#------------------------------------------------------------------------------ #$Date: 2016-05-07 04:04:50 +0300 (Sat, 07 May 2016) $ #$Revision: 182822 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/24/16/2241680.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2241680 _cell_angle_alpha 90.000 _cell_angle_beta 92.116 _cell_angle_gamma 90.000 _cell_length_a 12.3401 _cell_length_b 6.5421 _cell_length_c 16.1350 _exptl_crystal_F_000 680.00 _reflns_d_resolution_high 0.8092 _cod_data_source_file su5297Isup2.hkl _cod_data_source_block I _shelx_title 'GVSU1015P in P21/n no. 14' _shelx_refln_list_code 4 _shelx_f_calc_maximum 205.23 _shelx_f_squared_multiplier 1.000 loop_ _space_group_symop_operation_xyz 'x, y, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x-1/2, -y-1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 25.75 -2.38 2.38 o 4 0 0 42120.15 40695.38 1248.64 o 6 0 0 607.47 605.98 14.72 o 8 0 0 486.19 500.86 14.86 o 10 0 0 178.38 184.13 10.06 o 12 0 0 1.77 -4.75 4.75 o 14 0 0 12.24 12.52 11.23 o 1 1 0 2150.38 2300.48 21.29 o 2 1 0 9672.87 10072.08 79.03 o 3 1 0 749.71 783.28 8.70 o 4 1 0 2.95 0.02 0.77 o 5 1 0 928.96 969.09 12.24 o 6 1 0 6107.50 6530.13 61.00 o 7 1 0 4158.40 4356.50 44.21 o 8 1 0 947.03 971.79 15.50 o 9 1 0 2.92 4.95 2.06 o 10 1 0 374.00 378.81 12.05 o 11 1 0 405.39 396.84 12.94 o 12 1 0 1640.00 1680.26 34.65 o 13 1 0 38.72 23.93 5.15 o 14 1 0 588.65 610.88 25.09 o 15 1 0 375.64 416.88 21.74 o 0 2 0 1124.01 1148.89 19.17 o 1 2 0 5412.28 5414.47 48.87 o 2 2 0 7162.49 7465.79 61.16 o 3 2 0 2268.99 2449.27 23.54 o 4 2 0 385.95 386.93 7.49 o 5 2 0 9472.75 10014.49 88.94 o 6 2 0 6586.95 6836.53 59.35 o 7 2 0 14.73 16.41 2.17 o 8 2 0 486.59 418.86 22.54 o 9 2 0 157.07 157.58 9.12 o 10 2 0 1539.03 1561.27 27.68 o 11 2 0 32.42 37.19 5.23 o 12 2 0 120.50 118.73 8.17 o 13 2 0 225.17 207.14 11.02 o 14 2 0 219.00 191.93 12.55 o 1 3 0 5100.49 5334.51 50.53 o 2 3 0 267.08 231.21 5.46 o 3 3 0 1011.49 1079.07 13.79 o 4 3 0 267.08 259.95 5.72 o 5 3 0 388.85 370.41 8.90 o 6 3 0 1258.59 1221.65 25.99 o 7 3 0 149.91 124.28 9.16 o 8 3 0 1569.99 1570.81 30.14 o 9 3 0 540.26 513.85 19.33 o 10 3 0 332.03 387.00 14.78 o 11 3 0 0.48 6.14 3.74 o 12 3 0 100.96 92.30 9.65 o 13 3 0 90.09 96.42 10.26 o 14 3 0 71.65 51.49 13.59 o 0 4 0 1390.41 1474.19 28.08 o 1 4 0 1075.22 1060.31 15.94 o 2 4 0 461.16 412.12 10.64 o 3 4 0 2315.32 2285.80 33.89 o 4 4 0 31.95 25.81 3.14 o 5 4 0 49.40 44.91 4.04 o 6 4 0 3482.05 3625.74 47.38 o 7 4 0 344.09 336.32 12.88 o 8 4 0 202.69 183.80 13.73 o 9 4 0 341.64 282.73 12.85 o 10 4 0 247.25 281.47 13.29 o 11 4 0 232.04 213.53 12.35 o 12 4 0 170.65 154.76 11.02 o 13 4 0 201.72 206.97 13.29 o 1 5 0 144.90 126.79 5.62 o 2 5 0 137.11 129.17 6.03 o 3 5 0 976.57 937.93 17.61 o 4 5 0 2525.04 2637.54 40.23 o 5 5 0 86.29 86.59 8.40 o 6 5 0 23.41 19.20 4.77 o 7 5 0 934.10 1003.43 24.96 o 8 5 0 557.68 628.49 19.93 o 9 5 0 0.36 0.05 3.28 o 10 5 0 150.48 145.45 12.19 o 11 5 0 192.51 200.76 14.72 o 0 6 0 1422.51 1428.10 33.46 o 1 6 0 293.79 259.69 9.22 o 2 6 0 43.67 37.80 4.51 o 3 6 0 316.48 281.22 10.99 o 4 6 0 990.84 999.01 22.10 o 5 6 0 272.21 263.57 11.26 o 6 6 0 10.76 6.28 3.55 o 7 6 0 295.17 283.94 36.69 o 8 6 0 16.99 8.73 5.34 o 9 6 0 217.95 222.40 15.50 o 10 6 0 37.48 30.70 8.13 o 1 7 0 2.05 -0.27 2.47 o 2 7 0 1845.90 2017.94 34.69 o 3 7 0 191.92 199.59 11.60 o 4 7 0 77.91 60.44 7.82 o 5 7 0 3.20 -0.59 3.39 o 6 7 0 19.19 15.44 5.29 o 7 7 0 576.85 662.47 26.65 o 0 8 0 0.39 3.89 8.20 o 1 8 0 66.97 61.11 30.44 o 2 8 0 7.33 11.88 7.63 o -15 0 1 7.07 13.82 11.23 o -13 0 1 12.48 8.20 8.64 o -11 0 1 8.62 4.40 3.15 o -9 0 1 1365.86 1300.28 27.88 o -7 0 1 2213.05 2286.17 37.86 o -5 0 1 2483.85 2241.36 34.27 o -3 0 1 6694.48 6951.74 85.50 o -1 0 1 2921.92 3030.24 37.14 o 1 0 1 3493.53 3716.68 44.95 o 3 0 1 33998.72 31339.01 377.11 o 5 0 1 186.44 187.95 12.29 o 7 0 1 3272.85 3422.09 51.27 o 9 0 1 505.34 496.95 16.71 o 11 0 1 71.07 66.62 8.70 o 13 0 1 11.06 10.80 8.64 o 15 0 1 33.35 32.09 10.26 o -15 1 1 46.43 43.76 9.27 o -14 1 1 576.36 578.58 24.47 o -13 1 1 2.66 3.45 3.61 o -12 1 1 24.00 19.60 4.11 o -11 1 1 7.16 2.64 2.56 o -10 1 1 1221.86 1235.80 28.55 o -9 1 1 1442.55 1388.90 20.54 o -8 1 1 908.75 894.17 14.84 o -7 1 1 48.18 48.55 3.90 o -6 1 1 460.69 483.22 10.49 o -5 1 1 1053.73 1090.92 14.26 o -4 1 1 1953.22 1995.40 20.35 o -3 1 1 5037.54 5406.03 50.16 o -2 1 1 3834.48 3995.11 36.39 o -1 1 1 3290.40 3416.56 28.27 o 0 1 1 1255.36 1300.87 12.09 o 1 1 1 4275.39 4343.99 35.19 o 2 1 1 11.30 9.83 1.82 o 3 1 1 67.63 59.16 1.99 o 4 1 1 612.21 569.34 7.56 o 5 1 1 61.59 45.48 2.55 o 6 1 1 675.23 679.33 10.39 o 7 1 1 1543.44 1433.47 17.89 o 8 1 1 76.36 61.80 3.57 o 9 1 1 2434.65 2466.21 31.25 o 10 1 1 302.41 272.32 9.01 o 11 1 1 194.89 186.76 8.90 o 12 1 1 191.75 187.05 11.99 o 13 1 1 158.77 155.39 10.36 o 14 1 1 3.64 -0.96 4.72 o 15 1 1 174.85 155.21 19.40 o -14 2 1 224.38 206.50 17.58 o -13 2 1 124.08 120.43 8.39 o -12 2 1 18.29 3.38 3.34 o -11 2 1 11.64 13.70 3.64 o -10 2 1 1448.41 1493.62 26.80 o -9 2 1 2.28 -0.19 1.83 o -8 2 1 293.95 279.35 8.79 o -7 2 1 69.54 68.58 3.60 o -6 2 1 596.09 681.54 10.46 o -5 2 1 603.64 573.05 9.80 o -4 2 1 3938.73 3996.07 43.70 o -3 2 1 11220.78 11547.33 100.82 o -2 2 1 3256.60 3252.56 29.28 o -1 2 1 166.98 158.31 4.67 o 0 2 1 7213.07 7268.20 63.93 o 1 2 1 15195.70 15398.36 130.12 o 2 2 1 3198.71 3275.83 31.73 o 3 2 1 159.75 150.06 3.44 o 4 2 1 2425.45 2665.86 26.36 o 5 2 1 1.35 -0.18 1.04 o 6 2 1 461.50 431.30 8.85 o 7 2 1 416.39 388.62 8.20 o 8 2 1 804.99 789.88 16.95 o 9 2 1 206.68 175.14 8.01 o 10 2 1 53.33 51.78 5.57 o 11 2 1 13.85 13.48 3.61 o 12 2 1 43.68 53.67 6.48 o 13 2 1 36.35 31.12 8.48 o 14 2 1 0.01 -1.06 3.59 o -14 3 1 95.58 90.58 11.41 o -13 3 1 715.86 776.08 24.01 o -12 3 1 1.58 -0.55 2.86 o -11 3 1 418.42 456.31 19.28 o -10 3 1 185.80 193.80 10.55 o -9 3 1 50.85 47.60 5.90 o -8 3 1 2.79 1.96 2.36 o -7 3 1 32.29 19.89 3.29 o -6 3 1 1397.01 1337.56 21.72 o -5 3 1 414.65 407.68 10.26 o -4 3 1 26.57 16.73 2.34 o -3 3 1 152.81 175.41 4.55 o -2 3 1 44.78 27.88 2.21 o -1 3 1 118.03 133.67 4.11 o 0 3 1 19.95 15.80 1.96 o 1 3 1 165.40 223.72 5.73 o 2 3 1 1126.66 1175.25 15.63 o 3 3 1 198.11 180.32 5.20 o 4 3 1 3555.03 3607.39 37.93 o 5 3 1 153.65 111.43 4.79 o 6 3 1 254.69 251.42 8.86 o 7 3 1 0.67 3.63 2.14 o 8 3 1 769.73 764.05 19.59 o 9 3 1 679.30 652.51 18.81 o 10 3 1 38.26 31.28 6.86 o 11 3 1 531.45 537.64 18.39 o 12 3 1 122.22 106.43 11.28 o 13 3 1 1416.37 1502.54 41.58 o 14 3 1 0.42 2.27 4.91 o -13 4 1 84.09 80.97 11.47 o -12 4 1 1.93 0.93 4.87 o -11 4 1 443.98 423.11 16.93 o -10 4 1 0.68 1.13 3.20 o -9 4 1 0.33 0.76 2.81 o -8 4 1 1141.51 1231.74 27.28 o -7 4 1 526.27 507.10 15.94 o -6 4 1 378.19 349.04 12.59 o -5 4 1 62.11 59.42 4.60 o -4 4 1 2714.15 2789.79 33.59 o -3 4 1 1639.82 1638.23 22.77 o -2 4 1 1.44 3.13 1.25 o -1 4 1 138.67 126.82 4.57 o 0 4 1 1181.60 1230.17 17.54 o 1 4 1 1501.28 1416.41 26.56 o 2 4 1 399.65 347.78 8.42 o 3 4 1 5.07 3.04 1.35 o 4 4 1 483.77 495.31 12.49 o 5 4 1 251.42 253.29 9.32 o 6 4 1 3891.99 4157.85 52.51 o 7 4 1 58.84 43.84 5.17 o 8 4 1 520.54 491.27 16.42 o 9 4 1 52.96 49.75 6.70 o 10 4 1 30.12 26.67 5.65 o 11 4 1 60.12 62.53 8.07 o 12 4 1 366.88 376.68 16.96 o 13 4 1 33.52 40.63 10.67 o -11 5 1 0.00 0.86 4.29 o -10 5 1 149.75 158.67 13.04 o -9 5 1 12.28 13.85 5.40 o -8 5 1 375.16 428.73 16.31 o -7 5 1 173.63 181.78 13.71 o -6 5 1 8.63 7.18 3.19 o -5 5 1 244.38 238.61 9.88 o -4 5 1 233.95 227.35 8.32 o -3 5 1 169.45 169.47 7.08 o -2 5 1 1069.76 1048.10 18.19 o -1 5 1 1353.45 1319.81 20.69 o 0 5 1 2313.38 2268.04 26.83 o 1 5 1 377.38 377.53 9.69 o 2 5 1 873.51 821.63 17.91 o 3 5 1 1911.68 1914.72 27.07 o 4 5 1 13.63 8.42 2.82 o 5 5 1 14.11 16.57 3.77 o 6 5 1 20.87 19.02 4.08 o 7 5 1 25.83 21.03 4.31 o 8 5 1 39.84 40.59 6.14 o 9 5 1 79.90 58.99 8.41 o 10 5 1 274.99 270.44 14.02 o 11 5 1 21.95 25.32 6.29 o -10 6 1 5.68 9.61 5.65 o -9 6 1 161.88 151.89 15.75 o -8 6 1 1.44 -3.42 3.42 o -7 6 1 1.54 0.69 4.12 o -6 6 1 76.16 68.79 9.70 o -5 6 1 895.43 922.75 24.91 o -4 6 1 28.73 22.05 4.47 o -3 6 1 126.15 118.74 6.71 o -2 6 1 166.38 153.30 7.85 o -1 6 1 213.77 228.99 8.77 o 0 6 1 45.87 54.79 5.80 o 1 6 1 254.38 232.48 8.85 o 2 6 1 1422.68 1383.63 23.29 o 3 6 1 127.38 129.35 8.44 o 4 6 1 323.08 345.98 12.61 o 5 6 1 0.23 1.37 2.81 o 6 6 1 196.78 191.09 10.20 o 7 6 1 21.40 11.57 4.30 o 8 6 1 0.01 2.56 4.04 o 9 6 1 87.78 75.29 15.54 o 10 6 1 76.19 61.81 10.67 o -7 7 1 731.40 896.11 39.17 o -6 7 1 0.34 -2.07 4.25 o -5 7 1 33.14 28.02 7.14 o -4 7 1 190.66 185.79 12.90 o -3 7 1 550.96 558.29 19.28 o -2 7 1 185.34 179.42 11.41 o -1 7 1 107.35 100.44 11.90 o 0 7 1 241.42 249.56 10.12 o 1 7 1 70.04 58.51 6.69 o 2 7 1 310.16 306.11 14.17 o 3 7 1 35.71 33.41 6.14 o 4 7 1 16.28 21.19 5.70 o 5 7 1 361.58 375.46 16.54 o 6 7 1 18.85 20.40 5.67 o 7 7 1 27.89 13.66 6.86 o -2 8 1 10.11 8.73 5.25 o -1 8 1 3.64 4.72 3.99 o 0 8 1 176.75 182.42 14.01 o 1 8 1 0.21 -5.34 5.34 o 2 8 1 4.50 2.59 9.93 o -14 0 2 461.19 424.91 35.84 o -12 0 2 129.12 127.82 18.14 o -10 0 2 8226.16 8306.25 114.55 o -8 0 2 2.10 0.22 1.71 o -6 0 2 2204.29 2289.75 36.56 o -4 0 2 962.67 963.58 17.55 o -2 0 2 1947.86 1956.31 26.81 o 0 0 2 3583.28 3743.46 46.28 o 2 0 2 3655.18 3714.59 47.08 o 4 0 2 1318.23 1426.05 31.49 o 6 0 2 1640.68 1739.94 29.50 o 8 0 2 969.12 895.75 20.92 o 10 0 2 3.64 1.50 3.20 o 12 0 2 287.14 261.31 31.09 o 14 0 2 170.76 178.53 18.31 o -15 1 2 0.73 1.32 5.14 o -14 1 2 59.79 52.42 12.05 o -13 1 2 31.85 26.79 5.09 o -12 1 2 1073.05 1097.39 30.98 o -11 1 2 63.37 64.13 7.00 o -10 1 2 113.76 105.97 6.51 o -9 1 2 409.27 386.95 9.72 o -8 1 2 198.27 197.37 6.43 o -7 1 2 133.68 125.62 4.78 o -6 1 2 90.76 101.67 3.96 o -5 1 2 3219.32 3541.61 35.82 o -4 1 2 1568.29 1719.59 18.97 o -3 1 2 2166.70 2208.28 20.48 o -2 1 2 371.34 362.49 4.43 o -1 1 2 4.21 1.59 1.00 o 0 1 2 545.14 560.60 6.94 o 1 1 2 1818.89 1855.69 16.81 o 2 1 2 8616.36 8726.63 82.53 o 3 1 2 1645.32 1651.30 16.21 o 4 1 2 1804.34 1810.57 20.73 o 5 1 2 0.14 1.90 0.84 o 6 1 2 246.99 198.13 6.70 o 7 1 2 724.01 662.10 10.90 o 8 1 2 928.49 897.70 15.61 o 9 1 2 1326.37 1301.77 20.60 o 10 1 2 2520.54 2455.53 32.52 o 11 1 2 225.74 225.14 11.21 o 12 1 2 85.65 78.59 8.47 o 13 1 2 338.35 345.04 22.50 o 14 1 2 914.26 947.91 28.22 o -14 2 2 320.23 291.22 13.59 o -13 2 2 180.04 179.91 9.89 o -12 2 2 216.84 212.00 10.32 o -11 2 2 75.44 71.08 6.69 o -10 2 2 2247.72 2347.41 35.62 o -9 2 2 271.04 241.39 9.56 o -8 2 2 726.23 698.54 14.29 o -7 2 2 2162.88 2085.99 26.54 o -6 2 2 3418.85 3657.68 34.71 o -5 2 2 537.50 574.03 10.73 o -4 2 2 15545.55 15924.89 150.68 o -3 2 2 2079.18 1958.78 37.31 o -2 2 2 12.68 14.53 1.62 o -1 2 2 23.84 38.53 1.95 o 0 2 2 5525.17 5732.40 47.82 o 1 2 2 418.75 441.26 8.04 o 2 2 2 1811.01 1830.90 19.87 o 3 2 2 1426.50 1387.13 14.92 o 4 2 2 38.11 22.93 2.27 o 5 2 2 306.61 310.62 7.25 o 6 2 2 2.95 2.86 1.22 o 7 2 2 261.48 234.02 9.36 o 8 2 2 197.65 191.78 6.83 o 9 2 2 110.80 93.82 6.64 o 10 2 2 249.44 222.41 12.09 o 11 2 2 385.68 372.88 17.03 o 12 2 2 11.63 8.92 4.80 o 13 2 2 127.55 108.43 10.07 o 14 2 2 10.58 12.84 4.89 o -14 3 2 366.97 374.56 29.25 o -13 3 2 21.47 19.51 5.51 o -12 3 2 9.29 7.55 4.14 o -11 3 2 842.88 842.50 24.56 o -10 3 2 135.22 130.35 12.30 o -9 3 2 1.46 0.74 2.56 o -8 3 2 69.20 76.94 11.18 o -7 3 2 68.21 51.06 6.21 o -6 3 2 275.03 268.87 11.34 o -5 3 2 48.79 57.93 6.53 o -4 3 2 161.47 144.04 5.81 o -3 3 2 414.02 382.50 7.33 o -2 3 2 670.10 668.25 12.10 o -1 3 2 846.80 799.32 11.20 o 0 3 2 378.84 414.47 7.52 o 1 3 2 266.20 254.16 6.54 o 2 3 2 894.01 1022.04 14.41 o 3 3 2 1212.16 1188.64 16.07 o 4 3 2 3602.73 3639.54 35.22 o 5 3 2 426.66 460.59 7.91 o 6 3 2 701.80 653.60 12.51 o 7 3 2 67.31 73.58 5.81 o 8 3 2 4315.55 4464.75 62.29 o 9 3 2 241.94 232.96 11.21 o 10 3 2 426.99 447.15 16.02 o 11 3 2 125.52 111.51 8.82 o 12 3 2 524.55 545.72 19.32 o 13 3 2 12.44 7.31 5.71 o 14 3 2 7.67 3.72 5.62 o -13 4 2 91.85 90.11 16.96 o -12 4 2 28.62 19.91 6.33 o -11 4 2 49.80 48.72 8.56 o -10 4 2 141.06 136.12 17.67 o -9 4 2 97.39 102.25 9.91 o -8 4 2 842.68 892.64 22.44 o -7 4 2 213.26 229.17 10.59 o -6 4 2 579.23 559.21 13.94 o -5 4 2 597.25 620.52 14.32 o -4 4 2 4970.83 5090.15 53.47 o -3 4 2 974.29 947.12 16.02 o -2 4 2 114.26 116.38 4.39 o -1 4 2 102.35 78.26 3.67 o 0 4 2 867.51 865.14 13.06 o 1 4 2 3025.84 2998.19 30.86 o 2 4 2 85.10 63.36 3.91 o 3 4 2 14.04 14.22 2.71 o 4 4 2 459.34 431.92 12.25 o 5 4 2 1027.85 1062.98 20.66 o 6 4 2 918.78 903.77 19.50 o 7 4 2 3.95 5.29 2.55 o 8 4 2 92.29 92.97 7.29 o 9 4 2 49.52 40.95 6.13 o 10 4 2 432.48 474.27 25.43 o 11 4 2 46.99 35.72 6.37 o 12 4 2 79.73 78.15 9.36 o 13 4 2 49.74 38.76 7.50 o -11 5 2 93.77 74.29 10.96 o -10 5 2 632.46 671.61 26.40 o -9 5 2 74.86 76.57 14.89 o -8 5 2 18.50 7.79 5.59 o -7 5 2 19.14 18.26 10.92 o -6 5 2 2640.30 2795.29 45.89 o -5 5 2 222.53 207.71 9.20 o -4 5 2 69.72 58.29 4.96 o -3 5 2 287.46 257.18 8.64 o -2 5 2 535.24 509.26 20.72 o -1 5 2 38.65 22.52 3.18 o 0 5 2 5.35 3.53 1.73 o 1 5 2 409.54 381.61 9.11 o 2 5 2 427.86 408.05 10.41 o 3 5 2 2779.59 2799.02 43.40 o 4 5 2 877.89 937.46 20.00 o 5 5 2 92.43 85.36 7.00 o 6 5 2 241.31 234.49 10.33 o 7 5 2 456.37 497.21 16.65 o 8 5 2 99.84 88.56 8.46 o 9 5 2 68.21 58.95 7.59 o 10 5 2 495.04 456.86 18.24 o 11 5 2 16.13 17.19 5.73 o -10 6 2 61.72 66.39 11.02 o -9 6 2 555.43 537.23 49.96 o -8 6 2 36.85 29.32 7.29 o -7 6 2 23.82 24.00 6.16 o -6 6 2 90.71 73.50 9.67 o -5 6 2 31.18 26.80 6.02 o -4 6 2 0.08 -0.86 2.66 o -3 6 2 0.01 -0.66 2.20 o -2 6 2 541.74 535.76 13.53 o -1 6 2 1440.71 1491.30 24.08 o 0 6 2 21.91 23.31 4.00 o 1 6 2 8.56 6.11 2.88 o 2 6 2 875.49 850.15 18.82 o 3 6 2 43.56 39.22 5.30 o 4 6 2 13.92 5.13 3.28 o 5 6 2 1151.14 1186.20 25.28 o 6 6 2 609.99 636.03 18.34 o 7 6 2 106.68 93.89 8.37 o 8 6 2 109.98 82.03 8.49 o 9 6 2 1524.94 1587.56 36.71 o 10 6 2 447.33 452.65 19.31 o -7 7 2 20.69 14.46 6.39 o -6 7 2 4.29 -0.44 4.51 o -5 7 2 344.75 363.12 18.78 o -4 7 2 295.28 297.60 16.49 o -3 7 2 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