#------------------------------------------------------------------------------ #$Date: 2016-04-03 06:50:05 +0300 (Sun, 03 Apr 2016) $ #$Revision: 181298 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/23/76/2237672.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2237672_Fobs loop_ _publ_author_name 'Fl\"orke, Ulrich' 'Ahmida, Aziza' 'Schr\"oder, J\"org' 'Egold, Hans' 'Henkel, Gerald' _publ_section_title ; Dichloridobis(1,3-diisopropyl-4,5-dimethyl-1H-imidazol-3-ium-2-thiolate-\kS)copper(II) ; _journal_coeditor_code NC2307 _journal_issue 4 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first m211 _journal_volume 69 _journal_year 2013 _space_group_IT_number 60 _symmetry_space_group_name_Hall '-P 2n 2ab' _symmetry_space_group_name_H-M 'P b c n' _cell_angle_alpha 90.000 _cell_angle_beta 90.000 _cell_angle_gamma 90.000 _cell_length_a 14.0663 _cell_length_b 13.1359 _cell_length_c 14.9278 _exptl_crystal_F_000 1180.00 _reflns_d_resolution_high 0.7510 _cod_data_source_file nc2307Isup2.hkl _cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' C22 H40 Cl2 Cu N4 S2 in Pbcn' _shelx_refln_list_code 4 _shelx_f_calc_maximum 320.62 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x+1/2, -y+1/2, z+1/2' '-x, y, -z+1/2' 'x+1/2, -y+1/2, -z' '-x, -y, -z' 'x-1/2, y-1/2, -z-1/2' 'x, -y, z-1/2' '-x-1/2, y-1/2, z' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 102797.45 118241.48 3195.80 o 4 0 0 1358.91 1809.61 59.54 o 6 0 0 571.90 555.27 38.29 o 8 0 0 308.11 268.92 36.52 o 10 0 0 466.25 625.42 54.35 o 12 0 0 3807.96 3790.30 244.48 o 14 0 0 12733.60 12594.68 663.33 o 16 0 0 4168.54 4345.06 382.98 o 18 0 0 96.71 221.75 128.30 o 1 1 0 740.13 965.79 23.53 o 3 1 0 8425.84 9171.57 385.13 o 5 1 0 269.22 257.12 18.01 o 7 1 0 11357.40 11747.19 208.28 o 9 1 0 1176.24 1217.07 49.03 o 11 1 0 318.83 301.69 30.76 o 13 1 0 121.32 149.06 56.20 o 15 1 0 3161.39 3234.06 226.25 o 17 1 0 249.21 315.07 98.80 o 0 2 0 57337.55 66672.09 1799.63 o 2 2 0 42006.79 49381.14 772.52 o 4 2 0 618.64 558.71 23.92 o 6 2 0 1662.71 1940.27 60.18 o 8 2 0 205.80 196.87 23.64 o 10 2 0 31.46 66.86 20.29 o 12 2 0 924.95 951.70 69.42 o 14 2 0 2568.38 2370.07 253.30 o 16 2 0 2640.13 2753.86 217.52 o 18 2 0 348.09 444.16 111.66 o 1 3 0 28089.56 31537.05 549.94 o 3 3 0 12703.23 13934.84 232.20 o 5 3 0 9092.52 9703.32 188.04 o 7 3 0 7740.49 6946.13 138.90 o 9 3 0 4402.19 4332.24 106.94 o 11 3 0 440.23 452.93 42.89 o 13 3 0 3310.31 3328.86 208.29 o 15 3 0 4036.92 3942.23 245.84 o 17 3 0 1123.93 971.14 140.99 o 0 4 0 305.66 253.43 42.94 o 2 4 0 4238.69 4521.04 86.29 o 4 4 0 7056.90 7843.35 143.11 o 6 4 0 10030.33 9461.29 239.26 o 8 4 0 19191.52 18646.44 322.03 o 10 4 0 1129.75 1197.85 61.65 o 12 4 0 108.29 56.85 37.45 o 14 4 0 411.59 546.56 74.41 o 16 4 0 492.55 387.54 98.48 o 18 4 0 830.49 699.06 125.86 o 1 5 0 1652.60 1717.58 50.19 o 3 5 0 10567.41 11143.90 193.79 o 5 5 0 4728.35 4295.66 91.51 o 7 5 0 324.78 403.42 42.57 o 9 5 0 486.77 436.48 44.02 o 11 5 0 7579.59 7471.36 205.45 o 13 5 0 2236.50 2270.03 113.76 o 15 5 0 3.37 42.65 68.42 o 17 5 0 434.42 339.62 291.50 o 0 6 0 4862.16 5161.40 268.77 o 2 6 0 1498.94 1542.43 53.41 o 4 6 0 7859.13 8066.62 151.36 o 6 6 0 14802.36 14712.35 259.31 o 8 6 0 16908.54 16304.38 316.51 o 10 6 0 6602.02 6115.26 153.77 o 12 6 0 1025.22 976.42 77.15 o 14 6 0 474.68 455.15 70.94 o 16 6 0 41.11 46.97 94.36 o 1 7 0 2189.81 2283.97 86.18 o 3 7 0 1585.16 1511.01 89.09 o 5 7 0 894.07 1019.18 45.53 o 7 7 0 5022.04 4980.51 111.93 o 9 7 0 816.11 742.98 57.14 o 11 7 0 185.67 161.16 48.04 o 13 7 0 9.39 35.31 38.12 o 15 7 0 71.52 88.12 68.75 o 17 7 0 3.35 108.49 118.63 o 0 8 0 1191.92 853.20 325.28 o 2 8 0 463.94 474.59 34.17 o 4 8 0 14266.05 13643.53 275.54 o 6 8 0 1104.85 1134.61 57.52 o 8 8 0 2149.26 2182.81 98.86 o 10 8 0 7064.28 6649.60 223.11 o 12 8 0 1535.44 1712.71 125.17 o 14 8 0 252.45 194.87 130.44 o 16 8 0 4.14 -61.06 64.58 o 1 9 0 2108.88 2038.92 91.41 o 3 9 0 6628.58 6340.79 149.91 o 5 9 0 4675.97 4620.16 124.57 o 7 9 0 1458.60 1490.66 85.57 o 9 9 0 514.10 538.11 58.64 o 11 9 0 3101.68 2651.21 268.05 o 13 9 0 328.72 374.19 73.17 o 15 9 0 77.34 141.61 77.19 o 2 10 0 785.79 767.27 61.77 o 4 10 0 1.14 -4.20 25.07 o 6 10 0 1985.05 2046.31 85.82 o 8 10 0 2594.12 2704.11 151.73 o 10 10 0 701.80 837.23 89.85 o 12 10 0 511.52 391.86 201.01 o 14 10 0 819.79 896.93 105.50 o 1 11 0 2367.89 2331.48 191.49 o 3 11 0 2826.96 2916.23 120.67 o 5 11 0 1128.99 1167.10 79.45 o 7 11 0 81.49 98.12 45.86 o 9 11 0 1284.43 1279.64 90.59 o 11 11 0 1963.90 1972.76 143.00 o 13 11 0 929.22 788.55 132.35 o 0 12 0 384.75 197.53 272.71 o 2 12 0 2898.79 2603.97 120.35 o 4 12 0 3664.40 3671.17 174.67 o 6 12 0 152.65 187.31 67.05 o 8 12 0 1895.85 1953.65 135.56 o 10 12 0 703.65 834.82 130.80 o 12 12 0 1941.79 1863.77 185.20 o 1 13 0 586.91 594.07 65.54 o 3 13 0 550.37 562.26 64.68 o 5 13 0 20.72 50.67 47.99 o 7 13 0 648.43 706.44 106.59 o 9 13 0 203.72 293.89 84.38 o 11 13 0 116.10 195.77 83.35 o 0 14 0 694.36 450.86 450.24 o 2 14 0 1658.22 1647.75 109.11 o 4 14 0 1030.12 1021.60 155.65 o 6 14 0 12.19 105.99 57.70 o 8 14 0 21.95 39.25 59.55 o 10 14 0 82.17 79.63 116.30 o 1 15 0 174.97 94.49 46.53 o 3 15 0 428.97 495.18 79.19 o 5 15 0 66.47 85.70 61.15 o 7 15 0 3.79 87.10 61.80 o 9 15 0 254.67 404.21 168.52 o 0 16 0 2604.98 2449.52 201.18 o 2 16 0 305.79 593.24 136.96 o 4 16 0 169.57 265.86 92.95 o 6 16 0 74.71 47.78 91.72 o 1 17 0 1922.91 1644.82 215.51 o 3 17 0 132.46 70.14 63.98 o 1 1 1 30829.09 37050.63 472.96 o 3 1 1 3891.64 4347.89 64.45 o 4 1 1 3421.36 3765.16 51.70 o 5 1 1 1010.32 951.62 22.42 o 6 1 1 1061.53 1159.02 26.83 o 7 1 1 4397.18 4070.68 62.40 o 8 1 1 2377.27 2537.18 46.45 o 9 1 1 1323.63 1295.95 34.65 o 10 1 1 3177.12 3074.85 57.20 o 11 1 1 474.36 539.93 28.87 o 12 1 1 419.57 388.57 34.44 o 13 1 1 3602.06 3786.58 176.72 o 14 1 1 91.98 170.97 47.07 o 15 1 1 3841.47 3913.70 175.50 o 16 1 1 131.71 165.08 70.14 o 17 1 1 195.30 180.53 61.03 o 18 1 1 551.83 636.22 89.61 o 0 2 1 4440.05 5372.16 231.89 o 1 2 1 8585.10 9864.09 119.22 o 2 2 1 688.47 717.75 15.89 o 3 2 1 230.99 278.14 12.58 o 4 2 1 7.78 17.22 5.98 o 5 2 1 421.04 406.67 16.43 o 6 2 1 12878.77 13057.26 174.22 o 7 2 1 116.22 147.13 13.11 o 8 2 1 16635.93 16406.38 210.84 o 9 2 1 239.63 256.18 18.66 o 10 2 1 24.42 22.69 14.62 o 11 2 1 14.60 10.42 17.70 o 12 2 1 105.26 102.67 21.33 o 13 2 1 809.28 855.83 53.85 o 14 2 1 3033.74 3265.41 130.71 o 15 2 1 386.99 287.70 58.79 o 16 2 1 1046.02 1209.54 102.75 o 17 2 1 32.29 108.42 55.10 o 18 2 1 5.32 -34.63 57.33 o 1 3 1 2.09 0.96 4.71 o 2 3 1 7954.56 9297.13 111.94 o 3 3 1 32971.90 37209.90 458.36 o 4 3 1 1780.89 1947.47 33.40 o 5 3 1 59.09 80.78 8.92 o 6 3 1 84.66 133.02 11.32 o 7 3 1 5235.84 5341.22 77.56 o 8 3 1 2814.68 2961.90 56.08 o 9 3 1 120.71 95.97 15.75 o 10 3 1 2155.87 2102.71 50.44 o 11 3 1 250.98 285.29 25.70 o 12 3 1 2526.24 2457.43 76.36 o 13 3 1 566.44 559.19 44.60 o 14 3 1 103.44 71.75 32.68 o 15 3 1 409.87 421.97 57.30 o 16 3 1 633.46 575.48 78.41 o 17 3 1 431.76 401.78 95.05 o 18 3 1 247.30 215.08 64.14 o 0 4 1 13871.93 14530.54 260.72 o 1 4 1 338.01 448.35 15.29 o 2 4 1 2246.21 2133.89 34.61 o 3 4 1 12476.13 13832.92 164.98 o 4 4 1 2781.70 2436.06 42.23 o 5 4 1 0.08 8.23 7.90 o 6 4 1 8556.70 8533.72 112.86 o 7 4 1 269.52 335.57 17.41 o 8 4 1 2912.08 2704.25 49.73 o 9 4 1 44.11 82.74 15.12 o 10 4 1 2463.61 2376.06 55.57 o 11 4 1 3.24 -10.56 17.97 o 12 4 1 2528.19 2482.85 100.51 o 13 4 1 23.50 1.82 24.93 o 14 4 1 634.13 618.78 56.04 o 15 4 1 0.01 -4.43 36.41 o 16 4 1 555.26 611.61 79.30 o 17 4 1 194.61 224.37 95.95 o 18 4 1 474.28 428.27 104.43 o 1 5 1 3968.63 4085.30 68.50 o 2 5 1 1917.97 1815.87 31.85 o 3 5 1 226.69 282.40 14.31 o 4 5 1 397.06 420.88 17.81 o 5 5 1 1760.27 1667.96 35.50 o 6 5 1 1773.62 1962.15 41.72 o 7 5 1 11636.24 11041.61 143.85 o 8 5 1 156.65 134.75 14.56 o 9 5 1 2652.89 2472.33 54.77 o 10 5 1 1356.02 1362.13 57.61 o 11 5 1 14.73 19.45 19.15 o 12 5 1 907.39 898.27 51.05 o 13 5 1 58.58 74.39 29.12 o 14 5 1 0.46 -26.51 27.95 o 15 5 1 101.38 65.49 36.62 o 16 5 1 899.78 949.20 80.16 o 17 5 1 16.97 32.48 48.36 o 0 6 1 490.99 493.26 28.06 o 1 6 1 629.84 654.28 35.96 o 2 6 1 1730.61 1687.97 39.98 o 3 6 1 807.57 966.71 25.11 o 4 6 1 6375.29 6305.77 87.88 o 5 6 1 478.96 607.03 23.30 o 6 6 1 95.34 87.90 13.39 o 7 6 1 154.88 159.01 15.41 o 8 6 1 82.69 84.46 16.30 o 9 6 1 1208.53 1277.66 50.89 o 10 6 1 2762.19 2711.41 71.86 o 11 6 1 471.11 468.59 34.44 o 12 6 1 1443.49 1474.23 64.79 o 13 6 1 99.36 82.53 28.14 o 14 6 1 136.06 142.18 35.14 o 15 6 1 1.08 -22.33 39.54 o 16 6 1 48.42 42.90 39.53 o 17 6 1 212.34 150.49 57.40 o 1 7 1 451.05 531.26 24.02 o 2 7 1 380.40 451.70 23.33 o 3 7 1 6585.71 6201.22 105.41 o 4 7 1 133.19 95.49 11.95 o 5 7 1 11629.66 11170.75 145.25 o 6 7 1 229.47 222.41 17.33 o 7 7 1 5417.91 5222.16 81.62 o 8 7 1 845.24 892.76 36.94 o 9 7 1 4759.32 4528.68 87.55 o 10 7 1 190.52 190.06 28.23 o 11 7 1 4099.89 3904.55 98.06 o 12 7 1 213.20 245.32 33.47 o 13 7 1 124.23 133.73 32.31 o 14 7 1 0.89 9.80 41.12 o 15 7 1 264.82 224.26 58.35 o 16 7 1 28.19 80.64 52.52 o 17 7 1 188.18 345.44 130.91 o 0 8 1 1871.23 1766.32 105.80 o 1 8 1 32.09 30.74 11.03 o 2 8 1 1382.13 1307.18 38.80 o 3 8 1 47.36 47.84 13.81 o 4 8 1 1066.85 1015.63 37.87 o 5 8 1 45.71 73.81 14.62 o 6 8 1 500.52 505.67 26.23 o 7 8 1 100.17 95.84 17.45 o 8 8 1 8.11 -18.42 18.81 o 9 8 1 153.44 102.57 27.67 o 10 8 1 141.23 157.92 30.70 o 11 8 1 79.66 43.48 28.64 o 12 8 1 383.00 382.21 47.11 o 13 8 1 24.80 41.31 35.53 o 14 8 1 83.30 94.20 44.88 o 15 8 1 24.27 25.37 47.63 o 16 8 1 1.23 12.30 50.03 o 1 9 1 12.09 24.11 16.02 o 2 9 1 0.14 -1.97 12.67 o 3 9 1 2326.97 2186.28 64.40 o 4 9 1 1144.39 1086.47 41.92 o 5 9 1 5495.00 5249.08 95.59 o 6 9 1 643.52 666.76 35.40 o 7 9 1 1397.85 1419.25 53.99 o 8 9 1 187.19 168.54 27.22 o 9 9 1 1505.08 1480.43 64.00 o 10 9 1 165.28 143.28 31.80 o 11 9 1 2525.82 2596.72 107.49 o 12 9 1 25.90 13.69 34.63 o 13 9 1 45.29 41.74 37.65 o 14 9 1 127.84 161.06 49.43 o 15 9 1 392.45 350.28 65.91 o 16 9 1 7.57 11.61 50.44 o 0 10 1 462.88 548.92 77.89 o 1 10 1 13.99 1.10 16.89 o 2 10 1 3019.53 2773.41 93.67 o 3 10 1 8.98 47.99 20.57 o 4 10 1 9689.24 9330.25 170.56 o 5 10 1 34.99 22.76 18.24 o 6 10 1 916.86 904.06 45.30 o 7 10 1 46.03 46.96 23.00 o 8 10 1 961.55 898.45 51.36 o 9 10 1 0.12 -7.25 23.87 o 10 10 1 3193.48 3164.73 117.02 o 11 10 1 33.29 26.98 34.21 o 12 10 1 1035.74 1175.67 79.23 o 13 10 1 148.98 156.98 41.33 o 14 10 1 18.19 -23.96 40.50 o 15 10 1 31.83 32.63 56.21 o 1 11 1 391.04 332.95 32.68 o 2 11 1 245.03 269.21 30.81 o 3 11 1 809.70 829.79 47.77 o 4 11 1 22.67 19.94 26.18 o 5 11 1 2.85 32.27 23.88 o 6 11 1 192.46 243.66 37.18 o 7 11 1 1438.84 1327.90 85.73 o 8 11 1 81.70 86.93 37.49 o 9 11 1 191.23 149.19 33.63 o 10 11 1 67.02 19.74 32.27 o 11 11 1 695.97 741.97 64.44 o 12 11 1 45.49 47.08 39.29 o 13 11 1 361.47 293.54 52.24 o 14 11 1 79.63 142.79 50.76 o 0 12 1 1905.43 1755.74 100.07 o 1 12 1 197.42 173.20 28.63 o 2 12 1 2113.40 2147.60 117.35 o 3 12 1 16.87 13.60 22.91 o 4 12 1 979.89 1000.25 55.67 o 5 12 1 56.13 5.84 26.07 o 6 12 1 383.98 436.62 49.12 o 7 12 1 57.70 28.53 31.95 o 8 12 1 938.93 977.33 70.54 o 9 12 1 14.57 35.18 37.83 o 10 12 1 771.11 904.79 89.53 o 11 12 1 36.55 2.70 44.74 o 12 12 1 208.75 268.08 63.43 o 13 12 1 186.98 199.43 59.44 o 1 13 1 1186.61 1298.07 64.88 o 2 13 1 2063.25 1995.90 78.79 o 3 13 1 2312.66 2236.05 84.35 o 4 13 1 500.40 430.63 44.51 o 5 13 1 830.73 930.15 69.06 o 6 13 1 8.97 40.68 33.34 o 7 13 1 4.40 -22.10 32.51 o 8 13 1 0.60 28.55 37.57 o 9 13 1 257.48 319.13 58.38 o 10 13 1 3.31 -21.74 46.58 o 11 13 1 922.96 841.90 93.22 o 12 13 1 382.77 490.66 78.73 o 0 14 1 619.75 690.44 113.03 o 1 14 1 4.02 49.25 29.41 o 2 14 1 32.23 83.57 31.67 o 3 14 1 0.09 7.58 30.78 o 4 14 1 431.60 379.85 50.42 o 5 14 1 131.07 168.10 42.78 o 6 14 1 191.71 170.23 44.19 o 7 14 1 2.48 22.51 39.25 o 8 14 1 350.47 236.91 56.39 o 9 14 1 7.42 6.27 48.88 o 10 14 1 66.24 59.68 53.20 o 11 14 1 11.26 64.45 56.82 o 1 15 1 1582.48 1695.51 86.57 o 2 15 1 271.82 264.24 41.29 o 3 15 1 403.80 315.78 46.30 o 4 15 1 469.79 529.07 58.49 o 5 15 1 152.29 144.79 44.75 o 6 15 1 50.79 47.30 41.82 o 7 15 1 882.32 1022.37 80.09 o 8 15 1 22.28 23.28 47.31 o 9 15 1 395.50 464.97 77.84 o 0 16 1 1054.80 1213.07 143.86 o 1 16 1 73.83 72.04 33.47 o 2 16 1 482.41 543.74 55.77 o 3 16 1 261.36 249.48 63.34 o 4 16 1 179.82 117.82 59.53 o 5 16 1 0.37 15.73 44.66 o 6 16 1 158.14 196.06 50.93 o 7 16 1 11.70 16.87 52.76 o 1 17 1 429.82 334.37 54.65 o 2 17 1 29.12 80.94 45.30 o 3 17 1 29.43 66.49 45.32 o 4 17 1 40.68 75.01 47.80 o 0 0 2 104.37 114.46 14.64 o 1 0 2 895.19 959.82 24.91 o 2 0 2 39.57 57.15 9.79 o 3 0 2 2499.68 2726.80 55.17 o 4 0 2 199.87 319.85 17.43 o 5 0 2 3294.29 3238.29 73.77 o 6 0 2 18947.45 19007.69 316.62 o 7 0 2 1742.67 1800.33 50.98 o 8 0 2 6335.37 5798.69 118.16 o 9 0 2 1558.58 1412.47 74.83 o 10 0 2 2817.89 2658.49 83.28 o 11 0 2 2273.21 2084.37 80.29 o 12 0 2 1717.62 1795.46 92.66 o 13 0 2 970.92 985.26 74.32 o 14 0 2 1762.47 1806.66 165.02 o 15 0 2 926.46 778.51 191.97 o 16 0 2 1686.58 1733.72 179.62 o 17 0 2 5.94 110.26 79.94 o 18 0 2 35.19 157.50 100.37 o 1 1 2 4734.68 5723.51 72.77 o 2 1 2 2736.87 2825.95 44.92 o 3 1 2 1379.73 1664.22 30.28 o 4 1 2 9017.85 10231.85 130.07 o 5 1 2 3.39 4.06 6.07 o 6 1 2 3946.34 4097.90 59.88 o 7 1 2 4783.19 4554.21 67.28 o 8 1 2 959.29 985.93 27.90 o 9 1 2 2466.67 2413.20 47.66 o 10 1 2 1752.59 1795.97 53.57 o 11 1 2 520.35 529.72 34.08 o 12 1 2 325.96 317.14 29.90 o 13 1 2 1005.89 1003.17 52.62 o 14 1 2 247.26 203.41 42.53 o 15 1 2 499.33 585.72 73.32 o 16 1 2 90.37 162.78 53.00 o 17 1 2 31.01 97.98 57.11 o 18 1 2 38.38 65.90 59.29 o 0 2 2 24.33 32.50 11.45 o 1 2 2 11021.70 12718.90 153.48 o 2 2 2 820.37 1005.66 19.95 o 3 2 2 8808.58 9893.52 124.66 o 4 2 2 5769.44 6260.50 89.45 o 5 2 2 864.56 893.58 26.86 o 6 2 2 1143.05 971.23 27.27 o 7 2 2 265.26 283.79 15.15 o 8 2 2 2444.42 2238.80 43.58 o 9 2 2 1768.69 1718.40 39.71 o 10 2 2 2245.99 2226.72 56.11 o 11 2 2 3067.81 2983.27 68.39 o 12 2 2 1668.47 1625.71 58.13 o 13 2 2 878.80 855.21 54.41 o 14 2 2 876.08 937.37 111.38 o 15 2 2 138.35 76.24 38.04 o 16 2 2 130.10 67.95 48.44 o 17 2 2 379.25 551.98 79.30 o 18 2 2 285.40 302.08 71.81 o 1 3 2 28939.30 32970.60 369.55 o 2 3 2 10010.74 10934.86 142.41 o 3 3 2 119.61 98.31 8.43 o 4 3 2 231.96 291.04 14.98 o 5 3 2 249.63 185.34 13.48 o 6 3 2 634.31 640.35 26.98 o 7 3 2 13418.32 13427.77 176.37 o 8 3 2 536.91 540.45 27.11 o 9 3 2 2221.45 2032.20 52.43 o 10 3 2 52.34 32.60 16.77 o 11 3 2 373.09 358.36 28.03 o 12 3 2 945.25 929.09 50.24 o 13 3 2 1905.70 1916.30 79.69 o 14 3 2 287.37 311.41 49.41 o 15 3 2 1532.02 1579.50 98.66 o 16 3 2 160.66 222.64 57.17 o 17 3 2 5.60 0.11 49.76 o 18 3 2 135.64 175.35 70.30 o 0 4 2 11627.22 12477.08 209.42 o 1 4 2 18343.81 20439.00 235.35 o 2 4 2 620.22 658.71 21.91 o 3 4 2 17734.63 18897.19 220.80 o 4 4 2 174.45 168.44 11.04 o 5 4 2 32.16 25.98 9.84 o 6 4 2 745.95 676.10 26.03 o 7 4 2 1.50 7.12 10.84 o 8 4 2 757.17 756.17 36.24 o 9 4 2 346.40 320.71 22.38 o 10 4 2 648.82 666.57 34.64 o 11 4 2 2775.18 2738.51 67.28 o 12 4 2 1459.25 1521.57 105.37 o 13 4 2 1601.67 1557.42 88.37 o 14 4 2 202.57 190.95 36.25 o 15 4 2 29.27 18.32 36.00 o 16 4 2 468.59 546.65 67.53 o 17 4 2 1031.52 934.25 103.00 o 18 4 2 41.14 131.43 77.59 o 1 5 2 4382.85 4183.38 59.15 o 2 5 2 1171.14 1418.85 32.40 o 3 5 2 10101.61 10119.43 127.33 o 4 5 2 352.43 441.43 18.79 o 5 5 2 7323.88 7509.70 110.19 o 6 5 2 114.96 107.05 14.40 o 7 5 2 670.00 775.66 30.75 o 8 5 2 1126.08 1122.92 37.51 o 9 5 2 1570.12 1643.23 46.38 o 10 5 2 1771.45 1775.14 54.63 o 11 5 2 3536.39 3179.09 79.86 o 12 5 2 62.81 88.00 25.18 o 13 5 2 186.96 218.03 37.86 o 14 5 2 118.68 90.45 31.85 o 15 5 2 89.74 93.96 42.07 o 16 5 2 28.06 70.21 42.91 o 17 5 2 519.45 206.22 143.41 o 0 6 2 3974.20 3894.99 99.06 o 1 6 2 1880.09 1875.45 36.85 o 2 6 2 6411.80 6276.93 84.97 o 3 6 2 7220.59 6915.75 93.61 o 4 6 2 8676.82 8321.55 110.82 o 5 6 2 4935.23 4802.78 73.11 o 6 6 2 719.53 784.93 28.14 o 7 6 2 519.32 487.12 26.00 o 8 6 2 1499.71 1488.86 44.53 o 9 6 2 1058.57 994.55 37.90 o 10 6 2 262.07 278.89 34.73 o 11 6 2 3460.90 3336.25 94.24 o 12 6 2 185.46 180.06 29.38 o 13 6 2 1119.04 1152.64 66.57 o 14 6 2 755.77 819.14 58.79 o 15 6 2 0.72 -22.62 35.80 o 16 6 2 455.14 511.96 64.76 o 17 6 2 303.34 292.86 59.08 o 1 7 2 1320.46 1239.31 35.12 o 2 7 2 975.82 1022.41 29.35 o 3 7 2 4154.94 4187.09 64.47 o 4 7 2 139.15 169.41 14.98 o 5 7 2 1159.72 1332.42 34.98 o 6 7 2 33.83 36.07 13.05 o 7 7 2 64.71 44.58 14.90 o 8 7 2 475.32 516.19 30.51 o 9 7 2 1355.37 1352.27 52.81 o 10 7 2 80.41 70.89 23.47 o 11 7 2 29.61 65.28 22.62 o 12 7 2 135.54 172.31 30.33 o 13 7 2 202.12 153.07 35.54 o 14 7 2 7.05 25.98 34.00 o 15 7 2 26.43 57.95 43.70 o 16 7 2 112.65 114.14 53.29 o 17 7 2 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5.87 44.23 o 1 9 5 3488.79 3169.41 67.25 o 2 9 5 3667.02 3348.41 70.63 o 3 9 5 3309.57 3108.29 69.08 o 4 9 5 998.89 1042.00 42.44 o 5 9 5 1700.15 1638.10 57.74 o 6 9 5 0.73 22.42 19.74 o 7 9 5 321.28 225.44 33.59 o 8 9 5 705.68 625.77 44.42 o 9 9 5 5.57 -12.82 23.17 o 10 9 5 2.32 40.82 29.61 o 11 9 5 19.15 11.33 29.68 o 12 9 5 2631.15 2608.21 114.41 o 13 9 5 748.37 808.55 75.92 o 14 9 5 338.08 456.26 61.15 o 15 9 5 1222.11 1283.27 99.11 o 0 10 5 8911.84 8062.01 254.12 o 1 10 5 1530.06 1611.66 63.96 o 2 10 5 4399.47 4179.46 99.27 o 3 10 5 613.02 589.52 39.95 o 4 10 5 1577.90 1659.33 59.56 o 5 10 5 439.53 468.23 35.67 o 6 10 5 803.24 791.02 44.60 o 7 10 5 16.05 38.27 24.05 o 8 10 5 512.27 662.37 51.21 o 9 10 5 532.61 588.78 56.47 o 10 10 5 653.96 725.79 57.40 o 11 10 5 0.23 71.28 34.83 o 12 10 5 939.51 1057.02 78.12 o 13 10 5 275.78 226.32 53.01 o 14 10 5 364.15 519.56 68.56 o 1 11 5 1127.76 1088.01 56.48 o 2 11 5 24.86 20.23 21.50 o 3 11 5 621.06 605.39 48.93 o 4 11 5 404.49 474.26 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14 626.49 811.28 69.02 o 1 3 14 2390.12 2342.83 69.31 o 2 3 14 767.87 785.77 39.61 o 3 3 14 262.65 254.96 32.33 o 4 3 14 4.93 23.94 20.12 o 5 3 14 478.24 564.50 43.27 o 6 3 14 266.56 318.74 35.63 o 7 3 14 1474.89 1486.38 69.17 o 8 3 14 15.21 -2.17 27.75 o 9 3 14 577.19 634.42 61.65 o 10 3 14 107.83 69.01 37.41 o 11 3 14 392.36 307.15 77.31 o 12 3 14 283.51 290.74 47.89 o 0 4 14 144.32 116.70 31.71 o 1 4 14 1208.41 1255.25 49.76 o 2 4 14 49.92 25.29 20.34 o 3 4 14 1466.79 1460.48 56.68 o 4 4 14 81.13 44.59 22.77 o 5 4 14 203.65 221.24 31.68 o 6 4 14 412.75 439.06 40.06 o 7 4 14 163.75 161.72 32.42 o 8 4 14 335.52 397.84 42.96 o 9 4 14 0.58 17.85 31.64 o 10 4 14 30.86 68.93 36.16 o 11 4 14 603.69 756.71 63.76 o 12 4 14 87.51 83.31 41.58 o 1 5 14 457.29 512.00 35.12 o 2 5 14 180.88 219.22 26.03 o 3 5 14 1130.56 1095.95 53.41 o 4 5 14 5.40 -15.93 25.17 o 5 5 14 989.27 976.43 55.21 o 6 5 14 64.93 58.18 27.39 o 7 5 14 695.96 682.00 49.70 o 8 5 14 145.65 207.24 36.52 o 9 5 14 460.73 445.23 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