Crystallography Open Database

Information card for entry 4068423

Preview

Coordinates	4068423.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C86 H113 Cl O6 P3 Rh
Calculated formula	C86 H113 Cl O6 P3 Rh
Title of publication	Rhodium Complexes with Pincer Diphosphite Ligands. Unusual Olefin in-Plane Coordination in Square-Planar Compounds†
Authors of publication	Rubio, Miguel; Suárez, Andrés; del Río, Diego; Galindo, Agustín; Álvarez, Eleuterio; Pizzano, Antonio
Journal of publication	Organometallics
Year of publication	2009
Journal volume	28
Journal issue	2
Pages of publication	547
a	13.4989 ± 0.0008 Å
b	16.7201 ± 0.0009 Å
c	19.3595 ± 0.0011 Å
α	110.784 ± 0.003°
β	96.741 ± 0.003°
γ	97.17 ± 0.003°
Cell volume	3991.2 ± 0.4 Å³
Cell temperature	100 ± 2 K
Ambient diffraction temperature	100 ± 2 K
Number of distinct elements	6
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.1368
Residual factor for significantly intense reflections	0.0693
Weighted residual factors for significantly intense reflections	0.1608
Weighted residual factors for all reflections included in the refinement	0.1943
Goodness-of-fit parameter for all reflections included in the refinement	1.016
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
178574 (current)	2016-03-21	cif/4/06/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/06/84.	4068423.cif
91935	2013-12-29	cod/ (saulius@koala.ibt.lt) Adding DOIs that could be assigned unambiguously to the rest of COD CIFs.	4068423.cif
39756	2012-03-07	../uploads/cif-deposit/cod/cif Adding structures of 4068423, 4068424, 4068425, 4068426, 4068427, 4068428, 4068429 via cif-deposit CGI script.	4068423.cif