#------------------------------------------------------------------------------ #$Date: 2016-01-22 06:01:16 +0200 (Fri, 22 Jan 2016) $ #$Revision: 174746 $ #$URL: file:///home/coder/svn-repositories/cod/cif/2/24/14/2241495.cif $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2241495 loop_ _publ_author_name 'Tiritiris, Ioannis' 'Kantlehner, Willi' _publ_section_title ; Crystal structure of N-[3-(dimethylazaniumyl)propyl]-N',N',N'',N''-tetramethyl-N-(N,N,N',N'-tetramethylformamidiniumyl)guanidinium dibromide hydroxide monohydrate ; _journal_coeditor_code SJ5490 _journal_issue 12 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first o1078 _journal_page_last o1079 _journal_paper_doi 10.1107/S2056989015024305 _journal_volume 71 _journal_year 2015 _chemical_formula_iupac 'C15 H37 N6 3+, 1.988Br -, O H -, H2 O' _chemical_formula_moiety 'C15 H37 N6 3+, 1.988(Br -), H O -, H2 O' _chemical_formula_sum 'C15 H40 Br1.99 N6 O2' _chemical_formula_weight 495.37 _chemical_name_systematic 'N-[3-(Dimethylazaniumyl)propyl]-N',N',N'',N''-tetramethyl-N-(N,N,N',N'-tetramethylformamidiniumyl)guanidinium dibromide hydroxide monohydrate' _space_group_crystal_system monoclinic _space_group_IT_number 4 _space_group_name_Hall 'P 2yb' _space_group_name_H-M_alt 'P 1 21 1' _symmetry_space_group_name_Hall 'P 2yb' _symmetry_space_group_name_H-M 'P 1 21 1' _atom_sites_solution_hydrogens geom _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _audit_creation_method SHELXL-2014/7 _cell_angle_alpha 90 _cell_angle_beta 97.454(3) _cell_angle_gamma 90 _cell_formula_units_Z 2 _cell_length_a 9.1584(6) _cell_length_b 12.2932(7) _cell_length_c 10.6633(6) _cell_measurement_reflns_used 25793 _cell_measurement_temperature 100(2) _cell_measurement_theta_max 30.54 _cell_measurement_theta_min 1.93 _cell_volume 1190.39(12) _computing_cell_refinement ; SAINT (Bruker, 2008) ; _computing_data_collection ; APEX2 (Bruker, 2008) ; _computing_data_reduction ; SAINT (Bruker, 2008) ; _computing_molecular_graphics ; DIAMOND (Brandenburg & Putz, 2005) ; _computing_publication_material ; SHELXL2014 (Sheldrick, 2015) ; _computing_structure_refinement ; SHELXL2014 (Sheldrick, 2015) ; _computing_structure_solution ; SHELXS97 (Sheldrick, 2008) ; _diffrn_ambient_temperature 100(2) _diffrn_measured_fraction_theta_full 1.000 _diffrn_measured_fraction_theta_max 0.999 _diffrn_measurement_device_type 'Bruker Kappa APEXII DUO' _diffrn_measurement_method '\f scans, and \w scans' _diffrn_radiation_monochromator Triumph _diffrn_radiation_type MoK\a _diffrn_radiation_wavelength 0.71073 _diffrn_reflns_av_R_equivalents 0.0327 _diffrn_reflns_limit_h_max 12 _diffrn_reflns_limit_h_min -13 _diffrn_reflns_limit_k_max 17 _diffrn_reflns_limit_k_min -17 _diffrn_reflns_limit_l_max 15 _diffrn_reflns_limit_l_min -15 _diffrn_reflns_number 25793 _diffrn_reflns_theta_full 25.242 _diffrn_reflns_theta_max 30.526 _diffrn_reflns_theta_min 1.926 _diffrn_standards_decay_% 0 _diffrn_standards_interval_count 0 _diffrn_standards_number 0 _exptl_absorpt_coefficient_mu 3.404 _exptl_absorpt_correction_T_max 0.481 _exptl_absorpt_correction_T_min 0.334 _exptl_absorpt_correction_type multi-scan _exptl_absorpt_process_details ; (Blessing, 1995) ; _exptl_crystal_colour colorless _exptl_crystal_density_diffrn 1.382 _exptl_crystal_density_method 'not measured' _exptl_crystal_description prism _exptl_crystal_F_000 515.2 _exptl_crystal_size_max 0.41 _exptl_crystal_size_mid 0.29 _exptl_crystal_size_min 0.25 _refine_diff_density_max 0.374 _refine_diff_density_min -0.231 _refine_ls_abs_structure_details ; refined as an inversion twin ; _refine_ls_abs_structure_Flack 0.109(8) _refine_ls_extinction_method none _refine_ls_goodness_of_fit_ref 0.992 _refine_ls_hydrogen_treatment mixed _refine_ls_matrix_type full _refine_ls_number_parameters 265 _refine_ls_number_reflns 7244 _refine_ls_number_restraints 1 _refine_ls_restrained_S_all 0.992 _refine_ls_R_factor_all 0.0389 _refine_ls_R_factor_gt 0.0306 _refine_ls_shift/su_max 0.000 _refine_ls_shift/su_mean 0.000 _refine_ls_structure_factor_coef Fsqd _refine_ls_weighting_details 'w=1/[\s^2^(Fo^2^)+(0.0344P)^2^] where P=(Fo^2^+2Fc^2^)/3' _refine_ls_weighting_scheme calc _refine_ls_wR_factor_gt 0.0672 _refine_ls_wR_factor_ref 0.0693 _reflns_number_gt 6391 _reflns_number_total 7244 _reflns_threshold_expression 'I > 2\s(I)' _cod_data_source_file sj5490sup1.cif _cod_data_source_block I _cod_database_code 2241495 _shelx_space_group_comment ; The symmetry employed for this shelxl refinement is uniquely defined by the following loop, which should always be used as a source of symmetry information in preference to the above space-group names. They are only intended as comments. ; _shelx_hkl_file ; 1 0 0 67.24 2.81 1 0 0 72.11 3.07 1 0 0 75.01 2.59 1 0 0 74.77 2.60 1 0 0 66.33 2.72 -1 0 0 76.88 2.72 -1 0 0 67.26 2.81 -1 0 0 68.07 3.06 -1 0 0 75.00 2.58 -1 0 0 76.23 2.59 -2 0 0 611.82 35.21 2 0 0 604.70 32.71 2 0 0 592.92 32.73 2 0 0 601.74 38.29 -2 0 0 615.99 38.30 -2 0 0 626.10 34.04 -2 0 0 630.23 34.04 2 0 0 618.65 35.22 2 0 0 609.72 34.03 -2 0 0 608.73 32.71 -3 0 0 31.98 2.31 -3 0 0 33.48 2.10 3 0 0 32.74 1.91 3 0 0 30.94 2.04 3 0 0 31.27 2.14 3 0 0 33.07 2.30 -3 0 0 30.15 1.82 -3 0 0 32.25 1.85 -3 0 0 30.17 2.08 -3 0 0 29.38 2.07 3 0 0 31.65 1.97 4 0 0 11.34 1.41 -4 0 0 12.56 0.96 -4 0 0 13.65 0.93 -4 0 0 12.92 1.26 4 0 0 11.19 1.16 -4 0 0 12.54 1.36 -4 0 0 12.23 1.19 4 0 0 11.53 1.19 -5 0 0 21.50 1.84 -5 0 0 24.91 1.92 5 0 0 23.48 1.84 -5 0 0 23.01 2.10 5 0 0 24.37 2.05 5 0 0 21.09 1.82 5 0 0 25.54 1.97 -5 0 0 22.83 1.42 -5 0 0 22.73 1.41 -6 0 0 169.89 10.27 -6 0 0 165.68 9.99 -6 0 0 178.00 11.24 6 0 0 166.53 9.52 6 0 0 171.20 9.94 6 0 0 174.07 10.31 7 0 0 13.75 1.68 7 0 0 12.87 1.60 -7 0 0 13.86 1.61 7 0 0 13.70 1.74 7 0 0 12.13 1.62 -8 0 0 244.76 14.97 8 0 0 260.27 15.43 8 0 0 274.74 16.80 8 0 0 257.75 14.26 8 0 0 248.24 16.86 9 0 0 14.51 2.04 9 0 0 14.45 1.94 -9 0 0 12.74 1.94 9 0 0 16.47 2.40 10 0 0 75.97 5.09 10 0 0 76.95 5.38 -10 0 0 75.18 5.37 11 0 0 -0.34 1.86 -11 0 0 0.17 2.09 -12 0 0 4.81 2.46 12 0 0 6.36 2.28 0 -1 0 0.20 0.13 -1 -1 0 119.36 6.21 1 -1 0 115.35 5.96 1 -1 0 115.04 7.00 1 -1 0 116.15 6.22 1 -1 0 109.97 7.01 1 1 0 103.55 6.20 -1 1 0 106.61 5.96 -1 1 0 103.44 7.00 1 1 0 103.25 6.20 2 -1 0 230.69 13.47 -2 -1 0 243.09 14.03 2 -1 0 233.74 15.83 2 -1 0 219.08 14.02 2 -1 0 239.61 13.48 2 -1 0 236.98 15.79 2 1 0 248.77 14.03 2 1 0 266.49 14.57 2 1 0 240.50 13.42 -2 1 0 252.12 14.50 -2 1 0 265.77 15.81 -2 1 0 259.70 13.47 2 1 0 260.16 14.02 -2 1 0 254.28 13.48 -2 1 0 260.73 14.05 2 1 0 262.81 15.79 2 1 0 253.46 13.41 -2 1 0 266.35 15.85 -2 1 0 270.23 14.05 3 -1 0 809.19 55.51 3 -1 0 860.28 47.44 3 -1 0 903.09 49.35 -3 -1 0 883.72 49.34 3 -1 0 845.65 55.66 3 -1 0 845.54 47.46 -3 -1 0 888.80 49.34 3 1 0 905.58 47.42 -3 1 0 895.40 47.43 -3 1 0 887.58 49.35 3 1 0 888.18 55.50 3 1 0 924.01 51.10 3 1 0 896.69 47.39 -3 1 0 904.32 47.44 -3 1 0 933.78 55.54 3 1 0 886.83 49.34 -3 1 0 920.18 51.03 -4 -1 0 226.10 12.08 4 -1 0 221.79 13.59 4 -1 0 211.39 12.07 4 -1 0 215.26 11.57 4 -1 0 219.45 13.62 4 1 0 215.18 13.55 -4 1 0 209.66 11.50 4 1 0 203.95 12.05 -4 1 0 210.58 12.08 -4 1 0 202.71 13.59 -4 1 0 203.99 12.43 4 1 0 212.04 11.48 4 1 0 208.61 11.52 5 -1 0 80.36 4.66 5 -1 0 75.52 4.92 5 -1 0 70.13 5.45 -5 -1 0 71.95 4.85 5 -1 0 71.66 5.47 -5 1 0 87.97 4.98 -5 1 0 90.25 5.00 -5 1 0 89.32 5.56 5 1 0 83.34 4.64 5 1 0 79.26 4.89 -5 1 0 79.19 4.53 5 1 0 86.49 5.10 6 -1 0 175.61 9.97 6 -1 0 175.99 11.79 6 -1 0 168.13 11.70 6 1 0 177.02 10.42 -6 1 0 180.53 10.73 6 1 0 184.70 9.96 -6 1 0 183.28 9.78 -6 1 0 184.39 11.80 6 1 0 184.37 10.84 7 -1 0 92.03 5.87 7 -1 0 98.00 5.67 -7 -1 0 94.59 5.96 -7 1 0 93.81 5.18 -7 1 0 93.76 5.92 7 1 0 91.00 6.52 -7 1 0 98.04 5.21 -7 1 0 90.33 6.63 7 1 0 89.52 5.56 -7 1 0 97.48 6.01 7 1 0 95.62 5.90 7 1 0 97.31 6.17 8 -1 0 59.29 3.85 8 -1 0 58.54 4.49 -8 -1 0 58.95 4.18 8 -1 0 64.20 4.04 8 1 0 51.17 3.99 -8 1 0 56.34 4.57 -8 1 0 55.27 4.02 8 1 0 50.54 4.04 8 1 0 55.12 3.85 -8 1 0 58.05 4.04 8 1 0 51.03 4.31 8 1 0 58.90 4.66 -9 -1 0 36.97 3.09 9 -1 0 32.94 3.35 9 -1 0 34.18 3.19 9 -1 0 38.88 3.01 9 1 0 32.45 3.08 9 1 0 32.00 3.00 9 1 0 31.99 3.03 -9 1 0 30.56 3.03 9 1 0 31.15 3.56 10 -1 0 9.75 1.97 10 -1 0 8.10 2.01 -10 -1 0 6.03 2.04 -10 1 0 11.28 1.96 10 1 0 8.58 2.04 11 -1 0 21.02 2.65 -11 -1 0 21.63 2.91 11 1 0 21.64 2.64 -11 1 0 22.16 2.72 -12 -1 0 38.28 3.89 12 -1 0 37.79 3.54 -12 1 0 34.94 3.90 12 1 0 37.74 3.68 0 -2 0 52.52 4.03 0 -2 0 47.95 4.02 0 -2 0 50.25 4.53 0 -2 0 52.87 4.53 0 -2 0 51.13 3.85 0 2 0 53.07 4.53 0 2 0 49.80 4.02 0 2 0 46.75 4.52 0 2 0 52.26 3.85 0 2 0 48.82 4.03 -1 -2 0 302.77 17.59 1 -2 0 304.33 15.02 1 -2 0 297.84 17.64 -1 -2 0 292.06 15.60 1 -2 0 307.27 17.61 1 -2 0 291.39 15.02 -1 -2 0 299.55 15.63 1 -2 0 292.06 15.64 -1 2 0 259.91 17.63 1 2 0 258.14 15.61 -1 2 0 264.53 17.59 -1 2 0 261.67 15.63 1 2 0 261.99 15.59 -1 2 0 272.91 15.03 -1 2 0 264.10 15.02 1 2 0 267.38 17.61 -1 2 0 265.15 15.02 -2 -2 0 213.17 11.60 -2 -2 0 204.35 11.57 2 -2 0 191.02 11.59 2 -2 0 206.58 11.11 2 -2 0 218.89 13.05 2 -2 0 213.26 13.07 2 2 0 204.52 11.55 -2 2 0 193.51 13.04 -2 2 0 205.41 11.11 -2 2 0 208.89 13.07 2 2 0 205.64 11.55 -3 -2 0 67.61 4.86 3 -2 0 67.11 5.47 -3 -2 0 70.27 4.87 3 2 0 92.91 5.51 3 2 0 88.86 4.91 -3 2 0 88.20 5.00 -3 2 0 92.34 5.54 -3 2 0 88.49 5.54 -3 2 0 87.88 4.66 3 2 0 88.39 4.53 3 2 0 86.60 4.53 4 -2 0 64.51 3.30 4 -2 0 65.02 3.50 4 -2 0 64.87 3.90 -4 -2 0 66.53 3.51 -4 2 0 51.53 3.45 4 2 0 50.85 3.81 4 2 0 50.50 3.10 -4 2 0 47.85 3.41 -4 2 0 52.62 3.22 4 2 0 54.53 3.13 -4 2 0 47.18 3.83 4 2 0 51.26 3.40 4 2 0 53.35 3.60 5 -2 0 30.29 2.61 5 -2 0 32.56 2.73 5 -2 0 32.12 2.26 -5 -2 0 31.85 2.42 5 -2 0 32.80 2.40 -5 2 0 32.34 2.31 5 2 0 32.27 2.48 -5 2 0 32.78 2.15 -5 2 0 33.91 2.69 -5 2 0 34.35 2.41 5 2 0 34.12 2.15 5 2 0 30.88 2.34 6 -2 0 85.83 4.86 6 -2 0 83.57 5.72 6 -2 0 82.94 5.18 6 -2 0 84.74 5.79 -6 -2 0 85.19 5.15 -6 2 0 84.01 5.76 6 2 0 79.22 4.78 -6 2 0 80.07 5.12 -6 2 0 78.48 5.09 -6 2 0 83.98 4.64 6 2 0 75.74 5.33 6 2 0 80.04 5.06 6 2 0 74.82 5.62 7 -2 0 58.27 4.49 7 -2 0 58.18 3.84 -7 -2 0 55.91 4.12 7 -2 0 55.74 4.12 7 -2 0 57.07 4.49 -7 2 0 58.61 4.18 -7 2 0 63.44 3.56 -7 2 0 61.30 4.02 7 2 0 59.64 4.00 7 2 0 60.10 3.78 7 2 0 59.66 4.19 7 2 0 59.09 4.46 -7 2 0 60.22 4.56 8 -2 0 13.33 1.82 -8 -2 0 9.36 1.88 8 -2 0 12.68 1.97 8 2 0 16.51 1.86 -8 2 0 18.10 1.43 -8 2 0 18.29 1.84 8 2 0 18.40 2.04 8 2 0 16.69 2.13 -8 2 0 17.11 1.99 -8 2 0 19.31 2.27 8 2 0 17.63 2.08 9 -2 0 55.18 4.07 -9 -2 0 57.16 4.28 9 -2 0 57.47 4.07 -9 2 0 52.54 4.01 9 2 0 53.30 4.04 -9 2 0 50.15 4.08 9 2 0 55.76 4.56 9 2 0 54.28 3.85 10 -2 0 32.54 3.10 -10 -2 0 30.35 3.06 10 -2 0 31.02 2.85 -10 2 0 24.92 2.88 10 2 0 28.32 2.81 11 -2 0 20.59 2.73 11 -2 0 15.83 2.69 -11 -2 0 15.40 2.62 11 2 0 22.16 2.50 -11 2 0 14.19 2.72 -12 -2 0 14.00 2.75 12 -2 0 19.19 2.96 12 2 0 11.67 2.49 -12 2 0 16.16 2.97 0 -3 0 0.09 0.31 0 -3 0 0.44 0.29 0 -3 0 0.13 0.28 0 -3 0 0.18 0.30 0 -3 0 0.24 0.28 0 3 0 0.49 0.36 0 3 0 0.04 0.20 0 3 0 0.36 0.31 0 3 0 -0.22 0.29 0 3 0 0.01 0.19 0 3 0 0.09 0.29 0 3 0 0.13 0.32 1 -3 0 20.97 1.41 1 -3 0 20.34 1.28 -1 -3 0 21.16 1.34 1 -3 0 21.24 1.58 1 -3 0 20.28 1.27 1 -3 0 20.96 1.61 -1 -3 0 20.89 1.49 -1 -3 0 19.54 1.38 1 -3 0 21.48 1.40 1 -3 0 20.17 1.29 -1 3 0 21.29 1.32 -1 3 0 21.68 1.34 1 3 0 21.49 1.37 1 3 0 21.21 1.34 1 3 0 23.46 1.54 -1 3 0 22.14 1.41 -1 3 0 21.97 1.62 -1 3 0 22.35 1.57 2 -3 0 112.86 6.86 2 -3 0 110.92 5.80 -2 -3 0 109.05 6.03 2 -3 0 114.29 6.86 2 -3 0 108.99 5.79 -2 -3 0 112.86 6.08 2 -3 0 111.14 6.10 2 3 0 100.40 6.79 -2 3 0 98.89 5.81 -2 3 0 96.51 6.83 -2 3 0 98.12 5.79 2 3 0 98.58 5.99 -2 3 0 101.87 6.85 -3 -3 0 319.54 17.32 -3 -3 0 313.67 17.28 3 -3 0 314.24 19.52 3 -3 0 339.82 19.51 -3 3 0 301.01 17.31 3 3 0 286.84 19.44 3 3 0 293.75 17.23 -3 3 0 300.12 19.51 -3 3 0 300.17 19.48 4 -3 0 0.74 0.68 -4 -3 0 0.28 0.64 4 -3 0 0.64 0.70 4 -3 0 1.01 0.67 -4 -3 0 1.10 0.71 4 3 0 3.04 0.95 -4 3 0 2.22 0.55 -4 3 0 2.63 0.78 4 3 0 3.58 0.69 -4 3 0 1.88 0.85 4 3 0 3.06 0.41 4 3 0 3.61 0.46 -4 3 0 2.93 0.82 -4 3 0 2.23 0.76 5 -3 0 160.51 9.53 -5 -3 0 155.48 9.51 5 -3 0 164.91 10.71 5 -3 0 151.15 10.71 5 -3 0 158.96 9.07 5 3 0 165.67 8.95 5 3 0 169.21 9.47 -5 3 0 160.54 9.72 5 3 0 169.96 9.96 -5 3 0 162.05 10.75 -5 3 0 168.75 9.05 -5 3 0 174.17 9.58 5 3 0 168.36 10.64 -6 -3 0 27.81 2.15 6 -3 0 26.48 2.11 6 -3 0 27.20 2.22 6 3 0 18.26 1.95 -6 3 0 19.88 1.75 -6 3 0 19.74 2.20 6 3 0 17.47 1.88 -6 3 0 19.86 1.80 -6 3 0 18.52 1.89 6 3 0 17.84 2.10 6 3 0 15.49 1.66 7 -3 0 193.10 11.44 7 -3 0 192.07 12.85 -7 -3 0 191.35 11.45 7 -3 0 203.52 12.90 -7 3 0 187.94 12.92 7 3 0 191.83 11.37 -7 3 0 200.04 11.67 7 3 0 194.03 12.74 7 3 0 207.70 11.94 -7 3 0 192.98 10.72 -7 3 0 192.37 11.47 7 3 0 192.48 10.82 8 -3 0 34.63 3.08 8 -3 0 33.97 2.73 -8 -3 0 32.73 2.97 8 -3 0 29.69 3.25 8 3 0 31.59 2.69 8 3 0 29.57 2.61 8 3 0 28.71 3.09 -8 3 0 31.13 3.17 -8 3 0 28.24 2.59 -8 3 0 32.13 2.25 8 3 0 32.69 3.03 -8 3 0 25.39 2.78 -9 -3 0 15.33 2.14 9 -3 0 14.98 2.22 9 -3 0 13.39 1.98 9 3 0 14.29 1.97 -9 3 0 14.19 1.67 -9 3 0 10.94 2.21 10 -3 0 33.77 3.31 10 -3 0 34.80 3.64 -10 -3 0 29.67 3.24 10 3 0 41.06 3.25 -10 3 0 38.46 3.48 11 -3 0 4.87 1.91 -11 -3 0 4.99 2.12 11 -3 0 4.39 2.11 -11 3 0 6.47 2.03 11 3 0 5.38 2.13 -12 -3 0 6.77 2.42 12 -3 0 4.93 2.31 12 3 0 10.09 2.30 -12 3 0 10.64 2.82 0 -4 0 351.83 24.56 0 -4 0 400.85 21.85 0 -4 0 393.71 24.61 0 -4 0 385.86 21.83 0 -4 0 383.71 20.86 0 4 0 410.13 24.58 0 4 0 391.69 20.94 0 4 0 405.46 20.87 0 4 0 390.99 24.63 0 4 0 398.07 20.94 0 4 0 393.10 21.83 1 -4 0 161.44 8.73 1 -4 0 171.14 8.76 1 -4 0 157.66 9.19 1 -4 0 181.24 9.23 -1 -4 0 152.43 9.14 -1 -4 0 159.79 9.16 1 -4 0 159.24 8.73 -1 -4 0 164.55 10.29 1 -4 0 155.16 10.34 -1 4 0 155.95 8.78 1 4 0 162.97 9.13 -1 4 0 166.12 8.80 -1 4 0 164.74 9.21 1 4 0 162.23 8.78 1 4 0 159.45 10.28 -1 4 0 167.03 10.35 -1 4 0 158.77 10.36 1 4 0 161.07 10.32 2 -4 0 57.44 3.36 -2 -4 0 59.78 3.56 2 -4 0 56.03 3.34 2 -4 0 60.95 4.02 -2 -4 0 59.42 3.49 2 -4 0 62.92 3.60 2 -4 0 60.87 4.03 -2 4 0 57.44 3.40 2 4 0 60.55 3.97 -2 4 0 58.37 4.02 2 4 0 58.34 3.46 -2 4 0 59.41 4.01 -2 4 0 60.76 3.59 3 -4 0 15.75 1.59 -3 -4 0 13.96 1.54 3 -4 0 15.10 1.47 -3 -4 0 16.30 1.40 3 -4 0 17.12 1.67 3 -4 0 15.47 1.39 3 4 0 21.78 1.64 -3 4 0 21.35 1.68 -3 4 0 19.34 1.45 3 4 0 19.50 1.32 -3 4 0 18.03 1.61 -3 4 0 21.39 1.72 4 -4 0 33.63 2.53 -4 -4 0 36.18 2.47 4 -4 0 35.07 2.35 -4 -4 0 33.63 2.53 4 -4 0 34.06 2.76 4 -4 0 35.12 2.80 4 4 0 35.89 2.72 -4 4 0 38.40 2.85 4 4 0 38.14 2.06 -4 4 0 36.68 2.87 -4 4 0 39.29 2.38 4 4 0 35.76 2.05 4 4 0 36.33 2.41 -4 4 0 37.66 2.57 5 -4 0 18.65 2.02 5 -4 0 19.96 2.05 5 -4 0 19.15 1.73 5 -4 0 18.47 2.11 -5 -4 0 19.94 1.91 5 4 0 17.93 1.98 -5 4 0 22.95 2.12 -5 4 0 22.23 1.72 -5 4 0 22.14 2.06 -5 4 0 21.05 1.92 -5 4 0 20.76 1.83 5 4 0 21.47 1.72 5 4 0 19.22 1.46 5 4 0 18.07 1.93 5 4 0 21.79 1.97 6 -4 0 7.92 1.45 6 -4 0 8.94 1.45 -6 -4 0 8.27 1.38 6 -4 0 8.42 1.39 6 4 0 11.26 1.28 6 4 0 11.05 1.42 6 4 0 9.43 1.31 -6 4 0 11.12 1.27 6 4 0 10.80 1.53 -6 4 0 11.78 1.50 -6 4 0 11.64 1.33 -6 4 0 9.83 1.54 6 4 0 12.75 1.17 7 -4 0 14.00 1.83 -7 -4 0 8.34 1.57 7 -4 0 10.76 1.80 7 -4 0 9.73 1.67 7 -4 0 9.56 1.50 7 4 0 12.06 1.70 7 4 0 12.87 1.44 7 4 0 12.47 1.93 7 4 0 10.80 1.60 -7 4 0 11.83 1.42 -7 4 0 10.15 1.34 7 4 0 14.21 1.61 -7 4 0 13.55 1.86 -7 4 0 10.08 1.83 8 -4 0 5.44 1.55 -8 -4 0 8.06 1.67 8 -4 0 5.55 1.68 -8 4 0 9.60 1.42 8 4 0 10.06 1.48 -8 4 0 7.87 1.33 8 4 0 7.02 1.53 -8 4 0 8.41 1.66 8 4 0 8.90 1.55 9 -4 0 6.78 1.78 9 -4 0 9.05 1.80 -9 -4 0 7.57 2.02 -9 4 0 7.33 1.48 9 4 0 7.04 1.67 -9 4 0 7.75 1.82 -9 4 0 6.68 1.27 10 -4 0 5.45 1.91 -10 -4 0 3.11 1.86 10 -4 0 4.58 1.80 -10 4 0 1.25 1.70 10 4 0 3.07 1.85 -11 -4 0 2.37 2.02 11 -4 0 1.57 1.93 11 -4 0 0.23 1.83 11 4 0 0.19 2.01 -11 4 0 -1.21 2.24 12 -4 0 13.85 2.73 -12 -4 0 9.97 2.53 -12 4 0 3.92 2.71 12 4 0 10.55 2.30 0 -5 0 0.16 0.52 0 -5 0 -0.21 0.47 0 -5 0 -0.12 0.40 0 -5 0 0.09 0.46 0 -5 0 0.63 0.48 0 5 0 0.76 0.41 0 5 0 0.07 0.52 0 5 0 0.36 0.35 0 5 0 -0.01 0.41 0 5 0 -0.10 0.49 0 5 0 -0.16 0.34 1 -5 0 4.27 0.71 -1 -5 0 3.60 0.69 1 -5 0 3.94 0.65 -1 -5 0 4.71 0.63 -1 -5 0 3.91 0.58 1 -5 0 4.03 0.71 1 -5 0 4.12 0.61 1 5 0 4.72 0.63 1 5 0 4.89 0.69 -1 5 0 4.95 0.59 -1 5 0 5.57 0.74 -1 5 0 4.99 0.63 -1 5 0 4.14 0.71 -1 5 0 5.08 0.80 1 5 0 5.60 0.69 1 5 0 4.82 0.57 2 -5 0 13.43 1.05 2 -5 0 13.95 1.04 -2 -5 0 12.73 1.24 2 -5 0 10.97 1.31 2 -5 0 14.25 1.03 2 -5 0 15.10 1.38 -2 -5 0 13.38 1.09 2 -5 0 12.36 1.22 2 5 0 13.40 1.26 -2 5 0 11.85 1.20 -2 5 0 13.94 1.31 -2 5 0 12.93 1.18 -2 5 0 12.60 1.46 2 5 0 12.77 1.07 3 -5 0 10.98 0.92 -3 -5 0 10.48 1.07 3 -5 0 11.11 1.21 3 -5 0 11.31 1.20 -3 -5 0 12.01 1.08 3 -5 0 10.25 1.08 -3 5 0 7.19 1.11 -3 5 0 7.36 1.07 3 5 0 6.86 1.02 3 5 0 7.17 0.82 -3 5 0 7.60 1.01 -3 5 0 7.56 0.97 4 -5 0 30.59 2.36 4 -5 0 29.46 2.10 4 -5 0 31.43 1.94 -4 -5 0 27.72 2.03 -4 -5 0 29.86 2.06 4 -5 0 31.07 2.29 -4 5 0 22.22 2.16 4 5 0 21.43 1.79 -4 5 0 20.94 2.20 -4 5 0 18.20 1.98 4 5 0 19.91 2.08 5 -5 0 41.84 2.76 5 -5 0 43.67 3.31 5 -5 0 44.91 3.04 5 -5 0 42.96 3.37 -5 -5 0 43.39 3.07 5 -5 0 40.91 2.78 5 5 0 39.92 2.46 5 5 0 37.86 3.15 5 5 0 43.67 2.79 5 5 0 42.49 3.23 -5 5 0 37.78 3.34 -5 5 0 41.07 3.32 5 5 0 39.37 3.18 -5 5 0 40.91 2.87 -5 5 0 43.35 3.04 6 -5 0 46.56 3.38 6 -5 0 45.09 3.24 -6 -5 0 43.63 3.08 6 -5 0 48.43 2.86 6 -5 0 49.31 3.58 6 5 0 36.84 3.14 -6 5 0 34.91 3.44 6 5 0 37.24 2.82 -6 5 0 37.32 2.77 6 5 0 37.92 2.54 6 5 0 37.46 3.22 6 5 0 34.99 3.34 -6 5 0 40.68 3.09 -6 5 0 31.93 3.29 -6 5 0 38.61 2.77 7 -5 0 36.76 3.57 -7 -5 0 40.79 3.13 7 -5 0 36.21 2.83 7 -5 0 36.68 3.33 7 -5 0 40.85 3.57 7 5 0 35.47 3.27 7 5 0 37.43 2.67 -7 5 0 36.59 3.17 -7 5 0 42.67 3.52 -7 5 0 37.67 2.85 -7 5 0 36.41 2.77 7 5 0 34.33 3.19 7 5 0 38.03 2.89 -8 -5 0 40.63 3.22 8 -5 0 40.87 3.20 8 -5 0 41.41 2.96 -8 5 0 30.01 2.74 -8 5 0 31.90 3.39 8 5 0 30.79 2.69 -8 5 0 31.44 2.78 8 5 0 34.15 3.15 9 -5 0 26.66 3.01 9 -5 0 29.89 2.76 -9 -5 0 32.65 3.09 -9 5 0 25.51 2.81 9 5 0 28.45 2.72 -9 5 0 26.80 2.47 10 -5 0 1.55 1.75 10 -5 0 3.93 2.18 -10 -5 0 3.28 1.86 -10 5 0 7.50 2.38 10 5 0 5.68 1.82 11 -5 0 18.96 2.59 11 -5 0 16.93 2.96 -11 -5 0 16.09 2.59 11 5 0 21.13 2.65 -11 5 0 20.39 2.79 -12 -5 0 6.38 2.33 12 -5 0 7.70 2.76 12 -5 0 11.37 2.68 12 5 0 4.84 2.38 -12 5 0 3.38 2.31 0 6 0 17.90 1.29 0 6 0 18.16 1.45 0 6 0 20.31 1.64 0 6 0 20.15 1.47 0 6 0 17.65 1.62 0 6 0 19.39 1.29 -1 -6 0 165.59 8.65 -1 -6 0 170.76 9.65 1 -6 0 170.58 8.26 1 -6 0 162.07 9.72 1 -6 0 174.65 9.77 1 -6 0 177.18 8.73 -1 -6 0 154.87 8.60 -1 6 0 137.27 9.73 1 6 0 139.80 8.56 1 6 0 140.50 8.11 -1 6 0 140.07 8.63 -1 6 0 142.10 9.72 1 6 0 140.99 8.12 1 6 0 128.55 9.62 1 6 0 144.02 8.27 1 6 0 145.62 9.69 -1 6 0 138.78 8.24 2 -6 0 53.61 2.87 2 -6 0 53.36 2.75 -2 -6 0 54.55 3.08 2 -6 0 50.03 3.11 2 -6 0 53.62 3.46 2 -6 0 54.63 2.75 2 -6 0 49.81 3.53 -2 -6 0 51.97 2.99 -2 6 0 42.01 3.41 -2 6 0 43.42 3.06 2 6 0 40.99 2.91 2 6 0 40.68 3.28 -2 6 0 42.97 2.90 2 6 0 43.49 3.35 3 -6 0 110.42 6.43 3 -6 0 108.49 5.99 3 -6 0 111.20 7.21 -3 -6 0 107.60 6.29 -3 -6 0 110.05 6.34 3 -6 0 103.76 7.17 -3 6 0 103.72 6.09 -3 6 0 112.90 7.27 -3 6 0 110.34 6.42 3 6 0 103.97 7.12 3 6 0 103.67 6.22 -3 6 0 109.14 7.19 -4 -6 0 50.51 3.47 4 -6 0 52.97 3.87 4 -6 0 49.96 3.50 4 -6 0 50.48 3.87 4 -6 0 52.57 3.18 -4 -6 0 47.12 3.36 -4 6 0 50.64 3.26 -4 6 0 48.40 3.86 -4 6 0 53.34 3.48 -4 6 0 53.20 3.85 4 6 0 53.41 3.21 4 6 0 57.96 3.86 5 -6 0 10.28 1.30 5 -6 0 8.44 1.58 5 -6 0 10.60 1.64 5 -6 0 10.90 1.56 -5 -6 0 11.12 1.51 5 6 0 13.32 1.10 5 6 0 14.08 1.57 -5 6 0 10.27 1.63 5 6 0 14.32 1.37 -5 6 0 13.40 1.81 -5 6 0 14.23 1.63 6 -6 0 65.71 5.00 6 -6 0 71.84 4.24 -6 -6 0 72.41 4.52 6 -6 0 73.63 4.57 6 -6 0 67.78 5.09 6 6 0 66.95 4.92 -6 6 0 64.94 4.20 6 6 0 66.25 3.90 -6 6 0 62.78 4.53 -6 6 0 67.28 5.05 6 6 0 65.54 4.20 -6 6 0 65.74 4.38 -6 6 0 62.62 4.96 6 6 0 67.53 4.90 7 -6 0 44.50 3.08 -7 -6 0 41.25 3.29 7 -6 0 44.60 3.06 7 -6 0 40.21 3.35 -7 6 0 42.24 3.09 7 6 0 41.80 2.84 -7 6 0 40.05 3.62 7 6 0 38.63 3.54 -7 6 0 41.61 3.10 8 -6 0 42.92 3.52 8 -6 0 45.26 3.26 -8 -6 0 42.51 3.57 8 -6 0 46.41 3.22 -8 6 0 39.44 3.51 8 6 0 36.83 3.03 -8 6 0 34.83 3.10 -8 6 0 39.02 3.05 8 6 0 41.70 3.71 9 -6 0 32.57 2.75 9 -6 0 26.82 2.53 -9 -6 0 25.77 2.62 9 -6 0 28.41 2.84 -9 6 0 21.53 2.66 9 6 0 23.14 2.41 -9 6 0 19.71 2.27 -10 -6 0 -0.54 1.66 10 -6 0 2.01 2.02 10 -6 0 -0.32 1.76 10 -6 0 0.12 1.93 10 6 0 -1.20 1.79 -10 6 0 0.14 1.79 11 -6 0 11.55 2.44 11 -6 0 12.06 2.34 -11 -6 0 9.19 2.21 11 -6 0 14.45 2.60 11 6 0 11.91 2.34 -11 6 0 12.10 2.88 -12 -6 0 19.78 2.85 12 -6 0 18.47 3.03 12 -6 0 19.48 3.05 12 -6 0 18.80 3.01 -12 6 0 21.22 3.17 12 6 0 25.85 3.00 0 -7 0 0.15 0.59 0 -7 0 -0.05 0.65 0 7 0 0.05 0.68 0 7 0 -0.13 0.62 0 7 0 0.03 0.55 0 7 0 -0.08 0.69 0 7 0 -0.13 0.70 1 -7 0 46.87 3.18 -1 -7 0 47.73 2.84 1 -7 0 46.43 2.74 1 -7 0 44.42 2.91 1 -7 0 40.65 3.25 -1 -7 0 44.85 2.92 -1 -7 0 48.48 3.06 1 7 0 42.61 3.18 -1 7 0 42.83 3.27 -1 7 0 43.29 2.92 -1 7 0 43.63 3.26 1 7 0 43.64 2.56 -1 7 0 44.60 2.71 1 7 0 42.68 2.81 1 7 0 41.20 2.80 1 7 0 45.43 2.54 1 7 0 44.55 3.16 2 -7 0 29.24 2.53 -2 -7 0 27.62 2.12 2 -7 0 30.14 2.05 2 -7 0 32.99 2.36 2 -7 0 32.00 2.37 -2 -7 0 30.14 2.14 -2 7 0 27.36 2.53 -2 7 0 29.40 2.08 2 7 0 31.33 2.30 -2 7 0 28.79 2.42 2 7 0 32.13 2.37 -2 7 0 31.41 2.33 2 7 0 29.78 2.11 2 7 0 29.96 2.03 -3 -7 0 186.97 10.37 3 -7 0 179.68 9.80 3 -7 0 176.80 11.70 3 -7 0 185.31 10.50 -3 -7 0 185.54 10.34 3 -7 0 177.04 9.85 3 -7 0 183.15 9.79 3 -7 0 194.25 11.77 3 7 0 171.40 11.64 -3 7 0 174.71 9.95 -3 7 0 170.09 11.73 3 7 0 172.62 10.21 -3 7 0 188.64 11.76 -3 7 0 176.97 10.43 4 -7 0 57.78 4.57 4 -7 0 55.87 4.64 4 -7 0 60.46 4.24 4 -7 0 57.68 3.72 -4 -7 0 59.52 4.05 4 7 0 66.03 3.83 -4 7 0 64.85 4.23 -4 7 0 61.78 4.69 4 7 0 72.01 4.58 -4 7 0 69.74 4.71 -4 7 0 65.55 3.90 -5 -7 0 282.87 15.99 5 -7 0 283.67 18.05 5 -7 0 284.38 15.23 5 -7 0 279.71 18.05 5 -7 0 266.67 16.03 5 7 0 274.39 15.02 5 7 0 279.20 15.75 -5 7 0 267.17 18.02 -5 7 0 293.77 16.08 -5 7 0 273.58 18.04 5 7 0 283.31 17.98 6 -7 0 42.76 3.41 6 -7 0 41.61 3.08 6 -7 0 44.57 3.70 -6 -7 0 43.81 3.33 6 -7 0 39.00 3.70 -6 7 0 48.99 3.52 -6 7 0 46.55 3.76 6 7 0 45.85 2.78 6 7 0 48.88 3.65 -6 7 0 41.97 3.15 -6 7 0 46.01 3.81 7 -7 0 32.34 2.54 7 -7 0 26.17 2.69 -7 -7 0 26.26 2.53 -7 7 0 25.73 2.21 7 7 0 26.31 2.20 7 7 0 28.18 2.81 -7 7 0 24.07 2.58 -7 7 0 23.49 2.43 8 -7 0 13.43 2.08 -8 -7 0 10.68 1.83 8 -7 0 10.90 1.74 -8 7 0 12.20 2.11 8 7 0 13.50 1.66 -8 7 0 13.47 1.82 -8 7 0 13.41 1.70 8 7 0 13.05 2.07 -9 -7 0 5.10 1.70 9 -7 0 2.33 1.76 9 -7 0 4.57 1.84 -9 7 0 7.21 1.97 9 7 0 5.30 1.71 -9 7 0 7.92 1.72 10 -7 0 45.03 3.86 -10 -7 0 37.20 3.54 10 -7 0 35.90 3.59 -10 7 0 29.84 3.47 10 7 0 34.16 3.45 -10 7 0 38.94 3.17 11 -7 0 6.85 2.72 11 -7 0 8.93 2.20 -11 -7 0 8.83 2.18 11 7 0 11.46 2.29 -11 7 0 12.51 2.96 0 -8 0 94.49 6.32 0 -8 0 97.34 5.77 0 8 0 96.38 6.46 0 8 0 97.90 5.39 0 8 0 96.59 5.50 0 8 0 97.34 5.70 0 8 0 93.66 6.38 -1 -8 0 205.31 10.78 1 -8 0 197.58 10.25 1 -8 0 207.30 12.12 1 -8 0 184.36 10.79 1 -8 0 201.00 12.06 -1 -8 0 199.12 11.94 -1 8 0 180.61 10.24 -1 8 0 176.42 12.07 1 8 0 182.70 12.06 1 8 0 181.75 10.27 -1 8 0 167.57 12.08 1 8 0 180.49 10.66 1 8 0 185.32 10.14 1 8 0 170.34 11.98 2 -8 0 140.81 9.93 2 -8 0 145.18 9.87 2 -8 0 147.22 8.35 -2 -8 0 149.74 8.77 2 -8 0 138.72 8.86 2 8 0 152.40 9.78 2 8 0 156.73 8.22 2 8 0 157.94 9.89 2 8 0 156.35 8.20 -2 8 0 168.82 9.98 -2 8 0 152.57 8.44 -2 8 0 150.94 9.98 2 8 0 149.49 8.67 3 -8 0 17.60 1.11 3 -8 0 16.04 1.84 -3 -8 0 19.23 1.61 3 -8 0 17.19 1.63 3 -8 0 19.47 1.53 3 -8 0 17.58 1.85 3 -8 0 17.47 1.16 -3 8 0 13.33 1.63 3 8 0 13.28 1.09 3 8 0 14.38 1.36 -3 8 0 11.88 1.48 3 8 0 12.21 1.51 3 8 0 12.14 1.05 -3 8 0 13.56 1.43 3 8 0 12.32 1.52 -3 8 0 13.78 1.69 4 -8 0 41.12 3.12 4 -8 0 42.10 3.25 4 -8 0 39.07 2.58 -4 -8 0 38.95 2.75 4 -8 0 39.79 3.23 4 -8 0 40.89 2.45 4 8 0 35.67 2.51 -4 8 0 34.38 2.72 -4 8 0 35.02 3.04 -4 8 0 37.06 3.29 4 8 0 33.89 3.02 -4 8 0 37.26 3.22 4 8 0 36.73 2.24 5 -8 0 17.82 1.92 5 -8 0 14.86 1.95 -5 -8 0 16.61 1.76 5 -8 0 14.27 1.80 5 -8 0 15.26 1.45 -5 8 0 14.18 1.89 -5 8 0 14.71 1.97 -5 8 0 14.11 2.13 5 8 0 16.33 1.37 5 8 0 14.23 1.87 -5 8 0 14.27 1.66 -6 -8 0 6.36 1.46 6 -8 0 6.22 1.76 6 -8 0 5.53 1.28 6 8 0 3.61 1.33 -6 8 0 3.94 1.71 -6 8 0 2.93 1.49 6 8 0 1.80 0.85 -7 -8 0 49.63 3.71 7 -8 0 48.25 3.42 7 -8 0 45.85 4.01 -7 8 0 50.63 3.92 -7 8 0 47.82 3.50 7 8 0 45.13 3.20 7 8 0 49.45 4.05 -7 8 0 50.43 3.57 8 -8 0 45.91 3.48 8 -8 0 47.48 3.92 -8 -8 0 46.66 3.74 -8 8 0 41.80 3.94 -8 8 0 44.46 3.54 8 8 0 50.85 4.16 8 8 0 48.72 3.36 9 -8 0 19.85 2.86 9 -8 0 18.51 2.22 -9 -8 0 18.25 2.47 -9 8 0 17.00 2.52 -9 8 0 14.63 2.31 -10 -8 0 20.62 2.85 10 -8 0 23.67 3.33 10 -8 0 21.85 2.65 -10 8 0 29.55 2.56 -10 8 0 29.13 3.49 11 -8 0 8.44 2.84 -11 -8 0 8.95 2.43 11 -8 0 7.18 2.25 -11 8 0 8.82 2.55 0 -9 0 1.12 0.92 0 -9 0 0.04 0.71 0 9 0 0.34 0.79 0 9 0 -0.45 0.74 0 9 0 1.02 0.89 0 9 0 -0.41 0.90 1 -9 0 11.38 1.44 1 -9 0 12.13 1.34 1 -9 0 11.30 1.34 -1 -9 0 11.23 1.41 1 -9 0 11.82 1.16 1 9 0 12.34 1.27 1 9 0 11.52 1.39 -1 9 0 12.94 1.49 1 9 0 12.70 1.48 -1 9 0 13.35 1.27 -1 9 0 13.27 1.41 1 9 0 12.71 1.22 -1 9 0 12.11 1.45 2 -9 0 119.66 8.34 2 -9 0 125.02 8.43 2 -9 0 120.94 7.57 2 -9 0 113.31 7.05 -2 -9 0 123.68 7.46 -2 9 0 131.34 8.47 -2 9 0 132.03 7.56 -2 9 0 131.28 7.14 2 9 0 129.54 8.27 2 9 0 129.36 8.38 2 9 0 130.30 6.93 2 9 0 126.89 7.33 3 -9 0 5.90 1.26 3 -9 0 7.50 1.06 3 -9 0 6.70 1.31 3 -9 0 3.47 1.37 -3 -9 0 5.92 1.20 3 9 0 5.49 1.19 3 9 0 5.30 0.72 -3 9 0 5.97 1.18 -3 9 0 6.24 1.31 -3 9 0 5.26 1.35 3 9 0 5.02 0.93 -3 9 0 5.10 1.29 4 -9 0 253.65 14.75 -4 -9 0 253.58 14.60 4 -9 0 251.66 13.74 4 -9 0 245.32 16.47 4 -9 0 227.12 16.49 -4 9 0 252.23 14.72 4 9 0 261.67 16.49 4 9 0 253.41 13.75 -4 9 0 252.50 14.07 -4 9 0 276.35 16.62 -4 9 0 276.76 16.62 5 -9 0 -0.95 1.15 5 -9 0 0.60 1.32 -5 -9 0 0.18 1.02 5 -9 0 0.78 0.88 5 -9 0 -0.16 0.98 -5 9 0 0.51 1.45 5 9 0 1.31 0.78 -5 9 0 -0.15 1.38 5 9 0 0.80 1.17 6 -9 0 84.37 5.99 -6 -9 0 85.96 5.68 6 -9 0 93.10 5.26 6 9 0 88.75 5.15 6 9 0 93.49 6.48 -6 9 0 87.14 5.59 -6 9 0 89.19 6.06 7 -9 0 10.70 1.89 -7 -9 0 9.73 1.78 7 -9 0 8.50 1.52 -7 9 0 6.62 1.65 -7 9 0 8.19 1.87 7 9 0 3.84 1.57 8 -9 0 18.99 2.14 8 -9 0 16.65 2.50 -8 -9 0 21.29 2.28 -8 9 0 19.66 2.88 -8 9 0 20.98 2.34 9 -9 0 8.55 2.18 -9 -9 0 9.35 1.90 9 -9 0 8.42 1.80 -9 9 0 5.93 2.00 -9 9 0 3.98 2.06 10 -9 0 7.04 2.10 -10 -9 0 6.33 2.18 10 -9 0 6.03 2.65 -10 9 0 5.21 2.11 -10 9 0 7.31 2.31 -11 -9 0 21.04 3.04 11 -9 0 28.81 3.75 11 -9 0 26.07 2.77 -11 9 0 21.44 3.64 0 -10 0 123.22 7.89 0 10 0 135.10 8.91 0 10 0 136.51 8.83 0 10 0 136.36 7.46 0 10 0 133.52 7.84 -1 -10 0 74.22 5.46 1 -10 0 78.93 6.01 1 -10 0 80.31 5.60 1 10 0 94.30 5.44 -1 10 0 96.31 6.26 1 10 0 92.00 6.12 -1 10 0 96.45 6.31 1 10 0 92.99 6.15 -1 10 0 94.29 5.56 1 10 0 95.20 5.11 -1 10 0 90.96 5.23 2 -10 0 153.41 10.00 2 -10 0 129.90 10.06 2 -10 0 143.67 9.04 2 -10 0 146.80 8.46 -2 -10 0 142.88 8.89 2 10 0 157.27 8.36 2 10 0 158.34 10.05 -2 10 0 164.98 10.14 2 10 0 156.09 8.80 -2 10 0 158.72 8.59 -2 10 0 156.00 10.19 -2 10 0 155.00 9.03 -3 -10 0 12.18 1.49 3 -10 0 9.79 1.26 3 -10 0 10.76 1.55 3 -10 0 11.59 1.65 3 -10 0 10.84 1.72 -3 10 0 10.83 1.64 -3 10 0 9.19 1.78 3 10 0 8.94 1.00 3 10 0 10.01 1.53 -3 10 0 10.62 1.84 -3 10 0 10.10 1.46 4 -10 0 16.18 2.15 -4 -10 0 18.99 1.91 4 -10 0 16.83 2.32 4 -10 0 16.03 1.67 4 -10 0 18.79 2.12 -4 10 0 19.07 1.92 4 10 0 19.25 2.20 4 10 0 18.90 1.53 -4 10 0 18.74 2.15 5 -10 0 15.05 1.97 5 -10 0 12.32 1.56 -5 -10 0 14.81 1.79 -5 10 0 14.01 1.90 -5 10 0 14.53 1.82 5 10 0 13.98 1.90 6 -10 0 5.01 1.67 6 -10 0 4.58 1.31 6 -10 0 5.51 1.15 -6 -10 0 3.87 1.50 -6 10 0 7.43 1.69 -6 10 0 12.31 2.14 6 10 0 9.92 1.90 7 -10 0 22.64 2.23 -7 -10 0 23.03 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6.22 1.14 -7 3 4 5.64 1.48 7 3 -4 5.03 1.67 6 -3 -4 70.43 5.08 -6 -3 4 69.33 4.71 6 -3 -4 67.09 5.15 6 -3 -4 69.09 4.58 -6 -3 4 71.82 4.03 6 -3 -4 72.80 4.15 6 -3 -4 71.03 5.07 6 3 -4 65.78 4.29 6 3 -4 67.67 5.11 -6 3 4 62.69 4.58 6 3 -4 64.31 4.68 5 -3 -4 18.87 1.58 -5 -3 4 16.12 1.87 -5 -3 4 19.64 1.59 5 -3 -4 19.33 2.14 5 -3 -4 20.77 2.16 5 -3 -4 19.14 2.01 5 -3 -4 20.98 1.95 5 3 -4 19.14 2.11 -5 3 4 16.07 1.88 5 3 -4 15.60 1.77 5 3 -4 17.75 1.67 -5 3 4 16.59 1.60 -4 -3 4 271.18 19.16 4 -3 -4 303.09 17.02 -4 -3 4 300.71 16.20 4 -3 -4 299.04 19.11 -4 -3 4 309.65 17.17 4 -3 -4 292.08 19.14 4 -3 -4 287.23 19.16 4 -3 -4 298.18 16.11 4 3 -4 294.47 17.08 -4 3 4 299.09 17.06 4 3 -4 327.25 19.29 -4 3 4 299.20 16.25 4 3 -4 306.68 16.31 3 -3 -4 21.56 1.80 -3 -3 4 18.60 1.84 -3 -3 4 22.70 1.53 3 -3 -4 21.85 1.82 3 -3 -4 21.80 1.72 -3 -3 4 18.75 1.82 3 -3 -4 20.01 1.73 3 3 -4 17.99 1.83 3 3 -4 13.15 1.47 3 3 -4 14.42 1.55 -3 3 4 13.93 1.48 -3 3 4 14.32 1.48 2 -3 -4 88.56 5.87 2 -3 -4 83.75 5.75 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7.65 1 4 -4 147.44 8.06 -1 4 4 144.63 8.92 -1 4 4 143.99 7.91 0 -4 -4 54.36 3.01 0 -4 4 52.12 3.18 0 -4 -4 52.52 2.93 0 -4 -4 52.02 2.91 0 -4 4 50.36 3.56 0 -4 -4 50.97 3.22 0 4 -4 47.84 3.46 0 4 4 46.67 3.19 0 4 4 45.44 3.17 0 4 4 45.38 2.78 0 4 -4 46.24 3.14 0 4 4 46.75 3.11 0 4 4 43.35 2.95 0 4 -4 47.08 2.99 1 -4 4 258.78 14.75 1 -4 4 263.28 14.07 -1 -4 -4 246.29 16.21 -1 -4 -4 260.57 14.45 -1 -4 -4 263.71 14.07 -1 -4 -4 255.75 14.45 1 -4 4 243.58 16.54 -1 4 -4 259.41 14.08 1 4 4 263.23 14.06 -1 4 -4 257.69 14.72 -1 4 -4 276.74 16.58 1 4 4 262.63 15.23 2 -4 4 102.35 6.90 2 -4 4 98.94 5.84 2 -4 4 103.02 6.18 2 4 4 107.61 5.89 -2 4 -4 101.06 6.93 -2 4 -4 105.54 6.17 2 4 4 104.24 6.43 -2 4 -4 107.66 5.83 -2 4 -4 102.19 6.89 -3 -4 -4 73.30 3.96 3 -4 4 80.32 4.93 3 -4 4 75.56 4.95 -3 -4 -4 73.03 3.97 3 -4 4 75.10 4.40 3 -4 4 75.36 4.14 3 4 4 59.71 4.54 -3 4 -4 62.66 4.40 -3 4 -4 60.59 3.98 -3 4 -4 64.21 4.85 -3 4 -4 61.18 4.90 4 -4 4 19.11 2.02 4 -4 4 19.69 1.79 -4 -4 -4 17.53 1.36 4 -4 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3.12 5 -5 -4 57.05 3.74 5 -5 -4 56.56 4.32 -5 -5 4 61.18 3.16 5 -5 -4 57.14 4.02 -5 -5 4 62.13 4.02 5 -5 -4 61.43 4.13 5 5 -4 43.67 4.13 5 5 -4 44.39 3.79 5 5 -4 42.49 3.45 -5 5 4 44.61 3.53 4 -5 -4 114.80 6.76 -4 -5 4 111.25 7.56 4 -5 -4 108.95 7.42 -4 -5 4 116.83 6.91 -4 -5 4 115.15 6.20 4 -5 -4 116.71 7.53 4 -5 -4 117.58 7.56 4 5 -4 103.20 6.38 4 5 -4 108.91 6.80 4 5 -4 108.91 7.63 -4 5 4 106.83 6.75 -4 5 4 108.96 6.34 3 -5 -4 108.57 6.90 3 -5 -4 107.55 6.28 3 -5 -4 115.12 6.99 -3 -5 4 101.46 7.14 -3 -5 4 107.99 6.44 -3 -5 4 102.44 5.85 3 -5 -4 106.80 7.04 3 5 -4 103.87 6.00 -3 5 4 97.68 6.26 -3 5 4 103.18 6.13 3 5 -4 103.79 7.14 -3 5 4 103.76 5.89 3 5 -4 100.01 6.36 2 -5 -4 63.69 3.98 2 -5 -4 62.74 3.90 -2 -5 4 60.71 4.15 -2 -5 4 63.18 4.57 2 -5 -4 65.47 4.27 2 -5 -4 62.07 4.31 2 -5 -4 60.98 4.43 -2 -5 4 64.26 3.80 -2 -5 4 57.83 4.15 2 5 -4 71.84 4.65 -2 5 4 63.49 3.61 2 5 -4 67.31 4.12 -2 5 4 69.48 3.95 2 5 -4 69.03 3.90 -2 5 4 62.28 4.41 -2 5 4 68.06 3.64 -2 5 4 66.84 4.00 1 -5 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3.39 -5 8 -4 39.57 3.12 5 8 4 41.84 3.01 -5 8 -4 41.16 3.45 6 -8 4 59.45 4.54 -6 -8 -4 59.13 3.61 6 -8 4 58.88 3.96 6 8 4 54.11 4.08 -6 8 -4 54.82 3.84 -6 8 -4 56.11 4.55 7 -8 4 21.64 2.94 -7 -8 -4 26.90 2.44 7 -8 4 26.08 2.65 -7 8 -4 30.95 2.58 7 8 4 30.07 2.68 -7 8 -4 28.09 3.09 8 -8 4 24.51 2.56 -8 -8 -4 25.16 2.43 8 -8 4 27.58 2.90 -8 8 -4 23.79 3.09 8 8 4 22.08 2.43 9 -8 4 18.64 2.64 9 -8 4 20.12 2.66 -9 8 -4 17.51 2.72 10 -8 4 18.68 3.16 10 -8 4 18.26 2.59 -10 8 -4 15.52 3.19 -11 -9 4 0.23 2.31 11 -9 -4 3.43 2.38 -11 9 4 5.92 2.40 11 9 -4 5.69 2.29 -11 9 4 2.58 2.79 -10 -9 4 14.49 2.68 10 -9 -4 12.72 2.65 10 9 -4 13.38 2.62 -10 9 4 12.69 2.97 -10 9 4 13.82 2.44 9 -9 -4 6.86 2.14 -9 -9 4 4.44 2.19 9 9 -4 8.04 2.27 -9 9 4 4.02 2.19 -9 9 4 4.43 2.36 8 -9 -4 2.13 1.74 -8 -9 4 4.38 2.05 -8 9 4 5.62 1.85 8 9 -4 6.11 2.01 -8 9 4 4.02 2.04 7 -9 -4 89.20 6.02 -7 -9 4 80.45 6.15 -7 9 4 89.74 6.20 -7 9 4 92.34 5.83 7 9 -4 91.04 5.70 6 -9 -4 4.47 1.65 -6 -9 4 2.79 1.59 6 -9 -4 3.10 1.44 6 9 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10 5 67.49 4.86 -1 10 -5 63.94 4.36 1 10 5 64.19 4.53 2 -10 5 7.42 1.81 2 -10 5 9.17 1.44 -2 -10 -5 10.17 0.98 2 10 5 15.32 1.36 -2 10 -5 16.44 2.03 -2 10 -5 15.81 1.84 3 -10 5 34.61 3.31 3 -10 5 33.45 2.88 3 10 5 37.19 2.64 -3 10 -5 44.02 3.13 -3 10 -5 38.91 3.61 4 -10 5 37.04 2.89 4 -10 5 33.96 3.22 -4 10 -5 33.06 2.93 4 10 5 32.01 2.45 -4 10 -5 33.05 3.30 5 -10 5 30.93 3.23 5 -10 5 34.19 2.98 -5 10 -5 31.25 3.36 -5 10 -5 33.25 2.86 5 10 5 30.16 2.46 6 -10 5 32.05 3.45 6 -10 5 29.50 2.81 -6 10 -5 35.55 3.12 6 10 5 31.95 2.68 -6 10 -5 30.18 3.44 7 -10 5 15.27 2.13 7 -10 5 20.30 2.65 -7 10 -5 10.19 2.40 -7 10 -5 10.03 1.93 8 -10 5 6.06 2.21 8 -10 5 7.20 2.19 -8 10 -5 7.98 2.80 9 -10 5 4.54 2.75 9 -10 5 8.01 2.39 -9 10 -5 3.69 2.37 -9 -11 5 3.17 2.37 9 -11 -5 2.51 2.52 -9 11 5 2.30 2.15 9 11 -5 0.75 2.13 8 -11 -5 2.38 2.29 -8 -11 5 2.59 2.35 -8 -11 5 -0.71 2.20 8 11 -5 0.66 1.96 -8 11 5 -0.55 2.03 -7 -11 5 60.23 4.81 7 -11 -5 56.65 4.58 7 -11 -5 64.11 4.45 -7 -11 5 58.39 5.02 -7 11 5 59.72 4.70 7 11 -5 56.05 4.37 6 -11 -5 1.99 1.56 -6 -11 5 2.16 2.15 6 -11 -5 2.33 1.89 -6 11 5 4.27 1.77 6 11 -5 4.56 1.83 -5 -11 5 127.47 8.15 5 -11 -5 132.03 8.87 5 -11 -5 125.67 7.95 5 -11 -5 132.47 7.64 5 11 -5 118.16 7.55 -5 11 5 118.57 7.53 -4 -11 5 1.03 1.94 4 -11 -5 -0.01 1.52 4 -11 -5 1.72 1.40 4 -11 -5 0.34 1.44 4 11 -5 2.31 1.56 -4 11 5 1.30 1.51 4 11 -5 2.44 1.43 3 -11 -5 167.25 10.54 3 -11 -5 163.68 9.18 -3 -11 5 165.02 9.85 3 -11 -5 160.67 9.44 -3 11 5 156.39 8.97 3 11 -5 144.38 9.07 3 11 -5 147.89 9.53 -3 11 5 157.18 10.62 -2 -11 5 4.18 1.64 2 -11 -5 3.83 1.23 2 -11 -5 4.51 1.26 2 -11 -5 7.23 1.75 2 11 -5 5.67 1.87 2 11 -5 6.72 1.61 -2 11 5 6.06 1.43 1 -11 -5 18.51 1.90 1 -11 -5 21.30 2.04 1 -11 -5 19.48 2.10 -1 -11 5 17.63 2.27 1 11 -5 18.41 2.20 -1 11 5 17.50 2.12 -1 11 5 20.35 2.29 1 11 -5 22.06 2.27 0 -11 -5 16.66 1.58 0 -11 5 12.60 2.05 0 11 5 18.36 2.15 0 11 5 17.21 1.91 0 11 -5 16.26 1.98 0 11 -5 15.22 2.29 1 -11 5 10.14 1.29 -1 -11 -5 9.81 1.16 1 -11 5 11.15 1.93 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12 -5 7.74 2.24 5 -12 -5 1.72 1.78 -5 -12 5 5.26 1.90 5 -12 -5 3.18 1.58 5 12 -5 -0.95 1.69 -5 12 5 0.34 1.79 -4 -12 5 6.30 2.19 4 -12 -5 4.68 1.49 4 -12 -5 5.85 1.59 4 -12 -5 6.91 1.98 4 12 -5 2.97 1.73 -4 12 5 3.10 1.69 -3 -12 5 15.80 2.28 3 -12 -5 16.52 2.10 3 -12 -5 17.73 2.20 3 -12 -5 16.26 2.27 -3 12 5 14.50 1.92 3 12 -5 13.87 2.32 3 12 -5 14.87 2.08 -2 -12 5 12.48 2.10 2 -12 -5 12.50 1.84 2 -12 -5 13.30 2.11 2 -12 -5 13.74 1.74 2 12 -5 14.01 1.98 -2 12 5 12.75 1.90 2 12 -5 11.29 2.20 1 -12 -5 98.56 5.67 -1 -12 5 90.28 6.23 1 -12 -5 93.98 5.74 1 -12 -5 91.20 6.18 1 12 -5 82.74 6.10 -1 12 5 85.91 6.29 1 12 -5 85.82 5.66 0 -12 -5 21.14 2.14 0 -12 5 19.51 2.51 0 12 -5 24.40 2.42 0 12 -5 23.41 2.52 0 12 5 25.60 2.42 1 -12 5 113.21 7.07 -1 -12 -5 112.15 6.36 1 12 5 108.10 7.21 -1 12 -5 100.86 7.10 -1 12 -5 98.14 6.60 2 -12 5 15.45 2.34 -2 12 -5 17.08 2.18 -2 12 -5 15.15 2.29 2 12 5 16.99 1.83 3 -12 5 10.54 1.53 3 -12 5 7.65 2.06 -3 12 -5 10.80 2.00 3 12 5 10.75 1.34 -3 12 -5 9.02 2.41 4 -12 5 37.78 3.00 4 -12 5 37.99 3.66 -4 12 -5 40.86 3.78 -4 12 -5 38.23 3.54 4 12 5 37.21 2.90 5 -12 5 17.98 3.03 5 -12 5 23.50 2.27 -5 12 -5 21.01 3.13 -5 12 -5 20.88 2.61 6 -12 5 31.74 3.39 6 -12 5 26.82 2.61 -6 12 -5 30.02 3.65 -6 12 -5 31.67 2.98 7 -12 5 37.26 3.79 7 -12 5 30.29 2.96 -7 12 -5 36.06 3.32 -7 12 -5 37.09 3.78 -8 -13 5 0.96 2.55 8 -13 -5 3.41 2.50 8 13 -5 4.61 2.21 -7 -13 5 3.80 2.53 7 -13 -5 3.56 1.96 7 13 -5 2.68 2.05 -7 13 5 3.79 2.21 -6 -13 5 48.34 4.69 6 -13 -5 48.87 4.35 6 -13 -5 50.47 4.03 -6 13 5 48.69 4.10 6 13 -5 46.25 4.20 5 -13 -5 17.53 2.52 -5 -13 5 17.55 2.59 5 -13 -5 17.36 2.50 -5 13 5 18.46 2.34 5 13 -5 15.92 2.38 4 -13 -5 32.85 3.22 4 -13 -5 30.02 3.12 -4 -13 5 36.23 3.45 4 -13 -5 29.89 3.04 -4 13 5 37.11 3.21 4 13 -5 32.29 3.13 3 -13 -5 44.90 3.43 -3 -13 5 43.27 4.01 3 -13 -5 37.53 3.32 -3 13 5 36.58 3.28 3 13 -5 32.85 3.32 2 -13 -5 51.49 4.07 -2 -13 5 58.08 4.72 2 -13 -5 58.33 4.33 2 13 -5 54.46 4.07 -1 -13 5 22.78 2.83 1 -13 -5 22.44 2.18 -1 13 5 16.13 2.31 1 13 -5 19.75 2.43 1 13 -5 20.54 2.36 0 -13 -5 19.07 1.86 0 -13 5 16.21 2.68 0 13 5 17.82 2.08 0 13 -5 13.33 2.22 0 13 -5 20.29 2.41 1 -13 5 15.15 2.48 -1 -13 -5 17.59 1.77 -1 13 -5 22.40 2.58 1 13 5 22.33 2.39 -1 13 -5 25.42 2.60 2 -13 5 8.85 2.10 2 13 5 6.94 1.39 -2 13 -5 7.53 2.33 -2 13 -5 6.21 1.92 3 -13 5 20.61 2.78 -3 13 -5 23.47 3.15 -3 13 -5 25.85 2.66 4 -13 5 32.19 3.69 -4 13 -5 34.37 3.28 -4 13 -5 36.67 3.76 5 -13 5 3.35 2.56 -5 13 -5 2.81 2.12 -5 13 -5 5.44 2.22 6 -13 5 13.52 3.01 -6 13 -5 7.50 2.49 -6 13 -5 10.08 2.35 7 -13 5 1.32 2.31 -7 13 -5 0.20 2.26 -7 13 -5 -1.06 2.10 7 -14 -5 0.47 2.34 -7 -14 5 0.47 2.48 -7 14 5 0.75 2.23 7 14 -5 0.42 2.11 6 -14 -5 20.05 2.93 -6 -14 5 16.53 3.09 -6 14 5 24.20 3.02 6 14 -5 21.86 2.76 -5 -14 5 2.05 1.96 5 -14 -5 2.06 2.25 5 14 -5 3.73 2.06 -5 14 5 2.28 2.15 4 -14 -5 4.17 1.76 4 -14 -5 3.05 1.83 -4 -14 5 0.42 2.28 -4 14 5 2.60 1.91 4 14 -5 3.68 1.98 -3 -14 5 31.57 3.27 3 -14 -5 32.11 2.99 3 -14 -5 29.23 2.89 3 -14 -5 30.44 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59.30 3.74 -5 3 9 58.08 3.89 -4 -3 9 89.54 6.96 -4 -3 9 95.45 6.51 -4 -3 9 94.56 5.76 4 -3 -9 97.51 5.85 4 -3 -9 97.37 6.24 -4 3 9 92.99 6.95 4 3 -9 97.22 6.31 -4 3 9 96.66 6.22 -4 3 9 94.08 5.72 4 3 -9 96.58 5.57 -3 -3 9 27.94 2.85 -3 -3 9 28.34 2.76 3 -3 -9 26.78 2.74 -3 -3 9 27.77 3.26 3 -3 -9 21.93 2.36 -3 -3 9 24.51 2.46 3 -3 -9 23.78 2.11 -3 3 9 30.02 2.35 3 3 -9 33.04 2.87 -3 3 9 31.23 3.03 3 3 -9 33.85 2.91 3 3 -9 32.29 2.18 -3 3 9 32.62 2.88 -2 -3 9 57.72 3.91 2 -3 -9 65.40 3.90 2 -3 -9 62.81 4.13 -2 -3 9 65.24 4.26 2 -3 -9 62.59 3.93 2 3 -9 53.62 4.39 -2 3 9 56.66 4.53 2 3 -9 56.51 4.21 2 3 -9 54.39 3.54 -2 3 9 55.70 3.63 -2 3 9 56.65 3.90 1 -3 -9 59.11 4.31 1 -3 -9 59.18 4.21 1 -3 -9 63.70 4.07 -1 -3 9 59.20 4.48 -1 -3 9 62.27 4.13 -1 -3 9 68.33 4.93 1 3 -9 65.08 4.58 -1 3 9 66.74 3.77 1 3 -9 67.10 3.78 -1 3 9 64.11 4.70 0 -3 9 16.92 1.73 0 -3 -9 16.45 1.74 0 -3 9 15.60 1.76 0 -3 -9 16.77 1.59 0 -3 -9 16.04 1.84 0 -3 9 16.52 1.96 0 3 9 13.35 1.28 0 3 -9 12.04 1.96 0 3 -9 12.33 1.19 0 3 9 12.83 1.65 -1 -3 -9 94.18 5.79 1 -3 9 95.57 6.33 1 -3 9 88.19 5.25 -1 -3 -9 92.60 5.32 1 -3 9 88.41 5.48 -1 3 -9 72.53 6.20 -1 3 -9 77.07 5.51 1 3 9 82.95 5.93 -2 -3 -9 47.60 3.58 2 -3 9 44.74 3.82 2 -3 9 44.58 3.13 2 -3 9 46.44 3.41 -2 -3 -9 44.24 3.08 -2 -3 -9 42.09 3.24 -2 3 -9 43.80 3.69 -2 3 -9 43.36 3.38 2 3 9 42.81 3.38 -3 -3 -9 100.31 6.50 3 -3 9 99.21 5.79 -3 -3 -9 97.71 5.78 -3 -3 -9 99.67 6.38 3 -3 9 94.54 6.86 3 -3 9 96.26 6.09 3 3 9 85.94 6.43 -3 3 -9 96.56 6.81 -3 3 -9 91.93 6.07 -4 -3 -9 26.62 2.15 4 -3 9 27.20 2.75 -4 -3 -9 25.35 2.22 4 -3 9 24.88 2.28 -4 3 -9 21.96 2.51 4 3 9 21.65 2.32 -4 3 -9 24.57 2.78 5 -3 9 28.91 3.36 5 -3 9 31.19 2.97 -5 -3 -9 28.93 2.55 -5 -3 -9 30.16 2.54 5 3 9 32.14 2.80 -5 3 -9 33.84 3.18 -6 -3 -9 24.63 2.45 6 -3 9 27.97 2.58 -6 -3 -9 26.36 2.45 -6 3 -9 22.92 2.74 6 3 9 22.74 2.60 7 -3 9 0.61 1.86 -7 -3 -9 0.65 1.43 7 -3 9 0.56 1.82 -7 3 -9 0.40 1.89 8 -3 9 0.77 2.03 8 -3 9 1.06 2.07 -8 -3 -9 1.32 1.65 -8 3 -9 0.28 2.32 9 -3 9 35.34 3.33 9 -3 9 31.23 3.29 -9 3 -9 22.80 3.20 -11 -4 9 34.00 3.78 11 -4 -9 35.83 3.78 11 4 -9 30.26 3.32 -11 4 9 32.04 3.31 11 4 -9 27.72 3.79 -11 4 9 30.98 3.95 -10 -4 9 9.35 2.48 10 -4 -9 13.03 2.54 10 4 -9 6.61 2.71 10 4 -9 9.66 2.37 -10 4 9 9.83 2.77 -10 4 9 4.12 2.20 9 -4 -9 62.19 5.51 -9 -4 9 71.04 5.46 -9 -4 9 70.64 4.54 9 4 -9 77.76 5.42 9 4 -9 61.90 4.87 -9 4 9 67.31 5.37 -9 4 9 69.63 5.01 -8 -4 9 21.10 2.09 8 -4 -9 18.16 2.78 -8 -4 9 18.79 2.69 -8 4 9 14.42 2.21 -8 4 9 13.94 2.41 8 4 -9 12.17 2.21 8 4 -9 14.56 2.48 -7 -4 9 48.34 4.33 -7 -4 9 49.37 3.73 7 -4 -9 42.78 4.27 7 4 -9 50.75 3.86 -7 4 9 56.05 3.87 7 4 -9 53.00 4.52 -7 4 9 56.97 4.25 -6 -4 9 15.20 2.59 -6 -4 9 14.20 1.75 6 -4 -9 14.51 2.25 6 4 -9 8.97 1.99 6 4 -9 9.39 1.80 -6 4 9 6.85 1.73 -6 4 9 8.94 2.02 5 -4 -9 6.58 1.85 -5 -4 9 9.45 2.30 -5 -4 9 7.66 1.70 5 -4 -9 8.08 1.79 -5 4 9 4.70 1.66 5 4 -9 6.00 1.50 5 4 -9 4.84 1.76 -5 4 9 5.63 1.48 -4 -4 9 16.61 2.24 4 -4 -9 16.76 2.33 4 -4 -9 15.81 1.90 -4 -4 9 17.59 2.31 4 -4 -9 16.89 2.13 -4 -4 9 15.50 1.88 -4 4 9 17.40 1.82 -4 4 9 13.54 2.23 -4 4 9 17.56 2.18 4 4 -9 19.19 1.87 4 4 -9 15.70 2.19 3 -4 -9 24.74 2.39 3 -4 -9 26.09 2.82 -3 -4 9 25.82 2.93 -3 -4 9 27.30 2.80 3 -4 -9 24.69 2.57 -3 -4 9 24.05 2.36 -3 4 9 24.71 2.81 3 4 -9 24.95 2.73 3 4 -9 24.39 2.58 -3 4 9 22.61 2.25 3 4 -9 26.07 2.20 -3 4 9 26.45 2.44 -2 -4 9 68.50 4.94 -2 -4 9 61.60 4.12 2 -4 -9 61.69 4.22 2 -4 -9 59.44 4.21 -2 -4 9 66.47 4.48 2 -4 -9 60.71 4.08 2 4 -9 55.84 4.37 2 4 -9 63.93 4.85 2 4 -9 59.93 3.70 -2 4 9 62.12 4.64 -2 4 9 62.05 3.74 2 4 -9 59.43 3.74 -1 -4 9 67.31 4.70 1 -4 -9 66.89 4.29 1 -4 -9 67.47 4.33 1 -4 -9 69.09 4.47 -1 -4 9 66.48 4.21 1 4 -9 62.74 3.76 1 4 -9 63.26 4.96 -1 4 9 63.63 3.78 -1 4 9 63.64 4.79 1 4 -9 66.50 4.59 0 -4 9 55.49 3.64 0 -4 9 54.96 4.49 0 -4 -9 49.88 3.96 0 -4 -9 55.55 3.77 0 -4 -9 57.77 3.66 0 -4 9 54.41 3.89 0 4 9 51.93 3.97 0 4 -9 51.46 4.14 1 -4 9 102.38 5.95 -1 -4 -9 102.13 5.91 1 -4 9 97.31 6.30 -1 -4 -9 106.43 6.61 1 -4 9 93.19 6.96 1 4 9 99.87 6.64 -1 4 -9 87.64 7.06 -1 4 -9 99.84 6.39 -2 -4 -9 21.85 2.26 2 -4 9 20.44 1.91 -2 -4 -9 20.63 1.77 2 -4 9 17.75 2.36 -2 -4 -9 22.12 1.77 2 -4 9 19.03 2.16 2 4 9 14.81 1.83 -2 4 -9 13.43 2.14 -2 4 -9 16.57 2.25 -3 -4 -9 49.05 3.17 3 -4 9 48.28 4.17 -3 -4 -9 46.89 3.35 3 -4 9 48.33 3.44 3 -4 9 45.52 3.70 -3 -4 -9 45.30 4.10 -3 4 -9 47.21 3.66 3 4 9 48.83 3.49 -3 4 -9 47.81 4.24 -4 -4 -9 69.29 4.19 4 -4 9 70.34 5.40 4 -4 9 69.41 4.77 -4 -4 -9 72.89 4.57 4 -4 9 70.50 4.55 4 4 9 58.69 4.67 -4 4 -9 60.92 4.84 -5 -4 -9 19.81 1.98 -5 -4 -9 21.56 1.83 5 -4 9 22.11 2.19 5 4 9 17.05 1.93 -5 4 -9 17.49 2.47 6 -4 9 56.03 4.38 -6 -4 -9 60.16 3.93 -6 4 -9 58.60 4.67 7 -4 9 26.74 2.81 -7 4 -9 21.49 2.90 8 -4 9 32.70 3.17 -8 4 -9 33.13 3.50 9 -4 9 7.66 2.54 -9 4 -9 4.35 2.77 10 -5 -9 2.34 2.09 -10 -5 9 2.06 2.64 10 5 -9 -0.03 2.02 10 5 -9 -0.53 1.88 -10 5 9 1.36 2.16 -10 5 9 1.56 2.41 9 -5 -9 5.84 2.51 -9 -5 9 4.84 2.26 -9 5 9 10.36 2.35 -9 5 9 5.77 2.47 9 5 -9 5.06 2.49 9 5 -9 7.02 2.25 8 -5 -9 0.92 1.73 -8 -5 9 2.15 1.95 -8 -5 9 0.54 1.46 8 5 -9 2.40 1.73 -8 5 9 1.24 1.97 -8 5 9 2.46 2.10 8 5 -9 2.60 1.90 7 -5 -9 51.02 4.25 -7 -5 9 47.54 3.88 -7 -5 9 52.04 4.56 -7 5 9 53.81 4.01 7 5 -9 59.34 4.00 -7 5 9 54.93 4.62 7 5 -9 60.04 4.77 -6 -5 9 17.63 2.05 -6 -5 9 18.42 2.92 6 -5 -9 18.61 2.51 6 5 -9 17.41 2.07 6 5 -9 17.50 2.48 -6 5 9 16.21 2.20 -6 5 9 21.20 2.67 -5 -5 9 144.97 8.23 -5 -5 9 145.29 9.08 5 -5 -9 141.28 8.77 5 -5 -9 146.86 8.47 5 5 -9 148.38 8.98 -5 5 9 138.76 8.78 5 5 -9 134.91 8.26 -5 5 9 139.56 8.23 -4 -5 9 2.80 1.70 4 -5 -9 3.60 1.41 4 -5 -9 3.38 1.64 -4 -5 9 2.53 1.65 4 -5 -9 2.83 1.55 -4 -5 9 2.47 1.51 4 5 -9 5.08 1.47 4 5 -9 4.06 1.68 -4 5 9 5.33 1.40 3 -5 -9 67.32 4.34 3 -5 -9 69.61 4.58 3 -5 -9 62.05 4.87 -3 -5 9 69.29 4.78 -3 -5 9 68.63 4.21 3 5 -9 59.59 4.06 -3 5 9 55.86 4.89 3 5 -9 63.04 4.87 -3 5 9 62.34 4.00 -2 -5 9 0.71 1.46 2 -5 -9 2.74 1.19 2 -5 -9 0.66 1.46 -2 -5 9 2.37 1.28 2 -5 -9 3.00 1.22 -2 5 9 1.93 0.97 -2 5 9 1.86 1.28 2 5 -9 1.44 1.13 2 5 -9 0.77 1.68 -1 -5 9 0.30 1.37 -1 -5 9 -0.20 1.28 1 -5 -9 0.46 1.35 1 -5 -9 0.32 1.13 1 -5 -9 -0.84 1.10 -1 -5 9 -1.01 1.31 -1 5 9 -0.39 1.06 1 5 -9 0.68 0.99 1 5 -9 1.27 1.38 1 5 -9 2.10 1.55 0 -5 -9 41.82 3.03 0 -5 -9 44.93 3.18 0 -5 9 39.94 3.58 0 -5 9 41.91 3.12 0 5 -9 44.03 3.58 0 5 -9 41.56 2.66 0 5 -9 44.59 3.47 0 5 9 40.40 3.32 -1 -5 -9 11.78 1.34 1 -5 9 12.32 1.91 1 -5 9 11.25 1.74 1 -5 9 11.04 1.64 1 5 9 13.85 1.54 -1 5 -9 11.82 1.85 2 -5 9 50.55 4.22 -2 -5 -9 54.70 3.56 -2 -5 -9 60.12 3.85 -2 -5 -9 58.63 4.37 2 -5 9 53.01 4.58 2 -5 9 58.40 3.97 -2 5 -9 64.17 4.45 2 5 9 57.82 4.06 3 -5 9 19.03 2.13 -3 -5 -9 18.11 1.66 3 -5 9 19.74 2.33 -3 -5 -9 20.35 2.42 -3 -5 -9 18.91 1.50 3 5 9 20.50 1.86 -3 5 -9 17.83 2.42 -4 -5 -9 54.03 3.42 4 -5 9 52.13 3.91 4 5 9 57.83 3.92 -4 5 -9 53.59 4.34 5 -5 9 19.18 2.32 5 5 9 17.44 1.94 -5 5 -9 15.92 2.23 6 -5 9 11.99 2.01 -6 5 -9 10.29 2.41 7 -5 9 2.26 2.10 -7 5 -9 3.99 2.22 8 -5 9 16.34 2.48 -8 5 -9 12.24 2.72 -10 -6 9 6.40 2.83 10 -6 -9 4.55 2.32 10 6 -9 12.84 2.40 -10 6 9 8.38 2.51 10 6 -9 10.65 2.46 9 -6 -9 22.66 2.95 -9 -6 9 16.72 2.90 9 6 -9 25.80 3.37 9 6 -9 24.17 2.74 -9 6 9 22.37 2.72 -8 -6 9 29.25 3.58 8 -6 -9 32.36 3.61 -8 6 9 38.46 3.48 8 6 -9 36.57 3.74 8 6 -9 43.76 3.66 -7 -6 9 17.29 2.71 7 -6 -9 17.57 2.69 -7 -6 9 19.11 2.04 -7 6 9 18.91 2.45 7 6 -9 17.25 2.46 7 6 -9 19.46 2.93 6 -6 -9 15.92 2.13 6 -6 -9 14.60 2.39 -6 -6 9 14.50 2.78 -6 -6 9 13.44 1.82 -6 6 9 13.12 2.08 6 6 -9 13.48 2.14 6 6 -9 10.24 2.22 5 -6 -9 8.24 2.04 5 -6 -9 7.16 1.75 -5 -6 9 9.37 2.15 5 -6 -9 8.23 1.94 -5 -6 9 10.84 1.72 -5 -6 9 11.29 2.16 -5 6 9 6.92 1.71 5 6 -9 5.88 1.91 5 6 -9 5.08 1.75 -4 -6 9 19.91 2.56 4 -6 -9 19.01 2.24 4 -6 -9 19.78 2.41 -4 -6 9 18.41 2.10 4 -6 -9 19.00 2.20 4 6 -9 17.54 2.08 -4 6 9 20.55 2.05 4 6 -9 17.63 2.41 3 -6 -9 16.44 2.02 3 -6 -9 15.94 2.05 -3 -6 9 16.01 1.90 -3 -6 9 16.55 2.37 3 -6 -9 15.81 1.94 3 6 -9 18.57 2.55 -3 6 9 19.59 1.71 3 6 -9 17.22 1.93 -2 -6 9 44.22 3.27 2 -6 -9 44.22 3.50 -2 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7 -9 52.41 4.33 1 -7 -9 1.63 1.11 1 -7 -9 2.32 1.08 1 -7 -9 2.77 1.39 -1 -7 9 2.02 1.58 -1 -7 9 1.08 1.51 1 7 -9 3.78 2.03 1 7 -9 4.27 1.38 -1 7 9 3.11 1.31 0 -7 -9 8.99 1.14 0 -7 9 10.30 1.77 0 -7 -9 9.09 1.31 0 -7 9 7.04 1.82 0 -7 -9 8.48 1.87 0 7 9 10.21 1.46 0 7 -9 8.46 1.88 0 7 -9 12.33 1.55 1 -7 9 54.23 4.08 1 -7 9 53.82 3.85 -1 -7 -9 51.54 3.42 -1 -7 -9 49.26 3.41 -1 -7 -9 52.43 3.28 -1 7 -9 53.65 4.17 -1 7 -9 53.10 3.43 1 7 9 56.84 4.07 1 7 9 53.35 3.83 2 -7 9 0.14 1.41 2 -7 9 -1.97 1.72 -2 7 -9 -0.22 1.87 2 7 9 0.88 0.84 3 -7 9 25.79 2.74 3 -7 9 30.13 3.23 3 7 9 38.27 2.59 -3 7 -9 40.97 3.69 4 -7 9 24.37 2.82 4 -7 9 19.83 2.33 -4 7 -9 21.03 2.87 5 -7 9 1.67 1.76 5 -7 9 2.07 2.02 -5 7 -9 4.01 2.22 6 -7 9 1.35 1.90 -6 7 -9 4.02 1.99 7 -7 9 6.26 2.17 -7 7 -9 4.98 2.52 -8 7 -9 6.36 2.32 -9 -8 9 19.47 3.08 9 -8 -9 20.61 3.24 -9 8 9 21.77 3.01 9 8 -9 19.83 3.30 9 8 -9 20.82 2.98 -8 -8 9 7.15 2.39 8 -8 -9 6.78 2.51 -8 8 9 7.75 2.23 8 8 -9 6.89 2.37 8 8 -9 8.49 2.70 7 -8 -9 6.28 2.29 -7 -8 9 7.98 2.77 -7 -8 9 11.06 2.87 -7 8 9 9.55 2.26 7 8 -9 9.17 2.68 7 8 -9 7.62 2.27 6 -8 -9 19.74 2.68 -6 -8 9 17.35 3.21 -6 -8 9 18.49 3.19 6 -8 -9 21.70 2.57 6 8 -9 23.18 2.52 6 8 -9 24.54 2.88 -6 8 9 24.59 2.45 5 -8 -9 4.02 1.70 5 -8 -9 2.39 1.71 -5 -8 9 1.04 1.40 -5 -8 9 2.94 2.03 5 -8 -9 3.77 1.81 5 8 -9 3.94 1.96 -5 8 9 4.10 1.70 5 8 -9 2.43 2.28 4 -8 -9 -0.28 1.70 -4 -8 9 1.75 1.95 -4 -8 9 0.12 1.33 4 -8 -9 0.70 1.55 4 -8 -9 1.77 1.89 4 8 -9 1.91 1.76 -4 8 9 0.09 1.51 4 8 -9 0.62 1.74 3 -8 -9 8.64 1.59 -3 -8 9 8.12 1.70 3 -8 -9 8.08 1.80 3 -8 -9 8.42 1.55 -3 -8 9 8.25 2.09 3 8 -9 5.40 1.98 3 8 -9 4.47 1.82 -2 -8 9 11.66 1.68 2 -8 -9 8.46 1.42 -2 -8 9 9.96 2.07 2 -8 -9 10.75 1.64 2 -8 -9 8.93 1.77 2 8 -9 12.98 2.20 2 8 -9 11.57 1.90 -1 -8 9 13.28 2.19 1 -8 -9 10.70 1.85 -1 -8 9 10.50 1.75 1 -8 -9 12.02 1.58 1 -8 -9 11.23 1.38 1 8 -9 14.41 2.19 1 8 -9 13.30 1.87 0 -8 -9 10.20 1.22 0 -8 9 8.12 2.01 0 -8 9 11.13 1.75 0 -8 -9 10.42 1.77 0 -8 -9 8.45 1.28 0 8 -9 13.87 1.85 0 8 9 14.09 1.64 0 8 -9 12.38 2.13 1 -8 9 22.87 2.68 1 -8 9 24.10 2.48 -1 8 -9 24.75 2.45 -1 8 -9 25.33 2.81 1 8 9 27.27 2.29 2 -8 9 27.65 2.72 2 -8 9 25.40 3.00 2 8 9 26.53 2.23 -2 8 -9 27.81 3.10 3 -8 9 22.28 2.35 3 -8 9 25.11 2.69 -3 8 -9 18.66 2.59 4 -8 9 25.95 3.07 4 -8 9 24.95 2.52 -4 8 -9 22.57 2.84 5 -8 9 2.19 2.15 5 -8 9 -0.16 1.92 -5 8 -9 0.21 2.22 6 -8 9 3.81 1.97 -6 8 -9 3.11 2.54 7 -8 9 20.03 2.88 -7 8 -9 22.17 3.01 -9 -9 9 0.42 2.72 9 -9 -9 2.56 2.07 -8 -9 9 -1.58 2.62 8 -9 -9 -2.44 2.16 -8 -9 9 0.71 2.19 8 9 -9 4.20 2.60 -8 9 9 -1.12 2.25 8 9 -9 -0.61 1.95 7 -9 -9 3.65 2.14 -7 -9 9 0.80 2.16 -7 -9 9 0.73 2.58 7 9 -9 1.77 2.47 -7 9 9 0.15 2.12 7 9 -9 1.14 1.92 6 -9 -9 4.43 2.03 -6 -9 9 5.88 2.73 -6 9 9 6.63 2.04 6 9 -9 5.17 2.53 6 9 -9 2.71 2.09 -5 -9 9 36.85 3.67 5 -9 -9 35.32 3.55 5 -9 -9 27.79 3.05 5 -9 -9 33.85 3.15 -5 9 9 31.17 2.84 5 9 -9 32.87 3.24 5 9 -9 31.05 3.58 4 -9 -9 15.98 2.22 4 -9 -9 15.31 2.15 -4 -9 9 13.01 1.82 4 -9 -9 14.54 2.10 -4 -9 9 14.47 2.58 -4 9 9 13.61 1.84 4 9 -9 14.58 2.78 4 9 -9 14.52 2.21 -3 -9 9 19.17 2.09 3 -9 -9 19.90 2.30 -3 -9 9 20.45 2.78 3 -9 -9 20.75 2.32 3 -9 -9 21.38 2.39 3 9 -9 17.07 2.41 3 9 -9 20.39 2.66 -2 -9 9 4.92 2.00 2 -9 -9 5.80 1.59 2 -9 -9 5.73 1.99 -2 -9 9 6.49 1.69 2 -9 -9 6.22 1.34 2 9 -9 10.50 2.00 2 9 -9 8.33 2.42 -1 -9 9 13.50 2.34 1 -9 -9 13.96 1.64 1 -9 -9 14.75 2.06 -1 -9 9 13.85 1.96 1 -9 -9 13.07 1.46 1 9 -9 14.55 2.32 1 9 -9 13.38 2.06 0 -9 9 44.87 3.35 0 -9 9 50.28 4.21 0 -9 -9 39.17 3.74 0 -9 -9 40.73 2.90 0 -9 -9 44.10 2.98 0 9 -9 40.74 3.38 0 9 -9 42.36 4.15 1 -9 9 4.81 2.18 1 -9 9 6.85 1.81 -1 9 -9 3.93 2.23 -1 9 -9 3.25 1.62 2 -9 9 38.80 3.92 2 -9 9 42.73 3.40 -2 9 -9 27.44 3.29 -2 9 -9 38.15 3.07 3 -9 9 3.52 1.87 3 -9 9 1.64 2.20 -3 9 -9 4.60 1.98 4 -9 9 1.30 1.75 4 -9 9 0.24 2.23 -4 9 -9 1.88 1.94 5 -9 9 1.35 2.28 5 -9 9 2.85 1.90 -5 9 -9 1.43 2.48 6 -9 9 11.11 2.51 -6 9 -9 16.29 3.10 -7 9 -9 2.25 2.75 -8 -10 9 11.23 3.17 8 -10 -9 12.40 2.41 -8 -10 9 12.10 3.19 8 10 -9 8.04 2.66 -8 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22.50 2.91 -2 10 -9 24.18 2.42 3 -10 9 7.93 2.11 3 -10 9 11.39 2.66 -3 10 -9 8.88 2.34 4 -10 9 7.63 2.17 4 -10 9 6.32 2.21 -4 10 -9 5.79 2.22 5 -10 9 16.10 3.03 5 -10 9 19.54 2.65 -5 10 -9 19.14 3.25 6 -10 9 12.22 2.35 6 -10 9 12.65 2.94 -6 10 -9 9.42 3.06 7 -11 -9 6.58 2.36 -7 -11 9 4.51 2.56 -7 11 9 8.39 2.49 7 11 -9 6.49 2.34 6 -11 -9 40.59 4.15 -6 -11 9 48.03 4.51 6 11 -9 36.79 4.18 6 11 -9 33.93 3.55 -6 11 9 40.01 3.85 -5 -11 9 -0.59 2.19 5 -11 -9 -0.04 1.73 5 11 -9 1.22 2.09 5 11 -9 -0.70 2.18 -5 11 9 -0.31 1.82 -4 -11 9 67.86 5.35 4 -11 -9 63.97 4.79 4 11 -9 58.73 4.82 4 11 -9 61.59 5.10 -3 -11 9 -2.45 2.01 3 -11 -9 1.24 1.63 3 11 -9 4.51 2.50 3 11 -9 3.69 1.90 2 -11 -9 29.19 3.04 -2 -11 9 30.23 2.90 2 -11 -9 30.06 2.84 -2 -11 9 30.31 3.72 2 11 -9 37.73 3.55 2 11 -9 34.08 3.16 -1 -11 9 6.25 2.30 1 -11 -9 10.76 2.08 1 -11 -9 10.05 1.52 -1 -11 9 10.43 1.77 1 11 -9 13.52 2.29 1 11 -9 16.06 2.53 0 -11 9 0.31 1.67 0 -11 9 -0.14 2.33 0 11 -9 -0.22 1.91 0 11 -9 1.92 1.86 1 -11 9 41.35 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19.35 2.70 4 -4 -10 20.41 2.56 -4 -4 10 19.04 2.75 -4 4 10 21.72 2.06 4 4 -10 18.45 1.81 4 4 -10 20.71 2.48 -4 4 10 21.39 2.43 3 -4 -10 47.05 3.51 3 -4 -10 45.88 3.69 -3 -4 10 47.57 3.89 3 -4 -10 41.69 4.03 -3 -4 10 43.27 3.54 3 4 -10 51.98 3.96 -3 4 10 52.25 3.28 3 4 -10 43.91 3.01 -3 4 10 47.90 4.13 2 -4 -10 22.63 2.25 -2 -4 10 19.23 2.43 2 -4 -10 20.93 2.31 2 -4 -10 20.08 2.22 -2 -4 10 17.08 2.21 2 4 -10 26.32 1.90 -2 4 10 25.49 2.78 2 4 -10 26.29 2.59 -2 4 10 23.97 2.12 1 -4 -10 32.68 2.80 1 -4 -10 32.59 2.70 -1 -4 10 33.10 2.75 -1 -4 10 32.24 2.96 1 -4 -10 33.05 2.69 1 4 -10 33.34 3.38 -1 4 10 31.86 2.35 -1 4 10 28.63 3.14 0 -4 -10 2.79 1.43 0 -4 -10 3.21 1.34 0 -4 10 3.41 1.42 0 -4 -10 4.83 1.27 0 -4 10 5.76 1.88 0 -4 10 3.81 1.41 0 4 10 3.68 1.25 0 4 -10 3.28 1.79 1 -4 10 11.40 1.93 1 -4 10 10.18 1.67 1 -4 10 10.95 1.71 -1 -4 -10 11.76 1.42 -1 -4 -10 10.23 1.40 -1 -4 -10 11.30 2.00 1 4 10 13.37 1.70 -1 4 -10 16.53 2.01 2 -4 10 1.38 1.53 2 -4 10 2.40 1.54 -2 -4 -10 0.81 0.84 -2 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10 31.68 3.21 1 -5 10 31.25 2.99 1 5 10 40.01 2.93 -1 5 -10 33.70 3.42 -2 -5 -10 32.08 2.40 2 -5 10 31.47 2.83 -2 -5 -10 32.21 3.16 2 -5 10 27.66 2.93 -2 -5 -10 31.84 2.40 -2 5 -10 32.54 3.08 2 5 10 31.26 2.76 -3 -5 -10 47.24 3.30 -3 -5 -10 49.67 3.18 3 -5 10 52.98 4.06 3 -5 10 49.46 3.64 -3 5 -10 43.82 4.09 3 5 10 48.27 3.67 4 -5 10 11.16 2.09 -4 5 -10 13.00 2.10 5 -5 10 10.19 1.99 -5 5 -10 6.38 2.25 6 -5 10 12.62 2.19 -6 5 -10 10.59 2.53 7 -5 10 -0.17 2.17 -7 5 -10 0.91 2.28 -9 -6 10 26.65 3.41 9 -6 -10 24.43 3.43 9 6 -10 24.40 3.56 -9 6 10 27.56 2.98 -8 -6 10 4.44 2.25 8 -6 -10 1.42 1.88 8 6 -10 2.63 2.08 -8 6 10 2.48 1.97 8 6 -10 1.98 2.01 7 -6 -10 30.36 3.36 -7 -6 10 32.56 3.79 7 -6 -10 32.08 3.43 -7 -6 10 32.63 2.94 7 6 -10 30.70 3.61 7 6 -10 32.77 3.26 -7 6 10 30.01 3.07 6 -6 -10 8.53 2.28 -6 -6 10 6.62 2.59 -6 -6 10 6.07 1.74 6 -6 -10 7.71 2.15 -6 -6 10 7.53 2.59 6 6 -10 6.45 2.13 -6 6 10 7.16 1.81 6 6 -10 5.01 1.90 -5 -6 10 12.57 2.52 5 -6 -10 12.89 2.27 5 -6 -10 14.30 2.16 5 -6 -10 12.73 2.37 -5 -6 10 16.73 2.57 -5 -6 10 11.02 1.98 5 6 -10 19.57 2.13 -5 6 10 20.48 2.06 5 6 -10 15.54 2.83 4 -6 -10 65.40 4.79 -4 -6 10 63.79 4.46 4 -6 -10 60.49 4.64 4 -6 -10 60.71 5.08 -4 -6 10 60.47 5.24 4 6 -10 67.56 4.37 4 6 -10 62.52 4.90 -4 6 10 68.93 4.39 -3 -6 10 5.30 1.63 3 -6 -10 7.34 1.64 -3 -6 10 9.85 2.45 3 -6 -10 6.65 1.67 3 -6 -10 7.27 1.96 3 6 -10 10.81 2.08 3 6 -10 8.87 1.62 -3 6 10 8.59 1.48 -3 6 10 8.97 2.02 -2 -6 10 78.78 5.03 2 -6 -10 70.83 5.04 2 -6 -10 75.62 5.46 2 -6 -10 82.67 5.02 -2 -6 10 86.18 5.53 2 6 -10 74.79 5.61 -2 6 10 70.62 5.59 2 6 -10 69.52 4.66 1 -6 -10 1.88 1.38 -1 -6 10 1.82 1.46 -1 -6 10 4.45 1.71 1 -6 -10 4.71 1.31 1 -6 -10 2.61 1.06 1 6 -10 3.29 1.07 -1 6 10 2.90 1.54 1 6 -10 3.18 2.05 0 -6 -10 25.32 2.44 0 -6 10 28.85 2.95 0 -6 -10 24.71 2.21 0 -6 -10 28.65 2.34 0 -6 10 25.30 2.47 0 6 -10 24.97 2.70 0 6 10 22.88 2.57 1 -6 10 24.14 2.41 -1 -6 -10 22.71 2.03 -1 -6 -10 22.58 1.91 -1 -6 -10 24.65 1.92 1 -6 10 23.69 2.51 1 6 10 20.57 2.24 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13 6.47 2.19 5 4 -13 4.42 2.35 -4 -4 13 0.80 2.07 4 -4 -13 0.38 1.91 -4 -4 13 2.72 2.54 4 -4 -13 1.18 1.68 4 4 -13 2.33 2.55 -4 4 13 2.03 1.88 -3 -4 13 30.10 3.15 3 -4 -13 35.12 3.37 3 -4 -13 37.25 3.18 -3 4 13 34.32 3.22 3 4 -13 27.93 3.40 -2 -4 13 27.51 2.93 2 -4 -13 23.82 2.76 2 -4 -13 31.12 2.98 -2 4 13 31.72 3.57 2 4 -13 24.73 3.42 1 -4 -13 12.65 2.22 -1 -4 13 15.25 2.25 1 -4 -13 13.11 2.25 -1 4 13 16.88 2.44 1 4 -13 13.76 2.82 0 -4 13 52.27 3.95 0 -4 -13 49.19 3.86 0 4 -13 43.20 4.48 1 -4 13 8.15 1.99 -1 -4 -13 5.28 1.66 -1 4 -13 7.19 2.45 -2 -4 -13 25.48 2.63 2 -4 13 23.71 2.72 -2 4 -13 31.87 3.36 3 -4 13 6.67 2.04 -3 4 -13 7.42 2.40 4 -4 13 6.07 2.27 -4 4 -13 5.57 2.44 -7 -5 13 6.95 3.12 -7 -5 13 5.61 2.95 -7 -5 13 8.22 2.30 7 -5 -13 7.19 2.62 7 5 -13 11.91 2.75 -7 5 13 8.41 2.31 -6 -5 13 50.94 4.17 -6 -5 13 53.76 5.33 6 -5 -13 55.28 4.72 -6 5 13 51.49 4.44 5 -5 -13 4.51 2.11 -5 -5 13 2.72 2.78 -5 -5 13 3.68 2.19 -5 5 13 4.27 1.96 5 5 -13 3.95 2.30 -4 -5 13 31.74 3.91 4 -5 -13 34.00 3.36 -4 -5 13 32.73 3.34 4 5 -13 39.62 3.84 -4 5 13 36.43 3.44 -3 -5 13 7.95 2.24 3 -5 -13 3.92 2.11 3 -5 -13 9.07 2.25 -3 -5 13 4.66 2.14 3 5 -13 6.03 2.30 2 -5 -13 16.86 2.31 2 -5 -13 19.75 2.55 -2 -5 13 21.72 2.55 2 5 -13 18.75 2.89 1 -5 -13 17.48 2.49 1 -5 -13 18.69 2.33 -1 -5 13 15.91 2.58 1 5 -13 18.26 3.08 0 -5 13 0.35 1.84 0 -5 -13 0.02 1.65 0 5 -13 -1.95 2.27 -1 -5 -13 17.55 2.12 1 -5 13 19.95 2.69 -1 5 -13 20.42 2.77 2 -5 13 16.72 2.63 -2 5 -13 16.99 2.95 3 -5 13 27.56 3.05 -3 5 -13 24.05 3.30 4 -5 13 9.96 2.35 -4 5 -13 12.44 2.79 -6 -6 13 3.26 2.41 -6 -6 13 3.99 2.10 6 -6 -13 -1.42 2.50 -6 6 13 -0.33 2.13 6 6 -13 -2.20 2.22 -5 -6 13 3.70 1.99 5 -6 -13 6.31 2.17 -5 -6 13 1.62 2.84 5 6 -13 2.35 2.37 -5 6 13 8.85 2.05 -4 -6 13 13.22 3.22 -4 -6 13 22.42 2.59 4 -6 -13 15.30 2.47 4 6 -13 19.93 3.03 -4 6 13 19.38 2.47 -3 -6 13 9.21 2.12 3 -6 -13 5.05 2.09 -3 -6 13 4.28 2.64 3 6 -13 8.45 2.91 -2 -6 13 18.86 2.71 -2 -6 13 19.12 3.17 2 -6 -13 19.36 2.47 2 6 -13 20.44 3.33 1 -6 -13 21.69 2.38 -1 -6 13 18.51 2.73 1 6 -13 23.25 3.04 0 -6 13 23.98 2.72 0 -6 -13 24.51 2.38 0 6 -13 21.67 3.35 1 -6 13 3.26 2.24 -1 6 -13 8.56 2.73 2 -6 13 8.17 2.18 -2 6 -13 9.34 2.41 3 -6 13 3.71 2.13 -3 6 -13 6.15 2.68 -5 -7 13 7.09 3.09 -5 -7 13 6.87 2.27 5 -7 -13 8.39 2.57 -5 7 13 10.17 2.38 5 7 -13 13.62 2.83 4 -7 -13 5.03 1.95 -4 -7 13 3.24 2.38 -4 -7 13 3.42 2.18 4 7 -13 3.69 2.44 -3 -7 13 17.05 3.37 3 -7 -13 19.94 2.46 -3 -7 13 22.28 2.65 3 7 -13 23.15 3.25 -2 -7 13 4.85 2.20 2 -7 -13 3.13 1.79 -2 -7 13 9.27 2.44 2 7 -13 6.48 2.44 1 -7 -13 7.30 1.82 -1 -7 13 7.54 2.30 -1 -7 13 5.54 2.32 1 7 -13 4.50 2.36 0 -7 13 14.74 2.43 0 7 -13 17.47 3.20 1 -7 13 2.22 1.97 -1 7 -13 2.05 2.66 2 -7 13 14.86 2.71 -2 7 -13 16.90 3.14 4 -8 -13 6.14 2.24 -4 -8 13 9.23 2.36 -4 -8 13 5.13 2.58 4 8 -13 7.72 3.19 3 -8 -13 6.49 1.98 -3 -8 13 4.13 2.04 -3 -8 13 4.43 2.47 3 8 -13 4.19 2.49 -2 -8 13 1.35 2.15 -2 -8 13 4.21 2.80 2 -8 -13 1.15 1.61 2 8 -13 2.34 2.86 -1 -8 13 1.73 1.98 -1 -8 13 4.43 2.75 1 8 -13 3.28 2.89 0 -8 13 -1.19 2.19 0 8 -13 1.40 2.33 1 -8 13 5.14 2.37 -1 8 -13 6.49 2.88 -2 -9 13 11.33 3.26 -2 -9 13 11.80 2.50 2 9 -13 11.00 2.85 -1 -9 13 15.16 2.65 -1 -9 13 13.97 2.88 1 9 -13 21.02 3.23 -6 0 14 7.68 2.33 6 0 -14 8.39 2.42 -5 0 14 1.03 2.05 5 0 -14 3.43 2.49 -4 0 14 29.19 3.02 4 0 -14 31.30 3.51 -3 0 14 1.77 2.11 3 0 -14 3.58 2.30 2 0 -14 60.59 4.90 -2 0 14 58.32 4.56 1 0 -14 0.85 2.35 -1 0 14 1.81 1.90 0 0 14 70.96 5.01 0 0 -14 74.59 5.47 -1 0 -14 18.37 2.74 1 0 14 15.50 2.31 -2 0 -14 1.91 1.89 -3 0 -14 -1.47 2.04 6 -1 -14 26.07 3.38 -6 -1 14 22.03 3.06 -6 1 14 21.96 2.90 6 1 -14 21.54 3.42 -5 -1 14 21.81 2.95 5 -1 -14 20.74 3.12 -5 1 14 20.27 2.70 5 1 -14 20.77 3.24 4 -1 -14 2.09 2.28 -4 -1 14 4.30 2.27 -4 1 14 7.43 2.28 4 1 -14 7.79 2.61 -3 -1 14 13.10 2.47 3 -1 -14 11.57 2.55 -3 1 14 11.05 2.32 3 1 -14 7.40 2.60 2 -1 -14 2.13 2.07 -2 -1 14 -1.51 2.01 -2 1 14 -0.45 1.89 2 1 -14 0.06 2.18 1 -1 -14 -1.28 1.85 -1 -1 14 0.16 1.92 1 1 -14 0.35 2.15 -1 1 14 2.36 1.87 0 -1 14 33.43 3.16 0 -1 -14 32.47 3.37 0 1 -14 26.99 3.27 0 1 14 30.95 2.85 1 -1 14 18.68 2.33 -1 -1 -14 19.92 2.68 -1 1 -14 22.13 3.02 -2 -1 -14 20.30 2.69 2 -1 14 19.23 2.57 -2 1 -14 23.00 3.04 3 -1 14 39.25 3.76 -3 -1 -14 35.85 3.76 -3 1 -14 46.74 4.19 6 -2 -14 9.27 2.71 -6 -2 14 11.33 2.62 6 2 -14 15.71 2.76 -6 2 14 11.13 2.69 -5 -2 14 14.75 2.66 5 -2 -14 11.63 2.66 5 2 -14 8.00 2.83 -5 2 14 8.22 2.49 4 -2 -14 7.70 2.71 -4 -2 14 6.80 2.41 -4 2 14 4.07 1.99 4 2 -14 8.81 2.37 -3 -2 14 27.87 3.11 3 -2 -14 25.71 3.12 3 2 -14 32.51 3.33 -3 2 14 26.53 2.91 2 -2 -14 14.83 2.56 -2 -2 14 18.02 2.46 -2 2 14 20.11 2.43 2 2 -14 15.20 2.88 1 -2 -14 17.66 2.73 -1 -2 14 20.03 2.63 -1 2 14 18.06 2.35 1 2 -14 21.28 3.03 0 -2 14 3.35 1.89 0 -2 -14 6.31 2.21 0 2 -14 6.48 2.36 1 -2 14 0.43 1.98 -1 -2 -14 3.38 1.95 -1 2 -14 5.62 2.25 -2 -2 -14 2.32 1.88 2 -2 14 1.93 1.84 -2 2 -14 1.40 2.10 3 -2 14 3.23 2.15 -3 -2 -14 6.56 1.95 -3 2 -14 4.95 2.23 6 -3 -14 5.33 2.55 -6 3 14 6.89 2.32 6 3 -14 8.50 2.99 -5 -3 14 0.02 2.27 5 -3 -14 1.38 2.19 5 3 -14 2.90 2.73 -5 3 14 7.61 2.13 4 -3 -14 9.34 2.74 -4 -3 14 10.86 2.36 -4 3 14 11.24 2.38 4 3 -14 12.45 2.93 -3 -3 14 1.30 1.95 3 -3 -14 0.68 1.92 3 -3 -14 -0.98 1.91 -3 3 14 3.37 1.99 3 3 -14 1.91 2.51 2 -3 -14 5.92 2.35 -2 -3 14 7.12 2.33 -2 3 14 7.78 2.01 2 3 -14 10.52 2.74 -1 -3 14 8.45 2.09 1 -3 -14 5.93 1.93 1 3 -14 9.37 2.62 0 -3 14 4.49 2.19 0 -3 -14 5.97 2.05 0 3 -14 6.06 2.50 1 -3 14 27.97 2.97 -1 -3 -14 32.76 3.13 -1 3 -14 35.87 3.62 2 -3 14 4.59 2.00 -2 -3 -14 1.52 1.66 -2 3 -14 1.35 2.22 3 -3 14 10.52 2.43 -3 3 -14 9.11 2.52 5 -4 -14 0.44 2.15 -5 -4 14 2.69 2.10 -5 4 14 0.49 1.96 5 4 -14 0.61 2.26 -4 -4 14 7.27 2.29 4 -4 -14 11.36 2.65 4 4 -14 9.10 2.50 -4 4 14 14.12 2.40 -3 -4 14 4.34 2.07 3 -4 -14 4.52 2.07 -3 4 14 5.37 2.04 3 4 -14 3.07 2.71 -2 -4 14 3.13 2.23 2 -4 -14 2.12 1.71 2 -4 -14 3.85 1.87 2 4 -14 2.83 2.24 -1 -4 14 1.25 2.20 1 -4 -14 3.44 1.95 1 4 -14 6.37 2.68 0 -4 14 10.85 2.43 0 -4 -14 6.40 2.16 0 4 -14 5.21 2.58 1 -4 14 -0.72 2.15 -1 -4 -14 1.75 1.61 -1 4 -14 2.05 2.47 2 -4 14 -1.45 1.93 -2 4 -14 -3.29 2.21 5 -5 -14 3.06 2.15 -5 5 14 2.21 2.23 5 5 -14 -0.58 2.86 -4 -5 14 7.00 2.28 4 -5 -14 6.87 2.20 -4 5 14 7.06 2.26 4 5 -14 9.57 3.06 -3 -5 14 4.72 2.08 3 -5 -14 3.24 2.25 3 5 -14 1.65 2.32 2 -5 -14 1.99 1.96 -2 -5 14 2.92 2.27 2 5 -14 -0.04 2.12 1 -5 -14 1.70 2.00 -1 -5 14 0.15 1.98 1 5 -14 0.13 2.60 0 -5 14 6.01 2.15 0 -5 -14 4.63 1.77 0 5 -14 2.31 2.60 1 -5 14 0.59 2.27 -1 5 -14 8.47 2.77 4 -6 -14 2.76 2.28 4 6 -14 -2.36 2.28 -3 -6 14 30.47 3.05 3 -6 -14 28.32 3.12 3 6 -14 19.30 3.74 2 -6 -14 11.76 2.27 -2 -6 14 13.36 2.46 2 6 -14 14.13 3.23 -1 -6 14 11.00 2.54 1 -6 -14 10.85 2.04 1 6 -14 14.58 3.12 0 6 -14 4.03 2.83 3 0 -15 9.94 2.65 -3 0 15 8.93 2.49 -2 0 15 7.30 2.11 2 0 -15 3.40 2.35 -1 0 15 14.83 2.49 1 0 -15 15.99 2.79 0 0 -15 2.26 2.18 0 0 15 0.10 2.04 3 -1 -15 0.19 2.25 -3 -1 15 4.35 2.34 3 1 -15 1.41 2.49 -3 1 15 1.07 2.19 -2 -1 15 1.99 2.00 2 -1 -15 0.34 2.13 2 1 -15 1.41 2.37 -2 1 15 2.72 2.14 1 -1 -15 9.54 2.75 -1 -1 15 8.52 2.37 1 1 -15 8.19 2.61 -1 1 15 10.83 2.26 0 -1 -15 11.34 2.69 0 -1 15 13.37 2.47 0 1 -15 6.40 2.48 3 -2 -15 1.33 2.17 -3 -2 15 0.19 2.28 3 2 -15 -0.61 2.01 -3 2 15 1.77 2.17 2 -2 -15 31.51 3.40 -2 -2 15 35.13 3.24 -2 2 15 31.55 3.17 2 2 -15 29.78 3.75 -1 -2 15 2.61 2.02 1 -2 -15 1.58 2.05 1 2 -15 2.34 2.48 0 -2 15 7.02 2.37 0 -2 -15 6.25 2.11 0 2 -15 5.66 2.48 2 -3 -15 1.63 2.04 2 3 -15 5.32 2.74 0 0 0 0.00 0.00 ; _shelx_hkl_checksum 32573 _shelx_res_file ; C:\Crystal\x-step32\itsep10a.res created by SHELXL-2014/7 TITL TIR37, MONOCLINIC P2(1) CELL 0.71073 9.15840 12.29320 10.66330 90.00000 97.45400 90.00000 ZERR 2 0.00060 0.00070 0.00060 0.00000 0.00300 0.00000 LATT -1 SYMM -X, Y+ 0.50000, -Z SFAC C H N BR O UNIT 30 80 12 4 4 TEMP -173 L.S. 5 ACTA CONF SIZE 0.41 0.29 0.25 L.S. 5 BOND $H CONF ACTA FMAP 2 PLAN 20 TWIN -1 0 0 0 -1 0 0 0 -1 REM PRISM, COLORLESS WGHT 0.034400 BASF 0.10901 FVAR 0.25102 BR1 4 0.937618 0.228067 0.492504 0.70128 0.01575 0.01908 = 0.01268 0.00164 -0.00014 -0.00070 BR2 4 0.537053 0.949725 0.871155 0.83050 0.01885 0.01493 = 0.02373 0.00258 0.00287 0.00227 BR3 4 0.056374 0.847493 0.004321 0.45593 0.01718 0.01562 = 0.01910 0.00410 0.00496 0.00253 O1 5 0.775013 0.766223 0.822395 11.00000 0.02581 0.02792 = 0.03684 -0.01018 0.00586 -0.00107 H16 2 0.719891 0.809331 0.831128 11.00000 0.03277 C1 1 0.309952 0.493861 0.772624 11.00000 0.01762 0.01194 = 0.00896 -0.00116 0.00160 0.00030 N1 3 0.420479 0.564524 0.778376 11.00000 0.01734 0.01237 = 0.01489 0.00017 0.00053 -0.00278 N2 3 0.171465 0.524611 0.774329 11.00000 0.01840 0.01237 = 0.01726 0.00000 0.00427 0.00149 C2 1 0.573874 0.537489 0.828131 11.00000 0.01970 0.01694 = 0.02033 0.00082 -0.00481 -0.00470 AFIX 137 H2A 2 0.574673 0.479992 0.891877 11.00000 -1.50000 H2B 2 0.623140 0.602324 0.866774 11.00000 -1.50000 H2C 2 0.625805 0.512174 0.758826 11.00000 -1.50000 AFIX 0 C3 1 0.400736 0.675143 0.726454 11.00000 0.02675 0.01215 = 0.02204 0.00222 0.00048 -0.00281 AFIX 137 H3A 2 0.306701 0.679567 0.671174 11.00000 -1.50000 H3B 2 0.481436 0.692204 0.677686 11.00000 -1.50000 H3C 2 0.400912 0.727376 0.795902 11.00000 -1.50000 AFIX 0 C4 1 0.134480 0.623680 0.841414 11.00000 0.03110 0.01627 = 0.02454 -0.00196 0.01052 0.00714 AFIX 137 H4A 2 0.221807 0.649108 0.896490 11.00000 -1.50000 H4B 2 0.055776 0.607359 0.892644 11.00000 -1.50000 H4C 2 0.101266 0.680441 0.779712 11.00000 -1.50000 AFIX 0 C5 1 0.043337 0.465605 0.710372 11.00000 0.01307 0.01794 = 0.02336 0.00314 0.00165 0.00156 AFIX 137 H5A 2 0.077020 0.403419 0.664287 11.00000 -1.50000 H5B 2 -0.014952 0.514429 0.650830 11.00000 -1.50000 H5C 2 -0.017481 0.439627 0.773358 11.00000 -1.50000 AFIX 0 C6 1 0.444488 0.347610 0.689872 11.00000 0.01124 0.01087 = 0.01316 -0.00365 0.00127 -0.00170 N3 3 0.537454 0.268131 0.729200 11.00000 0.01349 0.01253 = 0.01614 -0.00144 0.00145 0.00050 N4 3 0.444043 0.392229 0.575708 11.00000 0.01590 0.01474 = 0.01334 0.00104 0.00287 0.00101 C7 1 0.599063 0.250297 0.862666 11.00000 0.01494 0.01895 = 0.01885 0.00176 -0.00444 0.00171 AFIX 137 H7A 2 0.565121 0.308081 0.915215 11.00000 -1.50000 H7B 2 0.706852 0.251350 0.870364 11.00000 -1.50000 H7C 2 0.566075 0.179632 0.890935 11.00000 -1.50000 AFIX 0 C8 1 0.584647 0.188900 0.640007 11.00000 0.02160 0.01513 = 0.02221 -0.00002 0.00569 0.00664 AFIX 137 H8A 2 0.517540 0.191612 0.560623 11.00000 -1.50000 H8B 2 0.583186 0.115736 0.676319 11.00000 -1.50000 H8C 2 0.684779 0.206356 0.623421 11.00000 -1.50000 AFIX 0 C9 1 0.310334 0.436106 0.501361 11.00000 0.02308 0.01879 = 0.01365 0.00264 0.00004 0.00351 AFIX 137 H9A 2 0.224432 0.394492 0.519950 11.00000 -1.50000 H9B 2 0.319296 0.430405 0.411009 11.00000 -1.50000 H9C 2 0.298264 0.512631 0.523630 11.00000 -1.50000 AFIX 0 C10 1 0.580419 0.406258 0.517092 11.00000 0.02237 0.01987 = 0.02102 -0.00027 0.01119 -0.00147 AFIX 137 H10A 2 0.664684 0.379968 0.575247 11.00000 -1.50000 H10B 2 0.594145 0.483479 0.499015 11.00000 -1.50000 H10C 2 0.572884 0.364633 0.438135 11.00000 -1.50000 AFIX 0 N5 3 0.341322 0.382811 0.765747 11.00000 0.01232 0.00990 = 0.01183 -0.00157 0.00176 -0.00252 C11 1 0.272093 0.303916 0.846882 11.00000 0.01493 0.01086 = 0.01236 0.00156 0.00320 -0.00097 AFIX 23 H11A 2 0.192382 0.341142 0.884581 11.00000 -1.20000 H11B 2 0.346851 0.279973 0.916891 11.00000 -1.20000 AFIX 0 C12 1 0.208467 0.204008 0.773927 11.00000 0.01693 0.01390 = 0.01368 0.00065 0.00163 -0.00548 AFIX 23 H12A 2 0.115185 0.223296 0.720937 11.00000 -1.20000 H12B 2 0.278635 0.177066 0.717839 11.00000 -1.20000 AFIX 0 C13 1 0.180548 0.116174 0.868761 11.00000 0.01629 0.01161 = 0.01379 0.00103 -0.00067 -0.00185 AFIX 23 H13A 2 0.276110 0.084632 0.905376 11.00000 -1.20000 H13B 2 0.135171 0.150072 0.938532 11.00000 -1.20000 AFIX 0 N6 3 0.082735 0.026724 0.812462 11.00000 0.01670 0.01208 = 0.01818 0.00323 -0.00100 -0.00187 H6 2 0.083646 -0.021908 0.870452 11.00000 0.03168 C14 1 -0.074759 0.060125 0.783773 11.00000 0.01355 0.02853 = 0.03284 0.01037 -0.00232 -0.00448 AFIX 137 H14A 2 -0.106055 0.095727 0.858077 11.00000 -1.50000 H14B 2 -0.135892 -0.004295 0.762117 11.00000 -1.50000 H14C 2 -0.085729 0.110871 0.712291 11.00000 -1.50000 AFIX 0 C15 1 0.137185 -0.025935 0.701274 11.00000 0.03509 0.01785 = 0.02011 -0.00466 0.00076 -0.00140 AFIX 137 H15A 2 0.126406 0.024681 0.629667 11.00000 -1.50000 H15B 2 0.079675 -0.091837 0.678271 11.00000 -1.50000 H15C 2 0.241233 -0.045232 0.722864 11.00000 -1.50000 AFIX 0 O2 5 0.265175 0.169724 0.420031 11.00000 0.02500 0.03234 = 0.03151 0.00455 -0.00013 0.00517 H17 2 0.185477 0.177144 0.442459 11.00000 0.04525 H18 2 0.251714 0.199588 0.346447 11.00000 0.04936 HKLF 4 REM TIR37, MONOCLINIC P2(1) REM R1 = 0.0306 for 6391 Fo > 4sig(Fo) and 0.0389 for all 7244 data REM 265 parameters refined using 1 restraints END WGHT 0.0344 0.0000 REM Highest difference peak 0.374, deepest hole -0.231, 1-sigma level 0.063 Q1 1 0.0921 0.8198 -0.0555 11.00000 0.05 0.37 Q2 1 0.0083 0.8565 -0.0770 11.00000 0.05 0.36 Q3 1 0.1120 0.9025 -0.0080 11.00000 0.05 0.36 Q4 1 0.0295 0.9139 0.0109 11.00000 0.05 0.36 Q5 1 0.0368 0.8123 0.0775 11.00000 0.05 0.36 Q6 1 0.0662 0.8009 0.0586 11.00000 0.05 0.36 Q7 1 -0.0356 0.8570 -0.0317 11.00000 0.05 0.34 Q8 1 0.9839 0.2586 0.4303 11.00000 0.05 0.34 Q9 1 0.5453 0.8794 0.8675 11.00000 0.05 0.34 Q10 1 0.8467 0.7946 0.8566 11.00000 0.05 0.33 Q11 1 0.0081 0.8417 0.0604 11.00000 0.05 0.33 Q12 1 0.1014 0.8613 0.0818 11.00000 0.05 0.31 Q13 1 0.9444 0.2012 0.5641 11.00000 0.05 0.31 Q14 1 -0.0210 0.8004 -0.0252 11.00000 0.05 0.31 Q15 1 0.9211 0.2974 0.4915 11.00000 0.05 0.30 Q16 1 0.9176 0.1607 0.5011 11.00000 0.05 0.30 Q17 1 0.5784 0.9949 0.9250 11.00000 0.05 0.29 Q18 1 0.0065 0.0405 0.8077 11.00000 0.05 0.29 Q19 1 0.5295 0.9769 0.7988 11.00000 0.05 0.29 Q20 1 0.4819 0.9056 0.8843 11.00000 0.05 0.29 ; _shelx_res_checksum 3664 loop_ _symmetry_equiv_pos_as_xyz x,y,z -x,1/2+y,-z loop_ _atom_site_type_symbol _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_calc_flag _atom_site_occupancy Br Br1 0.93762(4) 0.22807(3) 0.49250(4) 0.01601(14) Uani d 0.701(2) Br Br2 0.53705(4) 0.94972(3) 0.87115(3) 0.01916(12) Uani d 0.831(2) Br Br3 0.05637(7) 0.84749(5) 0.00432(6) 0.0171(2) Uani d 0.456(2) O O1 0.7750(3) 0.7662(2) 0.8224(3) 0.0300(6) Uani d 1 H H16 0.720(5) 0.809(4) 0.831(4) 0.033(13) Uiso d 1 C C1 0.3100(3) 0.4939(2) 0.7726(2) 0.0129(6) Uani d 1 N N1 0.4205(3) 0.5645(2) 0.7784(2) 0.0150(5) Uani d 1 N N2 0.1715(3) 0.5246(2) 0.7743(2) 0.0158(5) Uani d 1 C C2 0.5739(3) 0.5375(3) 0.8281(3) 0.0196(6) Uani d 1 H H2A 0.5747 0.4800 0.8919 0.029 Uiso calc 1 H H2B 0.6231 0.6023 0.8668 0.029 Uiso calc 1 H H2C 0.6258 0.5122 0.7588 0.029 Uiso calc 1 C C3 0.4007(4) 0.6751(2) 0.7265(3) 0.0205(6) Uani d 1 H H3A 0.3067 0.6796 0.6712 0.031 Uiso calc 1 H H3B 0.4814 0.6922 0.6777 0.031 Uiso calc 1 H H3C 0.4009 0.7274 0.7959 0.031 Uiso calc 1 C C4 0.1345(4) 0.6237(3) 0.8414(3) 0.0234(7) Uani d 1 H H4A 0.2218 0.6491 0.8965 0.035 Uiso calc 1 H H4B 0.0558 0.6074 0.8926 0.035 Uiso calc 1 H H4C 0.1013 0.6804 0.7797 0.035 Uiso calc 1 C C5 0.0433(3) 0.4656(3) 0.7104(3) 0.0182(6) Uani d 1 H H5A 0.0770 0.4034 0.6643 0.027 Uiso calc 1 H H5B -0.0150 0.5144 0.6508 0.027 Uiso calc 1 H H5C -0.0175 0.4396 0.7734 0.027 Uiso calc 1 C C6 0.4445(3) 0.3476(2) 0.6899(3) 0.0118(5) Uani d 1 N N3 0.5375(3) 0.26813(19) 0.7292(2) 0.0141(5) Uani d 1 N N4 0.4440(3) 0.3922(2) 0.5757(2) 0.0146(5) Uani d 1 C C7 0.5991(3) 0.2503(3) 0.8627(3) 0.0182(6) Uani d 1 H H7A 0.5651 0.3081 0.9152 0.027 Uiso calc 1 H H7B 0.7069 0.2514 0.8704 0.027 Uiso calc 1 H H7C 0.5661 0.1796 0.8909 0.027 Uiso calc 1 C C8 0.5846(4) 0.1889(2) 0.6400(3) 0.0194(6) Uani d 1 H H8A 0.5175 0.1916 0.5606 0.029 Uiso calc 1 H H8B 0.5832 0.1157 0.6763 0.029 Uiso calc 1 H H8C 0.6848 0.2064 0.6234 0.029 Uiso calc 1 C C9 0.3103(3) 0.4361(3) 0.5014(3) 0.0187(6) Uani d 1 H H9A 0.2244 0.3945 0.5200 0.028 Uiso calc 1 H H9B 0.3193 0.4304 0.4110 0.028 Uiso calc 1 H H9C 0.2983 0.5126 0.5236 0.028 Uiso calc 1 C C10 0.5804(3) 0.4063(3) 0.5171(3) 0.0203(6) Uani d 1 H H10A 0.6647 0.3800 0.5752 0.031 Uiso calc 1 H H10B 0.5941 0.4835 0.4990 0.031 Uiso calc 1 H H10C 0.5729 0.3646 0.4381 0.031 Uiso calc 1 N N5 0.3413(3) 0.38281(19) 0.7657(2) 0.0113(5) Uani d 1 C C11 0.2721(3) 0.3039(2) 0.8469(3) 0.0126(5) Uani d 1 H H11A 0.1924 0.3411 0.8846 0.015 Uiso calc 1 H H11B 0.3469 0.2800 0.9169 0.015 Uiso calc 1 C C12 0.2085(3) 0.2040(2) 0.7739(3) 0.0149(6) Uani d 1 H H12A 0.1152 0.2233 0.7209 0.018 Uiso calc 1 H H12B 0.2786 0.1771 0.7178 0.018 Uiso calc 1 C C13 0.1805(3) 0.1162(2) 0.8688(3) 0.0141(6) Uani d 1 H H13A 0.2761 0.0846 0.9054 0.017 Uiso calc 1 H H13B 0.1352 0.1501 0.9385 0.017 Uiso calc 1 N N6 0.0827(3) 0.0267(2) 0.8125(2) 0.0159(5) Uani d 1 H H6 0.084(4) -0.022(3) 0.870(4) 0.032(11) Uiso d 1 C C14 -0.0748(3) 0.0601(3) 0.7838(3) 0.0254(7) Uani d 1 H H14A -0.1061 0.0957 0.8581 0.038 Uiso calc 1 H H14B -0.1359 -0.0043 0.7621 0.038 Uiso calc 1 H H14C -0.0857 0.1109 0.7123 0.038 Uiso calc 1 C C15 0.1372(4) -0.0259(3) 0.7013(3) 0.0246(7) Uani d 1 H H15A 0.1264 0.0247 0.6297 0.037 Uiso calc 1 H H15B 0.0797 -0.0918 0.6783 0.037 Uiso calc 1 H H15C 0.2412 -0.0452 0.7229 0.037 Uiso calc 1 O O2 0.2652(3) 0.1697(2) 0.4200(3) 0.0299(6) Uani d 1 H H17 0.185(6) 0.177(4) 0.442(4) 0.045(14) Uiso d 1 H H18 0.252(5) 0.200(4) 0.346(5) 0.049(14) Uiso d 1 loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_12 _atom_site_aniso_U_13 _atom_site_aniso_U_23 Br1 0.0157(2) 0.0191(2) 0.0127(2) -0.00070(16) -0.00014(14) 0.00164(16) Br2 0.01885(18) 0.01493(17) 0.02373(19) 0.00227(15) 0.00287(13) 0.00258(15) Br3 0.0172(4) 0.0156(4) 0.0191(4) 0.0025(2) 0.0050(3) 0.0041(2) O1 0.0258(13) 0.0279(14) 0.0368(15) -0.0011(11) 0.0059(11) -0.0102(11) C1 0.0176(14) 0.0119(13) 0.0090(12) 0.0003(11) 0.0016(10) -0.0012(10) N1 0.0173(12) 0.0124(12) 0.0149(12) -0.0028(10) 0.0005(9) 0.0002(10) N2 0.0184(13) 0.0124(12) 0.0173(12) 0.0015(10) 0.0043(10) 0.0000(10) C2 0.0197(15) 0.0169(15) 0.0203(15) -0.0047(12) -0.0048(12) 0.0008(12) C3 0.0268(17) 0.0121(14) 0.0220(15) -0.0028(12) 0.0005(13) 0.0022(12) C4 0.0311(18) 0.0163(15) 0.0245(16) 0.0071(14) 0.0105(14) -0.0020(13) C5 0.0131(13) 0.0179(17) 0.0234(15) 0.0016(11) 0.0017(11) 0.0031(12) C6 0.0112(12) 0.0109(13) 0.0132(13) -0.0017(10) 0.0013(10) -0.0036(10) N3 0.0135(12) 0.0125(12) 0.0161(12) 0.0005(9) 0.0015(9) -0.0014(9) N4 0.0159(12) 0.0147(12) 0.0133(11) 0.0010(10) 0.0029(9) 0.0010(10) C7 0.0149(14) 0.0190(16) 0.0188(14) 0.0017(11) -0.0044(11) 0.0018(12) C8 0.0216(16) 0.0151(14) 0.0222(15) 0.0066(12) 0.0057(12) 0.0000(12) C9 0.0231(15) 0.0188(16) 0.0137(13) 0.0035(13) 0.0000(11) 0.0026(12) C10 0.0224(16) 0.0199(15) 0.0210(15) -0.0015(12) 0.0112(13) -0.0003(12) N5 0.0123(11) 0.0099(11) 0.0118(11) -0.0025(9) 0.0018(9) -0.0016(9) C11 0.0149(13) 0.0109(13) 0.0124(12) -0.0010(10) 0.0032(10) 0.0016(10) C12 0.0169(14) 0.0139(14) 0.0137(13) -0.0055(11) 0.0016(11) 0.0007(10) C13 0.0163(14) 0.0116(13) 0.0138(13) -0.0018(11) -0.0007(11) 0.0010(11) N6 0.0167(12) 0.0121(12) 0.0182(12) -0.0019(10) -0.0010(10) 0.0032(10) C14 0.0135(14) 0.0285(18) 0.0328(19) -0.0045(13) -0.0023(13) 0.0104(15) C15 0.0351(19) 0.0179(18) 0.0201(15) -0.0014(13) 0.0008(14) -0.0047(12) O2 0.0250(14) 0.0323(14) 0.0315(14) 0.0052(11) -0.0001(11) 0.0046(12) loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Br Br -0.2901 2.4595 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle N2 C1 N1 122.5(3) N2 C1 N5 118.8(3) N1 C1 N5 118.7(3) C1 N1 C3 122.1(3) C1 N1 C2 123.6(2) C3 N1 C2 114.1(2) C1 N2 C5 124.1(2) C1 N2 C4 121.5(3) C5 N2 C4 114.4(2) N1 C2 H2A 109.5 N1 C2 H2B 109.5 H2A C2 H2B 109.5 N1 C2 H2C 109.5 H2A C2 H2C 109.5 H2B C2 H2C 109.5 N1 C3 H3A 109.5 N1 C3 H3B 109.5 H3A C3 H3B 109.5 N1 C3 H3C 109.5 H3A C3 H3C 109.5 H3B C3 H3C 109.5 N2 C4 H4A 109.5 N2 C4 H4B 109.5 H4A C4 H4B 109.5 N2 C4 H4C 109.5 H4A C4 H4C 109.5 H4B C4 H4C 109.5 N2 C5 H5A 109.5 N2 C5 H5B 109.5 H5A C5 H5B 109.5 N2 C5 H5C 109.5 H5A C5 H5C 109.5 H5B C5 H5C 109.5 N3 C6 N4 121.1(3) N3 C6 N5 120.1(3) N4 C6 N5 118.7(3) C6 N3 C8 121.0(2) C6 N3 C7 124.2(2) C8 N3 C7 114.7(2) C6 N4 C9 123.1(2) C6 N4 C10 122.1(2) C9 N4 C10 114.8(2) N3 C7 H7A 109.5 N3 C7 H7B 109.5 H7A C7 H7B 109.5 N3 C7 H7C 109.5 H7A C7 H7C 109.5 H7B C7 H7C 109.5 N3 C8 H8A 109.5 N3 C8 H8B 109.5 H8A C8 H8B 109.5 N3 C8 H8C 109.5 H8A C8 H8C 109.5 H8B C8 H8C 109.5 N4 C9 H9A 109.5 N4 C9 H9B 109.5 H9A C9 H9B 109.5 N4 C9 H9C 109.5 H9A C9 H9C 109.5 H9B C9 H9C 109.5 N4 C10 H10A 109.5 N4 C10 H10B 109.5 H10A C10 H10B 109.5 N4 C10 H10C 109.5 H10A C10 H10C 109.5 H10B C10 H10C 109.5 C6 N5 C1 119.6(2) C6 N5 C11 120.4(2) C1 N5 C11 119.8(2) N5 C11 C12 112.9(2) N5 C11 H11A 109.0 C12 C11 H11A 109.0 N5 C11 H11B 109.0 C12 C11 H11B 109.0 H11A C11 H11B 107.8 C13 C12 C11 108.5(2) C13 C12 H12A 110.0 C11 C12 H12A 110.0 C13 C12 H12B 110.0 C11 C12 H12B 110.0 H12A C12 H12B 108.4 N6 C13 C12 113.5(2) N6 C13 H13A 108.9 C12 C13 H13A 108.9 N6 C13 H13B 108.9 C12 C13 H13B 108.9 H13A C13 H13B 107.7 C15 N6 C14 111.7(3) C15 N6 C13 113.2(2) C14 N6 C13 113.1(2) C15 N6 H6 107(3) C14 N6 H6 105(3) C13 N6 H6 106(3) N6 C14 H14A 109.5 N6 C14 H14B 109.5 H14A C14 H14B 109.5 N6 C14 H14C 109.5 H14A C14 H14C 109.5 H14B C14 H14C 109.5 N6 C15 H15A 109.5 N6 C15 H15B 109.5 H15A C15 H15B 109.5 N6 C15 H15C 109.5 H15A C15 H15C 109.5 H15B C15 H15C 109.5 H17 O2 H18 101(4) loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance O1 H16 0.75(5) C1 N2 1.326(4) C1 N1 1.329(4) C1 N5 1.399(4) N1 C3 1.471(4) N1 C2 1.474(4) N2 C5 1.470(4) N2 C4 1.474(4) C2 H2A 0.9800 C2 H2B 0.9800 C2 H2C 0.9800 C3 H3A 0.9800 C3 H3B 0.9800 C3 H3C 0.9800 C4 H4A 0.9800 C4 H4B 0.9800 C4 H4C 0.9800 C5 H5A 0.9800 C5 H5B 0.9800 C5 H5C 0.9800 C6 N3 1.328(4) C6 N4 1.335(4) C6 N5 1.390(3) N3 C8 1.465(4) N3 C7 1.478(4) N4 C9 1.472(4) N4 C10 1.477(4) C7 H7A 0.9800 C7 H7B 0.9800 C7 H7C 0.9800 C8 H8A 0.9800 C8 H8B 0.9800 C8 H8C 0.9800 C9 H9A 0.9800 C9 H9B 0.9800 C9 H9C 0.9800 C10 H10A 0.9800 C10 H10B 0.9800 C10 H10C 0.9800 N5 C11 1.494(4) C11 C12 1.528(4) C11 H11A 0.9900 C11 H11B 0.9900 C12 C13 1.523(4) C12 H12A 0.9900 C12 H12B 0.9900 C13 N6 1.494(4) C13 H13A 0.9900 C13 H13B 0.9900 N6 C15 1.492(4) N6 C14 1.493(4) N6 H6 0.86(4) C14 H14A 0.9800 C14 H14B 0.9800 C14 H14C 0.9800 C15 H15A 0.9800 C15 H15B 0.9800 C15 H15C 0.9800 O2 H17 0.80(5) O2 H18 0.86(5) loop_ _geom_hbond_atom_site_label_D _geom_hbond_atom_site_label_H _geom_hbond_atom_site_label_A _geom_hbond_site_symmetry_A _geom_hbond_distance_DH _geom_hbond_distance_HA _geom_hbond_distance_DA _geom_hbond_angle_DHA _geom_hbond_publ_flag N6 H6 Br3 1_546 0.86(4) 2.18(4) 3.038(4) 172(3) y O2 H18 O1 2_646 0.86(5) 1.96(4) 2.825(4) 179(3) y O2 H17 Br1 1_455 0.80(5) 2.48(4) 3.273(4) 171(3) y C2 H2A Br2 2_647 0.98 2.87 3.650(4) 137 y C3 H3A Br1 2_656 0.98 2.72 3.688(4) 170 y C5 H5C Br3 2_546 0.98 2.69 3.594(4) 153 y C7 H7B Br3 2_646 0.98 2.67 3.498(4) 142 y C8 H8C Br1 1 0.98 2.87 3.805(4) 160 y C11 H11A Br3 2_546 0.99 2.70 3.618(4) 154 y C12 H12A Br1 1_455 0.99 2.75 3.649(4) 151 y C14 H14C Br1 1_455 0.98 2.78 3.743(4) 167 y C15 H15B Br1 2_646 0.98 2.86 3.676(4) 142 y loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion N2 C1 N1 C3 -30.6(4) N5 C1 N1 C3 150.0(3) N2 C1 N1 C2 153.9(3) N5 C1 N1 C2 -25.5(4) N1 C1 N2 C5 149.2(3) N5 C1 N2 C5 -31.4(4) N1 C1 N2 C4 -30.2(4) N5 C1 N2 C4 149.2(3) N4 C6 N3 C8 -32.5(4) N5 C6 N3 C8 144.8(3) N4 C6 N3 C7 148.6(3) N5 C6 N3 C7 -34.0(4) N3 C6 N4 C9 148.6(3) N5 C6 N4 C9 -28.8(4) N3 C6 N4 C10 -34.6(4) N5 C6 N4 C10 148.0(3) N3 C6 N5 C1 140.6(3) N4 C6 N5 C1 -41.9(4) N3 C6 N5 C11 -34.9(4) N4 C6 N5 C11 142.5(3) N2 C1 N5 C6 139.8(3) N1 C1 N5 C6 -40.8(4) N2 C1 N5 C11 -44.6(4) N1 C1 N5 C11 134.8(3) C6 N5 C11 C12 -51.0(3) C1 N5 C11 C12 133.5(3) N5 C11 C12 C13 164.3(2) C11 C12 C13 N6 164.6(2) C12 C13 N6 C15 55.4(3) C12 C13 N6 C14 -73.0(3) _cod_database_fobs_code 2241495