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Information card for entry 2240759
Preview
| Coordinates | 2240759.cif |
|---|---|
| Structure factors | 2240759.hkl |
| Original IUCr paper | HTML |
| Chemical name | μ-Cyanido-1:2κ^2^<i>N</i>:<i>C</i>-dicyanido-1κ<i>C</i>,2κ<i>C</i>-bis(quinolin-8-amine-1κ^2^<i>N</i>,<i>N</i>')-2-silver(I)-1-silver(II) |
|---|---|
| Formula | C21 H16 Ag2 N7 |
| Calculated formula | C21 H16 Ag2 N7 |
| SMILES | [Ag]12([n]3cccc4cccc(c34)[NH2]1)([n]1cccc3cccc(c13)[NH2]2)(C#N)[N]#C[Ag]C#[N] |
| Title of publication | Crystal structure of μ-cyanido-1:2κ^2^<i>N</i>:<i>C</i>-dicyanido-1κ<i>C</i>,2κ<i>C</i>-bis(quinolin-8-amine-1κ^2^<i>N</i>,<i>N</i>')-2-silver(I)-1-silver(II): rare occurrence of a mixed-valence Ag^I,II^ compound |
| Authors of publication | Setifi, Zouaoui; Bernès, Sylvain; Pérez, Olivier; Setifi, Fatima; Rouag, Djamil-Azzeddine |
| Journal of publication | Acta Crystallographica Section E |
| Year of publication | 2015 |
| Journal volume | 71 |
| Journal issue | 6 |
| Pages of publication | 698 - 701 |
| a | 13.5449 ± 0.0007 Å |
| b | 6.9385 ± 0.0003 Å |
| c | 22.3824 ± 0.0011 Å |
| α | 90° |
| β | 94.767 ± 0.002° |
| γ | 90° |
| Cell volume | 2096.25 ± 0.17 Å3 |
| Cell temperature | 293 ± 2 K |
| Ambient diffraction temperature | 293 ± 2 K |
| Number of distinct elements | 4 |
| Space group number | 14 |
| Hermann-Mauguin space group symbol | P 1 21/c 1 |
| Hall space group symbol | -P 2ybc |
| Residual factor for all reflections | 0.055 |
| Residual factor for significantly intense reflections | 0.0344 |
| Weighted residual factors for significantly intense reflections | 0.0793 |
| Weighted residual factors for all reflections included in the refinement | 0.0878 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.023 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | Yes |
| Revision | Date | Message | Files |
|---|---|---|---|
| 181907 (current) | 2016-04-06 | hkl/2/24/ (antanas@echidna) Adding IUCr specific svn headers to multiple entries in subrange 2/24/07 |
2240759.cif 2240759.hkl |
| 137293 | 2015-05-24 | cif/ hkl/ Adding structures of 2240759 via cif-deposit CGI script. |
2240759.cif 2240759.hkl |
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Users of the data should acknowledge the original authors of the
structural data.