.81 o -5 9 1 407.65 282.40 70.50 o -3 9 1 0.05 155.71 62.40 o -1 9 1 25.51 4.08 80.99 o 1 9 1 1473.67 1458.02 109.44 o 3 9 1 542.69 470.59 80.13 o 5 9 1 27.52 51.99 94.03 o 7 9 1 1072.99 1075.08 102.85 o 9 9 1 113.23 126.52 84.94 o 11 9 1 41.24 74.14 79.26 o 13 9 1 70.11 59.28 118.77 o -8 10 1 933.65 686.61 74.13 o -6 10 1 1045.98 1170.72 78.48 o -4 10 1 1562.59 1618.74 88.65 o -2 10 1 596.59 467.74 92.64 o 0 10 1 309.32 165.16 85.34 o 2 10 1 152.25 284.79 92.22 o 4 10 1 232.02 219.38 83.18 o 6 10 1 5.44 79.52 94.78 o 8 10 1 6.83 12.03 71.44 o -10 0 2 3030.69 3684.94 323.19 o -8 0 2 349.38 574.03 137.11 o -6 0 2 14126.93 12593.87 197.71 o -2 0 2 1701.75 1309.85 255.31 o 0 0 2 2226.78 2017.01 111.55 o 2 0 2 3787.36 4260.27 279.36 o 4 0 2 829.76 1066.70 190.00 o 6 0 2 1636.50 1490.00 133.39 o 8 0 2 13636.51 12940.76 262.56 o 10 0 2 10098.72 9364.13 374.61 o 12 0 2 21072.79 19159.12 2954.64 o 14 0 2 37197.02 34607.72 3024.03 o -15 1 2 3033.94 3056.37 221.30 o -13 1 2 2452.72 2337.88 169.48 o -11 1 2 255.20 250.46 110.85 o -9 1 2 1090.67 901.41 123.72 o -7 1 2 24799.56 24729.77 448.47 o -5 1 2 11769.26 11184.45 134.64 o -3 1 2 33452.89 34013.74 717.23 o -1 1 2 6899.29 6185.92 117.06 o 1 1 2 14712.89 13405.54 165.29 o 3 1 2 59.20 251.16 140.10 o 5 1 2 1260.26 1202.25 88.95 o 7 1 2 4799.71 4551.37 84.50 o 9 1 2 95.73 83.21 86.24 o 11 1 2 881.32 597.73 86.42 o 13 1 2 2766.29 2560.75 111.45 o 15 1 2 1677.22 1703.06 141.26 o 17 1 2 7082.54 6443.20 685.84 o -20 2 2 171.02 156.33 133.00 o -18 2 2 17.46 6.50 107.71 o -16 2 2 420.28 388.05 136.54 o -14 2 2 7078.28 6813.17 256.30 o -12 2 2 20937.86 21189.82 530.49 o -10 2 2 973.21 767.01 84.65 o -8 2 2 1305.84 1516.46 85.95 o -6 2 2 108.50 113.74 75.01 o -4 2 2 525.67 537.99 67.46 o -2 2 2 80125.67 83418.51 453.21 o 0 2 2 1808.04 1834.37 131.42 o 2 2 2 4863.13 4777.70 98.12 o 4 2 2 32973.21 31633.45 544.12 o 6 2 2 3906.10 3780.61 272.63 o 8 2 2 2511.17 2552.73 93.10 o 10 2 2 41.68 37.68 81.29 o 12 2 2 10170.29 9893.43 228.75 o 14 2 2 113.73 81.75 95.35 o 16 2 2 292.65 257.10 103.44 o 18 2 2 1921.73 1936.42 102.26 o 20 2 2 1879.35 2124.44 126.70 o -23 3 2 7.03 90.69 157.51 o -21 3 2 504.83 446.51 116.52 o -19 3 2 352.66 194.40 128.81 o -17 3 2 2070.17 1984.75 123.68 o -15 3 2 13504.55 13614.15 400.54 o -13 3 2 8723.85 8748.29 178.63 o -11 3 2 1150.12 1321.41 74.33 o -9 3 2 1926.44 1851.60 81.26 o -7 3 2 6942.63 7519.79 99.95 o -5 3 2 10580.32 11152.65 174.59 o -3 3 2 406.77 505.46 70.66 o -1 3 2 229.63 250.23 59.75 o 1 3 2 525.02 508.60 74.48 o 3 3 2 21153.81 20570.19 225.88 o 5 3 2 24921.93 25524.91 668.01 o 7 3 2 31560.65 31274.01 727.85 o 9 3 2 6641.82 6455.13 90.67 o 11 3 2 920.82 1050.38 82.40 o 13 3 2 176.26 111.57 73.66 o 15 3 2 47.80 90.37 80.87 o 17 3 2 1137.26 1032.56 82.92 o 19 3 2 556.95 557.16 98.68 o 21 3 2 185.00 293.35 113.56 o 23 3 2 188.36 204.21 130.82 o -22 4 2 1047.38 1222.39 119.37 o -20 4 2 4.27 -23.88 111.27 o -18 4 2 4.84 19.44 103.08 o -16 4 2 577.36 575.32 84.78 o -14 4 2 69.08 91.29 69.96 o -12 4 2 3098.44 3017.56 144.20 o -10 4 2 6556.83 6626.67 84.10 o -8 4 2 7583.78 7972.33 84.19 o -6 4 2 8286.67 8758.11 109.47 o -4 4 2 2489.48 2331.32 81.31 o -2 4 2 4881.78 5920.76 160.58 o 0 4 2 4397.64 4693.66 91.29 o 2 4 2 1482.55 1582.03 92.09 o 4 4 2 1887.06 2038.76 79.48 o 6 4 2 8091.14 7843.17 131.83 o 8 4 2 7135.34 6964.25 128.94 o 10 4 2 6481.17 5759.83 197.00 o 12 4 2 675.23 652.94 86.52 o 14 4 2 3.92 -24.15 77.85 o 16 4 2 614.39 609.43 70.44 o 18 4 2 49.50 43.02 82.54 o 20 4 2 361.94 328.18 87.44 o 22 4 2 273.56 359.21 113.04 o -21 5 2 607.29 550.39 123.61 o -19 5 2 70.88 -25.41 112.19 o -17 5 2 45.64 -22.33 68.15 o -15 5 2 34.26 29.66 70.11 o -13 5 2 162.78 229.75 76.18 o -11 5 2 7989.10 8376.18 99.57 o -9 5 2 218.40 307.91 62.64 o -7 5 2 1082.13 1142.78 67.54 o -5 5 2 20842.95 21558.60 136.06 o -3 5 2 5010.55 5426.83 97.83 o -1 5 2 4082.11 4243.09 72.60 o 1 5 2 4120.94 4370.11 134.92 o 3 5 2 372.68 442.89 74.10 o 5 5 2 626.77 681.00 65.66 o 7 5 2 448.90 363.95 64.70 o 9 5 2 2095.94 2060.20 61.91 o 11 5 2 551.50 477.14 73.73 o 13 5 2 4.46 -66.25 66.25 o 15 5 2 4106.33 3980.50 86.21 o 17 5 2 1195.36 1128.53 83.04 o 19 5 2 758.94 750.67 96.06 o 21 5 2 75.81 36.17 113.86 o -20 6 2 999.07 1095.47 122.25 o -18 6 2 901.22 972.24 89.33 o -16 6 2 40.48 39.13 58.39 o -14 6 2 89.02 77.54 105.69 o -12 6 2 592.66 568.84 61.66 o -10 6 2 5160.62 5256.60 126.56 o -8 6 2 8110.95 8273.24 131.21 o -6 6 2 253.34 327.85 80.39 o -4 6 2 3276.37 3410.82 72.11 o -2 6 2 12359.95 13567.43 230.46 o 0 6 2 25937.43 28070.31 573.60 o 2 6 2 2156.19 2304.86 77.40 o 4 6 2 772.67 839.15 63.56 o 6 6 2 2584.23 2632.77 80.19 o 8 6 2 1878.48 1889.72 79.88 o 10 6 2 375.96 311.54 59.12 o 12 6 2 4262.38 4141.83 112.03 o 14 6 2 693.98 652.71 75.30 o 16 6 2 3068.74 2979.38 128.38 o 18 6 2 76.59 79.40 86.09 o 20 6 2 1100.83 1070.66 106.09 o -17 7 2 1769.85 1812.48 76.61 o -15 7 2 552.16 647.80 101.00 o -13 7 2 415.39 354.38 68.05 o -11 7 2 235.54 346.00 72.73 o -9 7 2 3294.11 3295.24 120.79 o -7 7 2 25.39 -56.29 56.29 o -5 7 2 5893.84 6232.71 77.38 o -3 7 2 332.72 264.00 76.52 o -1 7 2 7729.17 8476.71 147.55 o 1 7 2 205.31 241.66 73.17 o 3 7 2 622.51 642.80 113.39 o 5 7 2 2513.11 2380.47 111.79 o 7 7 2 441.46 524.55 63.55 o 9 7 2 149.61 197.74 85.51 o 11 7 2 1616.76 1712.07 66.24 o 13 7 2 843.39 756.18 72.01 o 15 7 2 953.02 1019.11 83.12 o 17 7 2 686.95 743.44 93.93 o -16 8 2 65.36 209.94 71.81 o -14 8 2 13.07 -78.06 78.24 o -12 8 2 569.68 563.29 74.40 o -10 8 2 3205.11 2943.00 108.02 o -8 8 2 1377.41 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