#------------------------------------------------------------------------------ #$Date: 2016-04-03 06:52:24 +0300 (Sun, 03 Apr 2016) $ #$Revision: 181305 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/23/83/2238354.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2238354_Fobs loop_ _publ_author_name 'Walker, Ashley' 'Forsyth, Craig M.' 'Perlmutter, Patrick' _publ_section_title ; 2-(10',10'-Dimethyl-3'-sulfanylidene-4'-azatricyclo[5.2.1.0^1,5^]decan-2'-yl)-10,10-dimethyl-4-azatricyclo[5.2.1.0^1,5^]decane-3-thione ; _journal_coeditor_code GW2136 _journal_issue 8 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first o1282 _journal_volume 69 _journal_year 2013 _space_group_IT_number 92 _symmetry_space_group_name_Hall 'P 4abw 2nw' _symmetry_space_group_name_H-M 'P 41 21 2' _cell_angle_alpha 90.000 _cell_angle_beta 90.000 _cell_angle_gamma 90.000 _cell_length_a 13.8159 _cell_length_b 13.8159 _cell_length_c 13.5221 _exptl_crystal_F_000 1080.00 _reflns_d_resolution_high 0.7076 _cod_data_source_file gw2136Isup2.hkl _cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' awtpr in P4(1)2(1)2' _shelx_refln_list_code 4 _shelx_f_calc_maximum 231.14 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-y+1/2, x+1/2, z+1/4' '-x, -y, z+1/2' 'y+1/2, -x+1/2, z+3/4' 'x+1/2, -y+1/2, -z+3/4' '-x+1/2, y+1/2, -z+1/4' 'y, x, -z' '-y, -x, -z+1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 0 2 0 661.70 637.46 10.35 o 1 2 0 8831.02 8772.11 37.45 o 2 2 0 45954.62 44604.66 216.25 o 1 3 0 209.91 165.84 8.20 o 2 3 0 2772.08 2792.80 27.23 o 3 3 0 395.30 432.03 18.78 o 0 4 0 1216.58 1333.33 19.02 o 1 4 0 637.41 613.88 10.38 o 2 4 0 673.16 630.74 17.06 o 3 4 0 1613.78 1562.29 29.27 o 4 4 0 1066.50 1055.30 30.49 o 1 5 0 9.76 15.78 4.64 o 2 5 0 452.21 487.82 13.40 o 3 5 0 971.48 1131.76 24.84 o 4 5 0 5568.78 5233.97 55.50 o 5 5 0 581.81 541.17 27.79 o 0 6 0 206.86 218.99 10.85 o 1 6 0 31.15 20.76 7.60 o 2 6 0 2337.46 2439.86 36.14 o 3 6 0 797.46 811.53 20.01 o 4 6 0 1381.11 1424.70 30.50 o 5 6 0 433.07 441.39 21.87 o 6 6 0 5508.26 5155.94 129.64 o 1 7 0 6008.63 6372.07 66.81 o 2 7 0 268.70 257.30 15.27 o 3 7 0 4410.13 4297.84 50.84 o 4 7 0 436.26 413.63 15.61 o 5 7 0 1116.62 1110.38 29.42 o 6 7 0 5.94 24.40 6.86 o 7 7 0 1773.48 1535.12 54.99 o 0 8 0 3449.66 3308.55 63.95 o 1 8 0 49.11 83.89 6.26 o 2 8 0 283.69 277.56 15.90 o 3 8 0 3.22 25.51 9.57 o 4 8 0 2.85 22.93 5.16 o 5 8 0 6.19 23.16 5.32 o 6 8 0 315.92 306.67 18.62 o 7 8 0 0.64 13.25 5.58 o 8 8 0 2031.90 2045.27 65.90 o 1 9 0 3760.94 3565.53 44.05 o 2 9 0 1094.78 1143.27 31.58 o 3 9 0 2.34 14.50 5.42 o 4 9 0 233.50 222.83 15.10 o 5 9 0 856.33 827.56 25.36 o 6 9 0 4.11 16.77 5.92 o 7 9 0 934.36 911.22 29.71 o 8 9 0 1339.72 1144.15 36.03 o 9 9 0 221.80 230.60 28.55 o 0 10 0 799.95 855.54 36.05 o 1 10 0 1018.68 1031.29 22.05 o 2 10 0 119.41 127.39 8.55 o 3 10 0 2134.53 2012.96 43.47 o 4 10 0 108.30 114.80 12.38 o 5 10 0 2263.52 2188.79 43.17 o 6 10 0 1099.53 1130.71 31.72 o 7 10 0 351.69 371.42 20.66 o 8 10 0 617.91 609.14 26.15 o 9 10 0 562.47 560.60 26.87 o 10 10 0 773.65 746.17 50.72 o 1 11 0 1032.25 1022.18 31.80 o 2 11 0 2983.11 2738.45 40.25 o 3 11 0 1761.31 1837.23 39.12 o 4 11 0 439.03 467.19 22.37 o 5 11 0 193.14 174.74 15.52 o 6 11 0 692.25 672.45 25.51 o 7 11 0 30.83 41.08 7.56 o 8 11 0 401.57 420.97 22.87 o 9 11 0 3.63 21.68 7.21 o 10 11 0 460.19 490.48 29.34 o 11 11 0 285.50 375.86 40.85 o 0 12 0 18.05 38.09 10.54 o 1 12 0 296.63 288.83 19.98 o 2 12 0 205.32 206.14 17.60 o 3 12 0 670.35 685.80 24.79 o 4 12 0 152.71 182.66 14.76 o 5 12 0 128.60 141.76 14.74 o 6 12 0 1486.67 1382.57 37.70 o 7 12 0 78.63 75.69 11.25 o 8 12 0 1057.57 1039.30 36.20 o 9 12 0 0.00 13.54 5.57 o 10 12 0 82.97 108.28 13.63 o 11 12 0 1028.99 1043.52 39.40 o 12 12 0 52.15 62.58 20.80 o 1 13 0 126.63 164.46 17.37 o 2 13 0 83.61 87.99 11.66 o 3 13 0 1.95 13.86 8.50 o 4 13 0 131.88 179.06 14.83 o 5 13 0 840.09 820.70 27.80 o 6 13 0 26.06 28.09 7.21 o 7 13 0 499.21 591.05 30.03 o 8 13 0 240.66 267.54 23.45 o 9 13 0 632.31 651.57 33.03 o 10 13 0 73.21 85.55 11.49 o 11 13 0 42.75 39.22 11.09 o 12 13 0 85.62 114.98 21.93 o 13 13 0 670.59 750.21 73.25 o 0 14 0 1125.74 1025.30 55.00 o 1 14 0 195.88 200.90 20.20 o 2 14 0 141.25 158.91 16.06 o 3 14 0 158.39 190.04 17.30 o 4 14 0 78.16 102.04 11.46 o 5 14 0 45.79 53.76 10.33 o 6 14 0 219.50 243.27 19.58 o 7 14 0 46.26 70.21 16.26 o 8 14 0 2.87 15.28 9.82 o 9 14 0 1.60 8.33 10.84 o 10 14 0 1.31 16.30 7.58 o 11 14 0 12.23 28.87 9.98 o 12 14 0 47.52 54.04 16.38 o 13 14 0 6.33 2.97 19.23 o 1 15 0 14.23 28.29 5.29 o 2 15 0 8.86 21.18 4.92 o 3 15 0 46.36 49.14 7.20 o 4 15 0 12.11 8.96 13.02 o 5 15 0 0.08 15.38 6.58 o 6 15 0 17.10 26.73 9.44 o 7 15 0 1782.27 1751.67 54.77 o 8 15 0 47.84 44.83 8.43 o 9 15 0 137.79 110.83 20.77 o 10 15 0 0.02 -4.53 16.47 o 11 15 0 45.36 69.04 15.65 o 12 15 0 22.72 47.60 10.73 o 0 16 0 42.15 34.90 16.51 o 1 16 0 104.53 111.25 14.06 o 2 16 0 313.69 310.24 23.80 o 3 16 0 128.48 99.66 12.55 o 4 16 0 25.86 32.14 5.48 o 5 16 0 0.10 24.35 9.29 o 6 16 0 825.13 851.19 37.43 o 7 16 0 40.18 40.25 11.68 o 8 16 0 246.76 220.28 25.17 o 9 16 0 66.08 43.35 11.05 o 10 16 0 0.00 32.42 8.87 o 11 16 0 131.37 102.04 34.30 o 1 17 0 214.31 175.01 18.63 o 2 17 0 17.40 41.73 17.93 o 3 17 0 171.72 136.94 21.50 o 4 17 0 373.12 375.61 32.10 o 5 17 0 93.85 62.69 22.64 o 6 17 0 16.52 41.70 15.01 o 7 17 0 52.99 66.27 12.60 o 8 17 0 249.58 211.73 25.49 o 9 17 0 11.50 5.79 10.13 o 0 18 0 349.05 305.20 66.92 o 1 18 0 81.10 69.77 12.19 o 2 18 0 47.07 91.05 19.05 o 3 18 0 511.88 584.18 47.86 o 4 18 0 5.70 4.54 9.32 o 5 18 0 880.58 909.60 49.75 o 6 18 0 103.30 86.79 13.89 o 7 18 0 295.53 272.00 30.68 o 1 19 0 15.02 34.24 6.49 o 2 19 0 0.11 2.46 8.78 o 3 19 0 12.88 36.82 16.27 o 4 19 0 29.23 68.47 29.29 o 0 1 1 32.59 40.06 2.19 o 1 1 1 1052.74 1097.94 12.93 o -1 2 1 485.23 497.75 8.20 o 0 2 1 2411.64 2351.48 13.76 o 1 2 1 448.22 462.95 8.12 o 2 2 1 8527.78 8317.53 60.10 o -2 3 1 2299.59 2284.69 23.21 o -1 3 1 1801.34 1787.71 13.94 o 0 3 1 5935.16 5796.75 51.20 o 1 3 1 1762.09 1739.72 17.22 o 2 3 1 2289.23 2256.99 23.55 o 3 3 1 3550.65 3354.79 34.02 o -3 4 1 206.83 189.69 9.38 o -2 4 1 403.84 437.21 11.75 o -1 4 1 3503.05 3356.84 24.81 o 0 4 1 2771.21 2767.34 22.10 o 1 4 1 3488.87 3374.36 35.08 o 2 4 1 424.25 466.10 14.29 o 3 4 1 212.44 187.79 11.12 o 4 4 1 6242.02 5885.35 61.44 o -4 5 1 1056.03 1047.55 24.95 o -3 5 1 1953.39 2182.81 32.72 o -2 5 1 814.26 846.05 26.89 o -1 5 1 1326.69 1359.46 18.19 o 0 5 1 9563.02 9146.63 49.46 o 1 5 1 1352.52 1383.25 20.77 o 2 5 1 798.57 786.66 19.74 o 3 5 1 1884.08 2068.89 31.06 o 4 5 1 1076.25 1067.71 24.39 o 5 5 1 571.96 675.04 20.44 o -5 6 1 577.08 592.11 20.75 o -4 6 1 642.95 596.77 16.54 o -3 6 1 35.67 42.25 6.59 o -2 6 1 1305.79 1218.08 22.44 o -1 6 1 1675.58 1689.01 24.86 o 0 6 1 1207.44 1344.72 25.80 o 1 6 1 1692.07 1710.67 23.75 o 2 6 1 1297.56 1200.73 24.10 o 3 6 1 35.74 45.49 7.73 o 4 6 1 647.39 588.05 18.34 o 5 6 1 600.42 618.14 20.71 o 6 6 1 139.92 146.56 12.23 o -6 7 1 408.01 412.50 19.12 o -5 7 1 1050.13 1085.74 28.73 o -4 7 1 819.77 818.01 24.04 o -3 7 1 2575.57 2583.48 40.24 o -2 7 1 1703.56 1620.83 32.96 o -1 7 1 353.56 388.33 12.56 o 0 7 1 20.40 36.52 5.08 o 1 7 1 360.17 382.11 12.33 o 2 7 1 1697.57 1600.07 29.07 o 3 7 1 2594.90 2557.21 44.53 o 4 7 1 853.01 856.16 22.63 o 5 7 1 1042.63 1091.51 29.40 o 6 7 1 419.43 462.50 22.03 o 7 7 1 1170.55 1121.96 31.99 o -7 8 1 3181.47 2875.39 50.08 o -6 8 1 655.11 610.06 23.64 o -5 8 1 1948.10 1864.20 37.65 o -4 8 1 741.44 721.98 21.90 o -3 8 1 199.05 218.99 14.50 o -2 8 1 786.31 834.60 25.19 o -1 8 1 1927.03 1787.16 26.48 o 0 8 1 100.18 115.60 8.09 o 1 8 1 1929.60 1885.32 29.05 o 2 8 1 780.95 868.12 19.88 o 3 8 1 192.01 203.51 13.56 o 4 8 1 747.26 753.72 22.57 o 5 8 1 1935.89 1835.72 35.96 o 6 8 1 658.81 628.66 21.23 o 7 8 1 3193.88 2911.89 53.76 o 8 8 1 252.92 262.69 19.76 o -8 9 1 590.27 620.11 26.70 o -7 9 1 898.89 896.65 29.69 o -6 9 1 1254.72 1231.17 34.70 o -5 9 1 525.74 547.40 19.98 o -4 9 1 277.05 319.18 16.58 o -3 9 1 273.15 317.97 18.82 o -2 9 1 1262.81 1266.25 32.69 o -1 9 1 572.51 593.94 15.37 o 0 9 1 9.38 14.73 2.98 o 1 9 1 577.97 571.47 22.40 o 2 9 1 1308.51 1265.94 25.33 o 3 9 1 279.84 307.55 18.58 o 4 9 1 268.20 254.95 15.92 o 5 9 1 512.20 529.56 19.78 o 6 9 1 1233.23 1178.31 32.91 o 7 9 1 879.06 862.84 27.51 o 8 9 1 592.21 586.48 26.74 o 9 9 1 721.04 701.54 27.52 o -9 10 1 41.24 40.47 10.99 o -8 10 1 777.59 723.71 29.58 o -7 10 1 1117.27 1107.52 33.90 o -6 10 1 158.00 170.00 14.67 o -5 10 1 35.63 40.70 7.10 o -4 10 1 1675.10 1597.82 36.96 o -3 10 1 98.84 122.53 13.26 o -2 10 1 750.18 677.62 25.26 o -1 10 1 218.89 219.14 14.84 o 0 10 1 1801.64 1811.28 28.89 o 1 10 1 223.75 227.11 11.57 o 2 10 1 736.18 710.40 19.70 o 3 10 1 100.70 115.25 9.88 o 4 10 1 1702.57 1647.52 36.67 o 5 10 1 30.82 37.87 7.35 o 6 10 1 148.33 164.25 13.98 o 7 10 1 1102.36 1009.36 29.45 o 8 10 1 783.75 768.47 27.57 o 9 10 1 43.61 65.58 8.67 o 10 10 1 761.55 760.93 35.32 o -10 11 1 85.94 124.72 15.97 o -9 11 1 30.89 46.27 9.29 o -8 11 1 342.00 361.68 23.90 o -7 11 1 928.80 925.05 30.52 o -6 11 1 1544.18 1488.89 37.95 o -5 11 1 404.66 472.30 22.68 o -4 11 1 1519.07 1489.61 37.20 o -3 11 1 916.10 928.06 31.74 o -2 11 1 299.37 331.72 14.12 o -1 11 1 364.84 373.28 20.24 o 0 11 1 1997.11 1930.44 43.44 o 1 11 1 350.57 347.37 13.90 o 2 11 1 313.05 334.50 14.84 o 3 11 1 924.63 887.05 23.92 o 4 11 1 1515.36 1426.67 33.78 o 5 11 1 399.76 474.36 21.61 o 6 11 1 1522.34 1529.92 38.33 o 7 11 1 903.19 898.77 29.05 o 8 11 1 321.90 348.77 21.16 o 9 11 1 34.21 46.97 8.79 o 10 11 1 90.79 144.14 21.44 o 11 11 1 17.04 54.04 17.69 o -11 12 1 116.58 106.94 14.77 o -10 12 1 82.89 102.34 16.83 o -9 12 1 69.44 72.66 10.17 o -8 12 1 115.49 127.95 13.52 o -7 12 1 551.05 542.55 25.95 o -6 12 1 197.25 225.19 17.97 o -5 12 1 338.08 348.63 22.47 o -4 12 1 566.58 561.24 24.69 o -3 12 1 383.29 426.81 23.15 o -2 12 1 361.32 365.77 19.43 o -1 12 1 23.91 34.91 6.11 o 0 12 1 41.51 72.07 10.76 o 1 12 1 21.76 28.82 12.12 o 2 12 1 375.74 402.41 20.64 o 3 12 1 378.62 369.87 20.90 o 4 12 1 575.63 537.87 18.76 o 5 12 1 337.44 346.41 18.25 o 6 12 1 203.84 247.81 19.64 o 7 12 1 545.29 519.47 25.45 o 8 12 1 115.39 115.98 13.26 o 9 12 1 69.14 76.69 12.03 o 10 12 1 86.61 115.35 12.97 o 11 12 1 117.15 136.78 21.88 o 12 12 1 796.55 798.14 42.33 o -12 13 1 74.24 51.85 16.97 o -11 13 1 157.70 188.56 24.81 o -10 13 1 14.91 40.15 19.42 o -9 13 1 71.38 75.28 10.09 o -8 13 1 549.90 580.68 29.19 o -7 13 1 575.87 597.93 29.67 o -6 13 1 19.18 25.42 5.86 o -5 13 1 311.04 287.11 23.04 o -4 13 1 81.37 96.42 12.65 o -3 13 1 2036.50 1963.05 44.06 o -2 13 1 2102.59 1925.04 48.18 o -1 13 1 473.54 427.31 23.97 o 0 13 1 1198.73 1072.81 38.77 o 1 13 1 490.93 463.38 25.25 o 2 13 1 2094.51 1919.39 46.17 o 3 13 1 2018.70 1935.05 48.16 o 4 13 1 76.39 92.31 9.62 o 5 13 1 319.02 288.75 17.62 o 6 13 1 17.39 28.62 6.91 o 7 13 1 588.49 629.75 27.31 o 8 13 1 554.33 547.85 28.85 o 9 13 1 74.99 76.45 9.49 o 10 13 1 14.64 17.41 8.09 o 11 13 1 159.22 156.85 22.29 o 12 13 1 71.25 55.38 14.24 o 13 13 1 65.69 41.24 9.77 o -13 14 1 2.17 4.51 10.16 o -12 14 1 63.51 71.41 14.85 o -11 14 1 491.02 545.74 43.64 o -10 14 1 44.41 69.02 13.02 o -9 14 1 770.98 792.31 36.12 o -8 14 1 267.47 298.38 24.54 o -7 14 1 839.04 871.02 36.61 o -6 14 1 100.14 93.49 12.54 o -5 14 1 708.94 748.67 29.15 o -4 14 1 661.19 679.20 26.98 o -3 14 1 13.49 37.87 6.77 o -2 14 1 82.26 51.07 9.10 o -1 14 1 836.85 767.10 33.68 o 0 14 1 65.26 68.36 15.12 o 1 14 1 856.33 831.02 33.83 o 2 14 1 79.49 82.68 16.23 o 3 14 1 14.88 42.53 6.45 o 4 14 1 658.26 632.52 26.42 o 5 14 1 722.11 770.11 27.29 o 6 14 1 94.12 103.20 17.53 o 7 14 1 839.40 848.46 35.15 o 8 14 1 266.95 243.88 22.62 o 9 14 1 763.51 821.77 43.86 o 10 14 1 41.78 46.19 10.01 o 11 14 1 475.12 528.02 42.42 o 12 14 1 63.32 71.67 12.82 o 13 14 1 2.48 26.97 9.54 o -12 15 1 239.51 229.37 26.16 o -11 15 1 283.73 270.32 31.04 o -10 15 1 52.49 57.82 11.33 o -9 15 1 10.40 22.43 7.38 o -8 15 1 513.00 507.25 35.98 o -7 15 1 111.63 96.58 12.56 o -6 15 1 71.86 90.00 10.40 o -5 15 1 512.96 533.92 27.40 o -4 15 1 387.06 426.85 26.07 o -3 15 1 291.54 316.72 22.99 o -2 15 1 546.74 524.29 25.94 o -1 15 1 179.07 162.36 18.16 o 0 15 1 56.76 87.66 16.70 o 1 15 1 182.80 156.03 16.45 o 2 15 1 553.70 557.32 28.96 o 3 15 1 291.65 278.75 32.04 o 4 15 1 382.85 372.20 23.99 o 5 15 1 508.26 516.40 51.17 o 6 15 1 75.49 80.88 12.36 o 7 15 1 113.86 133.38 15.36 o 8 15 1 527.67 564.07 39.95 o 9 15 1 9.21 -0.54 9.28 o 10 15 1 55.78 74.20 15.79 o 11 15 1 288.71 271.74 30.29 o 12 15 1 236.47 223.83 38.00 o -11 16 1 186.33 171.98 35.58 o -10 16 1 195.88 192.51 24.03 o -9 16 1 67.07 72.46 12.25 o -8 16 1 100.58 106.34 15.64 o -7 16 1 215.34 184.20 19.94 o -6 16 1 537.23 607.02 34.54 o -5 16 1 492.46 519.97 28.81 o -4 16 1 181.35 189.87 18.26 o -3 16 1 58.27 55.34 14.45 o -2 16 1 54.76 36.88 6.18 o -1 16 1 224.45 204.36 20.66 o 0 16 1 44.26 34.89 7.10 o 1 16 1 215.79 208.20 20.40 o 2 16 1 52.32 71.95 12.31 o 3 16 1 59.30 43.18 7.57 o 4 16 1 177.85 202.45 22.31 o 5 16 1 506.42 537.15 34.79 o 6 16 1 537.89 523.65 34.86 o 7 16 1 221.90 209.17 27.90 o 8 16 1 98.93 102.52 15.82 o 9 16 1 63.87 51.83 18.42 o 10 16 1 204.86 207.98 28.33 o 11 16 1 192.24 172.21 35.70 o -9 17 1 113.81 127.71 17.83 o -8 17 1 54.45 49.51 9.58 o -7 17 1 87.34 85.17 9.91 o -6 17 1 307.96 360.82 31.44 o -5 17 1 436.84 472.72 35.60 o -4 17 1 89.57 65.87 13.45 o -3 17 1 14.86 45.85 10.11 o -2 17 1 146.83 131.09 14.35 o -1 17 1 280.38 282.62 25.18 o 0 17 1 286.37 329.66 26.54 o 1 17 1 275.32 273.53 24.42 o 2 17 1 141.16 139.32 18.89 o 3 17 1 14.39 17.76 9.15 o 4 17 1 90.92 110.88 15.27 o 5 17 1 434.92 478.57 34.70 o 6 17 1 308.87 294.63 35.01 o 7 17 1 83.22 98.67 26.05 o 8 17 1 61.79 50.13 11.11 o 9 17 1 109.34 59.22 12.68 o -7 18 1 41.99 39.37 26.60 o -6 18 1 293.54 241.86 23.62 o -5 18 1 472.82 476.46 36.73 o -4 18 1 25.20 35.24 11.13 o -3 18 1 51.34 64.83 10.86 o -2 18 1 166.47 169.88 24.68 o -1 18 1 100.19 84.95 14.19 o 0 18 1 565.49 582.77 33.08 o 1 18 1 101.26 115.48 15.35 o 2 18 1 168.41 184.64 22.94 o 3 18 1 49.47 61.93 8.53 o 4 18 1 27.34 25.28 6.35 o 5 18 1 474.18 441.53 51.89 o 6 18 1 292.01 245.17 65.17 o 7 18 1 46.44 39.72 12.41 o -4 19 1 115.13 91.55 16.41 o -3 19 1 226.13 246.02 51.76 o -2 19 1 446.65 449.79 38.08 o -1 19 1 94.42 64.93 23.20 o 0 19 1 44.40 23.96 16.40 o 1 19 1 98.32 69.53 9.29 o 2 19 1 445.96 469.99 37.00 o 3 19 1 233.05 228.60 42.30 o 4 19 1 115.27 151.25 24.07 o 0 1 2 47253.01 46260.12 280.84 o 1 1 2 2290.86 2154.02 15.50 o -1 2 2 364.95 333.68 6.62 o 0 2 2 171.12 167.34 5.65 o 1 2 2 354.90 319.03 6.29 o 2 2 2 4956.90 4921.85 36.28 o -2 3 2 11564.93 11470.01 55.37 o -1 3 2 8540.39 8457.34 47.48 o 0 3 2 1478.24 1414.14 12.46 o 1 3 2 8504.92 8468.79 58.18 o 2 3 2 11538.16 11475.12 56.59 o 3 3 2 32.67 40.70 5.96 o -3 4 2 755.69 789.33 14.53 o -2 4 2 4830.12 4880.37 28.81 o -1 4 2 8459.31 8430.46 51.08 o 0 4 2 5218.09 5252.07 34.46 o 1 4 2 8511.78 8485.34 56.73 o 2 4 2 4808.58 4813.01 39.64 o 3 4 2 717.70 751.01 15.51 o 4 4 2 1579.63 1737.92 28.56 o -4 5 2 114.09 164.10 8.52 o -3 5 2 17.02 22.99 4.68 o -2 5 2 4945.92 4988.82 37.03 o -1 5 2 1430.32 1403.74 16.50 o 0 5 2 64.58 76.42 5.10 o 1 5 2 1442.47 1433.24 22.04 o 2 5 2 4959.04 4887.36 45.42 o 3 5 2 15.03 10.98 5.47 o 4 5 2 110.36 152.85 10.17 o 5 5 2 10.75 29.93 6.84 o -5 6 2 389.50 427.62 14.47 o -4 6 2 305.21 333.63 12.25 o -3 6 2 49.05 77.99 5.59 o -2 6 2 5110.14 5234.47 36.57 o -1 6 2 2768.22 2883.17 30.55 o 0 6 2 5392.79 4799.13 42.14 o 1 6 2 2806.68 2940.70 33.96 o 2 6 2 5133.41 5263.29 49.25 o 3 6 2 52.29 83.90 7.64 o 4 6 2 323.08 379.79 14.42 o 5 6 2 395.07 404.04 15.33 o 6 6 2 412.14 466.39 17.57 o -6 7 2 146.11 166.30 11.37 o -5 7 2 171.67 139.49 9.33 o -4 7 2 1322.03 1210.49 24.21 o -3 7 2 1761.07 1630.08 22.25 o -2 7 2 1570.19 1700.79 28.12 o -1 7 2 1948.56 1902.04 27.97 o 0 7 2 146.56 167.25 9.09 o 1 7 2 1963.84 1911.36 29.01 o 2 7 2 1559.35 1667.82 27.40 o 3 7 2 1754.90 1636.91 28.19 o 4 7 2 1325.68 1199.72 26.71 o 5 7 2 172.16 139.45 10.72 o 6 7 2 151.07 170.64 12.71 o 7 7 2 5.55 3.26 5.92 o -7 8 2 988.07 972.77 29.47 o 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