#------------------------------------------------------------------------------ #$Date: 2013-08-28 13:42:33 +0300 (Wed, 28 Aug 2013) $ #$Revision: 88054 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/23/76/2237639.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2237639_Fobs loop_ _publ_author_name 'Zukerman-Schpector, Julio' 'Olivato, Paulo R.' 'Cerqueira Jr, Carlos R.' 'Contieri, Bruna' 'Ng, Seik Weng' 'Tiekink, Edward R. T.' _publ_section_title ; 3,3-Bis(4-bromophenylsulfanyl)-1-methylpiperidin-2-one ; _journal_coeditor_code HG5299 _journal_issue 4 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first o556 _journal_volume 69 _journal_year 2013 _space_group_IT_number 14 _symmetry_space_group_name_Hall '-P 2yn' _symmetry_space_group_name_H-M 'P 1 21/n 1' _cell_angle_alpha 90.000 _cell_angle_beta 93.190 _cell_angle_gamma 90.000 _cell_length_a 7.8777 _cell_length_b 9.6481 _cell_length_c 24.6757 _exptl_crystal_F_000 968.00 _reflns_d_resolution_high 0.7922 _[local]_cod_data_source_file hg5299Isup2.hkl _[local]_cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' P21/n' _shelx_refln_list_code 4 _shelx_f_calc_maximum 275.61 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x-1/2, -y-1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 15906.33 15815.60 154.16 o 4 0 0 1930.88 1997.98 95.87 o 6 0 0 78.53 74.35 13.80 o 8 0 0 4717.42 4860.40 105.33 o 1 1 0 31.31 56.43 4.78 o 2 1 0 124.32 193.63 8.83 o 3 1 0 6252.14 5822.47 67.94 o 4 1 0 22477.96 21446.10 229.21 o 5 1 0 3698.98 3624.43 61.12 o 6 1 0 1994.05 2083.23 61.40 o 7 1 0 1811.15 1718.65 34.17 o 8 1 0 733.07 820.94 33.96 o 9 1 0 81.89 104.20 9.88 o 0 2 0 21757.47 22260.67 135.76 o 1 2 0 62082.24 53513.78 885.52 o 2 2 0 1.39 7.99 2.65 o 3 2 0 9723.64 9808.05 83.53 o 4 2 0 4471.88 4764.18 90.67 o 5 2 0 2224.63 2156.17 63.18 o 6 2 0 302.78 307.39 13.82 o 7 2 0 47.27 29.91 7.03 o 8 2 0 298.55 288.39 16.94 o 9 2 0 239.89 270.63 20.25 o 1 3 0 2192.04 2329.13 24.91 o 2 3 0 3673.73 4019.39 50.95 o 3 3 0 1816.05 1794.85 28.45 o 4 3 0 5334.39 5427.72 138.64 o 5 3 0 4155.28 4450.34 150.45 o 6 3 0 94.91 88.72 7.09 o 7 3 0 200.25 196.21 10.44 o 8 3 0 1068.89 1066.19 28.36 o 9 3 0 2683.16 3140.84 157.47 o 0 4 0 34956.59 36330.48 347.85 o 1 4 0 448.82 505.52 15.82 o 2 4 0 423.00 482.05 18.75 o 3 4 0 5.49 7.27 4.73 o 4 4 0 94.71 110.01 16.81 o 5 4 0 6147.28 6280.30 90.32 o 6 4 0 743.09 797.05 22.66 o 7 4 0 506.45 520.11 19.56 o 8 4 0 161.75 151.98 8.67 o 9 4 0 101.64 137.38 11.64 o 1 5 0 602.84 788.17 34.29 o 2 5 0 2554.35 2811.54 89.07 o 3 5 0 326.82 353.92 23.87 o 4 5 0 1017.31 1060.40 42.28 o 5 5 0 3.51 5.50 3.41 o 6 5 0 976.71 961.75 23.63 o 7 5 0 927.99 915.25 26.37 o 8 5 0 1062.37 1038.84 23.30 o 9 5 0 919.73 1166.59 39.58 o 0 6 0 58.75 69.37 16.97 o 1 6 0 417.63 385.88 26.55 o 2 6 0 222.67 203.33 13.53 o 3 6 0 123.04 126.39 13.17 o 4 6 0 3028.27 3129.12 62.57 o 5 6 0 54.86 80.19 6.99 o 6 6 0 490.64 485.67 16.99 o 7 6 0 993.78 994.14 28.86 o 8 6 0 66.93 85.59 9.70 o 1 7 0 602.12 700.35 31.95 o 2 7 0 86.55 84.63 6.96 o 3 7 0 8031.26 8194.32 113.40 o 4 7 0 1.42 7.79 4.57 o 5 7 0 313.12 312.43 14.20 o 6 7 0 25.61 35.73 5.43 o 7 7 0 50.02 56.13 10.09 o 8 7 0 1057.69 1057.87 51.75 o 0 8 0 2135.57 2283.13 52.91 o 1 8 0 764.91 776.82 23.69 o 2 8 0 6634.76 6787.94 131.69 o 3 8 0 1264.70 1277.35 27.21 o 4 8 0 359.28 354.54 17.34 o 5 8 0 1018.79 1067.61 30.27 o 6 8 0 3291.78 3365.20 71.45 o 7 8 0 1170.20 1051.52 88.85 o 1 9 0 141.47 156.27 15.93 o 2 9 0 4619.28 4734.28 61.46 o 3 9 0 72.16 69.45 7.19 o 4 9 0 378.85 411.03 19.03 o 5 9 0 62.96 74.42 7.86 o 6 9 0 450.79 505.97 39.89 o 0 10 0 89.79 106.56 15.22 o 1 10 0 7295.62 7610.94 90.77 o 2 10 0 1900.71 1995.59 37.28 o 3 10 0 21.39 15.07 4.58 o 4 10 0 269.95 287.51 16.85 o 5 10 0 2.79 6.60 3.84 o 1 11 0 138.38 117.37 9.21 o 2 11 0 120.81 110.16 9.69 o 3 11 0 1803.03 1865.15 39.88 o 4 11 0 50.08 55.74 9.47 o 0 12 0 695.30 812.74 27.69 o 1 12 0 753.81 792.47 21.98 o -9 0 1 1394.02 1455.58 154.81 o -7 0 1 6536.60 6516.75 135.79 o -5 0 1 1686.39 1925.27 64.89 o -3 0 1 264.69 404.53 33.42 o -1 0 1 4186.97 4547.20 81.13 o 1 0 1 455.14 477.01 20.38 o 3 0 1 35.60 21.78 5.05 o 5 0 1 558.08 592.36 31.53 o 7 0 1 23.15 51.23 10.25 o 9 0 1 4375.22 4926.38 558.89 o -9 1 1 251.99 287.44 18.75 o -8 1 1 275.93 269.87 13.59 o -7 1 1 1873.62 1839.23 35.86 o -6 1 1 313.10 318.62 14.90 o -5 1 1 4.95 21.18 5.32 o -4 1 1 3516.70 3456.45 74.06 o -3 1 1 66.47 80.78 4.13 o -2 1 1 925.72 997.35 11.18 o -1 1 1 10211.92 10445.82 81.91 o 0 1 1 15.62 30.79 1.85 o 1 1 1 5464.81 5728.83 51.74 o 2 1 1 16654.91 16413.07 260.30 o 3 1 1 385.78 352.98 13.55 o 4 1 1 1435.24 1434.06 34.19 o 5 1 1 16342.89 16071.60 132.12 o 6 1 1 4681.99 4502.85 73.87 o 7 1 1 372.88 371.60 22.16 o 8 1 1 326.92 346.54 22.88 o 9 1 1 25.83 25.47 6.20 o -9 2 1 146.91 194.15 18.18 o -8 2 1 5706.11 5645.49 69.42 o -7 2 1 10.88 15.32 4.93 o -6 2 1 64.07 73.06 6.73 o -5 2 1 5133.46 5231.70 146.07 o -4 2 1 25.31 60.83 7.75 o -3 2 1 16557.54 16935.28 237.43 o -2 2 1 14252.70 14901.27 344.52 o -1 2 1 7498.54 7781.94 56.38 o 0 2 1 41.55 44.40 3.24 o 1 2 1 8500.43 8985.23 69.21 o 2 2 1 4674.46 4637.46 34.40 o 3 2 1 7226.37 7113.76 69.22 o 4 2 1 34.54 71.97 8.50 o 5 2 1 6196.75 6505.91 83.91 o 6 2 1 582.08 563.68 19.07 o 7 2 1 1644.84 1641.31 39.82 o 8 2 1 371.76 393.88 22.52 o 9 2 1 11.00 1.44 11.35 o -9 3 1 785.86 958.70 48.52 o -8 3 1 1477.18 1480.18 33.94 o -7 3 1 856.46 913.64 24.59 o -6 3 1 57.05 53.59 6.16 o -5 3 1 482.71 490.09 28.99 o -4 3 1 5556.50 5948.75 104.41 o -3 3 1 6374.36 6688.54 75.50 o -2 3 1 1680.62 1679.12 18.52 o -1 3 1 31169.62 32133.31 148.05 o 0 3 1 11859.80 11671.06 101.07 o 1 3 1 12119.36 12574.85 74.89 o 2 3 1 220.23 334.91 11.27 o 3 3 1 5043.84 5005.99 43.72 o 4 3 1 1037.44 1147.78 31.94 o 5 3 1 651.30 643.64 33.03 o 6 3 1 2066.03 1988.93 32.81 o 7 3 1 806.94 854.39 22.19 o 8 3 1 72.11 83.07 10.79 o 9 3 1 257.33 307.21 18.32 o -9 4 1 14.27 12.76 6.50 o -8 4 1 11.78 12.16 4.39 o -7 4 1 672.04 678.65 22.26 o -6 4 1 2421.48 2392.90 39.10 o -5 4 1 3002.95 3181.69 64.10 o -4 4 1 15720.35 15603.37 287.24 o -3 4 1 853.24 1035.12 22.10 o -2 4 1 6254.46 6085.68 56.19 o -1 4 1 6676.75 7546.73 86.14 o 0 4 1 1.52 13.87 7.08 o 1 4 1 171.10 213.64 11.60 o 2 4 1 8337.67 8374.39 72.46 o 3 4 1 6039.91 6360.43 63.18 o 4 4 1 14911.31 15175.83 165.22 o 5 4 1 1634.43 1690.18 46.68 o 6 4 1 6481.91 6501.86 64.83 o 7 4 1 427.13 444.08 18.08 o 8 4 1 209.33 194.29 14.58 o 9 4 1 1910.70 2105.72 71.98 o -9 5 1 12.49 22.52 7.24 o -8 5 1 1193.28 1209.00 26.34 o -7 5 1 1230.26 1232.47 30.65 o -6 5 1 4094.89 4060.81 52.40 o -5 5 1 23.50 42.58 4.78 o -4 5 1 8.68 20.37 12.50 o -3 5 1 134.29 207.94 12.85 o -2 5 1 5958.11 6332.04 76.33 o -1 5 1 831.68 882.67 28.55 o 0 5 1 20653.19 21415.83 138.73 o 1 5 1 13881.22 13945.86 111.65 o 2 5 1 7759.28 7807.00 71.56 o 3 5 1 2.24 11.89 3.54 o 4 5 1 3.80 21.50 9.25 o 5 5 1 2571.77 2561.52 39.37 o 6 5 1 91.35 92.03 7.69 o 7 5 1 776.51 806.84 24.78 o 8 5 1 560.17 581.41 20.30 o -8 6 1 645.11 624.53 17.49 o -7 6 1 336.66 300.09 17.78 o -6 6 1 71.11 81.03 8.31 o -5 6 1 2297.87 2290.31 34.07 o -4 6 1 392.75 452.29 13.91 o -3 6 1 16250.20 15776.06 177.24 o -2 6 1 4745.89 5009.23 94.00 o -1 6 1 684.59 726.99 36.07 o 0 6 1 219.50 234.88 22.70 o 1 6 1 4111.86 4481.94 88.73 o 2 6 1 190.38 185.26 14.38 o 3 6 1 844.61 736.06 29.23 o 4 6 1 5684.61 5949.61 105.05 o 5 6 1 14620.98 14311.03 129.60 o 6 6 1 704.99 721.75 21.95 o 7 6 1 2031.14 1997.74 43.28 o 8 6 1 1499.06 1534.25 42.32 o -8 7 1 0.55 -6.67 8.50 o -7 7 1 566.77 552.31 20.12 o -6 7 1 1086.86 1108.87 23.88 o -5 7 1 1281.70 1227.99 29.68 o -4 7 1 267.29 260.99 13.06 o -3 7 1 102.27 111.85 7.15 o -2 7 1 311.91 338.07 13.24 o -1 7 1 5473.32 5650.46 130.34 o 0 7 1 924.48 927.79 37.27 o 1 7 1 3799.10 3843.22 90.39 o 2 7 1 926.27 926.27 22.72 o 3 7 1 37.23 26.35 4.22 o 4 7 1 166.55 159.43 10.58 o 5 7 1 153.11 152.40 9.97 o 6 7 1 12.96 22.21 4.92 o 7 7 1 4.78 4.76 4.82 o 8 7 1 382.75 386.61 31.17 o -7 8 1 116.39 130.20 14.41 o -6 8 1 416.39 390.61 15.17 o -5 8 1 2.71 9.80 4.41 o -4 8 1 3286.56 3286.38 54.87 o -3 8 1 61.04 69.62 6.77 o -2 8 1 668.61 662.51 24.57 o -1 8 1 445.93 458.51 17.16 o 0 8 1 161.18 167.75 10.09 o 1 8 1 24.07 21.79 4.90 o 2 8 1 452.19 447.35 20.46 o 3 8 1 1850.65 1838.35 35.48 o 4 8 1 398.66 365.07 17.85 o 5 8 1 23.51 22.40 5.56 o 6 8 1 1401.11 1462.87 32.95 o 7 8 1 19.73 26.39 7.36 o -6 9 1 290.45 289.00 14.83 o -5 9 1 267.49 267.55 12.63 o -4 9 1 33.23 40.44 6.87 o -3 9 1 0.58 11.03 4.74 o -2 9 1 724.81 756.63 24.79 o -1 9 1 521.10 504.01 24.33 o 0 9 1 321.41 310.63 18.77 o 1 9 1 3632.26 3782.25 74.95 o 2 9 1 233.04 242.97 16.08 o 3 9 1 643.10 687.04 21.12 o 4 9 1 337.76 332.56 16.14 o 5 9 1 52.65 47.53 9.36 o 6 9 1 176.92 164.46 9.35 o -5 10 1 0.05 5.39 3.24 o -4 10 1 100.62 104.30 10.26 o -3 10 1 293.95 302.82 14.12 o -2 10 1 15.39 7.89 6.46 o -1 10 1 699.28 743.66 28.83 o 0 10 1 82.22 112.76 9.58 o 1 10 1 8.04 18.12 8.82 o 2 10 1 48.53 50.62 7.14 o 3 10 1 856.98 880.05 23.99 o 4 10 1 98.93 91.51 12.23 o 5 10 1 137.19 150.56 12.06 o -4 11 1 109.60 120.59 13.01 o -3 11 1 1116.84 1077.39 38.44 o -2 11 1 643.08 656.68 22.18 o -1 11 1 767.73 820.53 26.01 o 0 11 1 810.41 812.52 26.48 o 1 11 1 121.92 125.84 8.92 o 2 11 1 3.24 -0.74 3.90 o 3 11 1 350.90 374.56 28.10 o 4 11 1 323.11 340.04 30.64 o -1 12 1 98.10 96.30 9.38 o 0 12 1 61.25 57.66 5.97 o 1 12 1 24.90 21.02 4.76 o -8 0 2 2791.32 2951.60 55.54 o -6 0 2 5730.09 5657.19 120.34 o -4 0 2 1240.72 1233.54 32.64 o -2 0 2 75959.29 48472.34 2154.04 o 0 0 2 5758.44 4867.23 62.49 o 2 0 2 21203.91 19798.20 121.26 o 4 0 2 1872.17 2043.11 51.21 o 6 0 2 7035.70 6739.01 105.88 o 8 0 2 0.82 10.47 7.33 o -9 1 2 297.29 319.16 19.39 o -8 1 2 324.07 299.16 14.67 o -7 1 2 170.81 182.54 10.87 o -6 1 2 3425.05 3426.22 61.21 o -5 1 2 7518.31 7924.62 102.29 o -4 1 2 14422.90 14599.38 240.16 o -3 1 2 23291.66 22550.07 338.86 o -2 1 2 43053.19 41395.21 431.46 o -1 1 2 1050.95 1058.55 10.69 o 0 1 2 1124.41 1125.85 26.75 o 1 1 2 944.10 1028.04 14.05 o 2 1 2 13681.29 13217.65 154.86 o 3 1 2 347.98 254.15 11.95 o 4 1 2 238.83 233.12 13.49 o 5 1 2 923.50 826.82 30.88 o 6 1 2 1378.16 1320.64 32.82 o 7 1 2 533.79 537.60 24.49 o 8 1 2 0.69 9.89 6.84 o 9 1 2 141.20 157.40 12.05 o -9 2 2 1672.35 1806.96 55.42 o -8 2 2 4.74 16.27 5.19 o -7 2 2 6271.23 6190.88 104.17 o -6 2 2 541.34 562.05 17.35 o -5 2 2 329.90 391.31 24.67 o -4 2 2 8.27 11.59 3.99 o -3 2 2 1453.32 1549.60 23.86 o -2 2 2 945.02 959.64 12.41 o -1 2 2 13669.21 13601.04 93.54 o 0 2 2 6991.46 7374.78 81.54 o 1 2 2 56639.48 48189.06 181.84 o 2 2 2 1761.08 1734.52 33.56 o 3 2 2 1085.24 1052.49 26.71 o 4 2 2 2943.93 2831.27 57.24 o 5 2 2 161.75 179.85 15.78 o 6 2 2 2749.52 2792.74 47.21 o 7 2 2 1971.69 1934.72 46.60 o 8 2 2 40.89 46.77 9.37 o 9 2 2 74.95 70.95 8.59 o -9 3 2 0.38 -6.02 6.02 o -8 3 2 2.58 15.92 5.36 o -7 3 2 485.81 477.96 18.05 o -6 3 2 556.91 547.75 16.73 o -5 3 2 4511.66 4751.20 97.39 o -4 3 2 1583.23 1582.39 45.89 o -3 3 2 19810.84 20657.76 142.11 o -2 3 2 6219.22 6402.91 59.35 o -1 3 2 939.31 967.73 21.18 o 0 3 2 2.70 19.04 3.77 o 1 3 2 3419.86 3360.91 39.01 o 2 3 2 1210.65 1412.73 20.51 o 3 3 2 1048.33 903.66 18.40 o 4 3 2 2574.03 2899.95 52.65 o 5 3 2 91.79 110.66 14.58 o 6 3 2 3240.43 3328.69 44.69 o 7 3 2 1376.89 1350.97 32.63 o 8 3 2 2650.65 2799.28 73.04 o 9 3 2 188.91 192.62 14.36 o -9 4 2 102.59 135.33 21.75 o -8 4 2 161.49 164.74 9.19 o -7 4 2 1144.62 1176.36 29.18 o -6 4 2 246.22 226.11 11.74 o -5 4 2 321.62 339.27 14.80 o -4 4 2 502.00 550.29 32.93 o -3 4 2 314.33 399.36 14.20 o -2 4 2 836.74 795.50 23.46 o -1 4 2 104.24 123.61 18.52 o 0 4 2 16.46 12.24 4.41 o 1 4 2 438.58 533.23 18.21 o 2 4 2 4763.25 4571.77 54.75 o 3 4 2 5052.68 5168.03 49.99 o 4 4 2 411.99 435.79 27.56 o 5 4 2 11573.85 12051.25 194.62 o 6 4 2 223.32 197.28 10.30 o 7 4 2 2358.58 2367.47 37.62 o 8 4 2 278.21 296.07 21.57 o 9 4 2 0.54 4.53 3.95 o -9 5 2 448.32 650.24 31.18 o -8 5 2 99.53 88.64 7.31 o -7 5 2 182.77 184.76 12.34 o -6 5 2 201.95 200.41 12.12 o -5 5 2 6.01 4.57 8.65 o -4 5 2 104.64 135.68 12.99 o -3 5 2 137.06 145.09 12.65 o -2 5 2 450.79 457.11 32.74 o -1 5 2 693.98 839.04 28.04 o 0 5 2 1204.09 1146.98 39.63 o 1 5 2 7184.35 7712.33 97.81 o 2 5 2 1291.42 1232.36 22.78 o 3 5 2 472.19 463.88 18.70 o 4 5 2 8626.37 9037.96 333.40 o 5 5 2 393.62 396.03 12.34 o 6 5 2 73.92 85.11 6.94 o 7 5 2 1217.54 1248.76 30.44 o 8 5 2 6.67 5.52 5.48 o -8 6 2 8.67 11.00 3.92 o -7 6 2 76.01 57.92 7.62 o -6 6 2 98.94 97.05 8.03 o -5 6 2 792.03 772.34 19.82 o -4 6 2 57.67 78.49 6.00 o -3 6 2 1291.19 1351.41 41.79 o -2 6 2 2567.88 2846.61 72.40 o -1 6 2 1013.50 1002.64 30.20 o 0 6 2 3494.17 3884.25 58.73 o 1 6 2 846.95 973.97 29.19 o 2 6 2 1595.15 1729.76 41.87 o 3 6 2 158.53 145.90 17.29 o 4 6 2 6129.95 6215.24 100.16 o 5 6 2 410.77 434.88 15.08 o 6 6 2 3795.68 3740.24 47.65 o 7 6 2 226.33 226.72 12.64 o 8 6 2 24.18 41.13 7.20 o -8 7 2 204.98 212.45 24.11 o -7 7 2 1545.84 1581.17 42.49 o -6 7 2 508.13 484.60 16.15 o -5 7 2 2687.71 2753.44 46.85 o -4 7 2 1447.15 1386.72 29.36 o -3 7 2 197.15 194.45 9.67 o -2 7 2 0.16 15.51 4.23 o -1 7 2 1910.37 1928.41 65.73 o 0 7 2 456.28 481.26 33.00 o 1 7 2 508.23 528.65 34.30 o 2 7 2 2662.85 2722.96 47.81 o 3 7 2 759.87 741.33 18.36 o 4 7 2 982.06 1015.09 24.39 o 5 7 2 663.21 701.86 21.06 o 6 7 2 1335.49 1335.13 33.93 o 7 7 2 2278.82 2206.81 42.43 o 8 7 2 589.17 585.60 37.35 o -7 8 2 46.71 43.22 9.43 o -6 8 2 18.68 11.23 4.53 o -5 8 2 539.15 563.43 19.73 o -4 8 2 17.64 14.32 5.58 o -3 8 2 347.48 399.92 16.30 o -2 8 2 1482.86 1540.22 31.67 o -1 8 2 4353.61 4448.01 62.63 o 0 8 2 10104.81 10475.00 102.26 o 1 8 2 2143.58 2224.96 58.66 o 2 8 2 27.45 29.20 5.76 o 3 8 2 2585.39 2611.40 42.46 o 4 8 2 4.38 8.71 4.77 o 5 8 2 993.54 1081.47 28.77 o 6 8 2 343.53 302.10 15.53 o 7 8 2 0.14 2.41 5.01 o -6 9 2 1706.42 1699.27 110.43 o -5 9 2 0.12 -2.62 5.13 o -4 9 2 7973.33 8355.87 92.74 o -3 9 2 262.97 264.50 12.62 o -2 9 2 335.93 348.20 18.08 o -1 9 2 63.68 65.82 9.59 o 0 9 2 551.24 548.19 22.52 o 1 9 2 292.48 332.31 22.93 o 2 9 2 854.66 857.03 29.37 o 3 9 2 6.15 6.56 4.65 o 4 9 2 6265.97 6490.00 92.39 o 5 9 2 158.27 165.51 14.98 o 6 9 2 54.18 50.18 5.85 o -5 10 2 409.20 422.58 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