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Information card for entry 4066703
Preview
| Coordinates | 4066703.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C29 H33 Cl N2 O2 Si |
|---|---|
| Calculated formula | C29 H33 Cl N2 O2 Si |
| SMILES | Cl[Si]12([N](=C(N1C(C)(C)C)c1ccccc1)C(C)(C)C)OC(=C(O2)c1ccccc1)c1ccccc1 |
| Title of publication | Reactions of a Bis-silylene (LSi−SiL, L = PhC(NtBu)2) and a Heteroleptic Chloro Silylene (LSiCl) with Benzil: Formation of Bis(siladioxolene) and Monosiladioxolene Analogue with Five-Coordinate Silicon Atoms in Both Ring Systems |
| Authors of publication | Tavčar, Gašper; Sen, Sakya S.; Roesky, Herbert W.; Hey, Jakob; Kratzert, Daniel; Stalke, Dietmar |
| Journal of publication | Organometallics |
| Year of publication | 2010 |
| Journal volume | 29 |
| Journal issue | 17 |
| Pages of publication | 3930 |
| a | 12.2971 ± 0.0004 Å |
| b | 18.4375 ± 0.0006 Å |
| c | 11.5359 ± 0.0003 Å |
| α | 90° |
| β | 95.673 ± 0.002° |
| γ | 90° |
| Cell volume | 2602.7 ± 0.14 Å3 |
| Cell temperature | 100 ± 2 K |
| Ambient diffraction temperature | 100 ± 2 K |
| Number of distinct elements | 6 |
| Space group number | 14 |
| Hermann-Mauguin space group symbol | P 1 21/c 1 |
| Hall space group symbol | -P 2ybc |
| Residual factor for all reflections | 0.0556 |
| Residual factor for significantly intense reflections | 0.0392 |
| Weighted residual factors for significantly intense reflections | 0.0917 |
| Weighted residual factors for all reflections included in the refinement | 0.1 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.06 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 178559 (current) | 2016-03-21 | cif/4/06/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/06/67. |
4066703.cif |
| 91935 | 2013-12-29 | cod/ (saulius@koala.ibt.lt) Adding DOIs that could be assigned unambiguously to the rest of COD CIFs. |
4066703.cif |
| 34330 | 2012-02-24 | cif/4/ Reorganising CIF range 4 into a prefix tree. |
4066703.cif |
| 33965 | 2012-02-13 | ../uploads/cif-deposit/cod/cif Adding structures of 4066703, 4066704 via cif-deposit CGI script. |
4066703.cif |
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