Crystallography Open Database

Information card for entry 4068464

Preview

Coordinates	4068464.cif
Original paper (by DOI)	HTML

Structure parameters

Chemical name	Di(η^5^-cyclopentadienyl)molybdenum-bis(bismuthdi(tri phenylsilanolat))
Formula	C82 H70 Bi2 Mo O4 Si4
Calculated formula	C82 H70 Bi2 Mo O4 Si4
Title of publication	Opening of Bent Bi−C Bonds by Silanols To Give Stable Cp2Mo(μ-BiOR)2MoCp2Complexes
Authors of publication	Knispel, Christina; Limberg, Christian; Mehring, Michael
Journal of publication	Organometallics
Year of publication	2009
Journal volume	28
Journal issue	2
Pages of publication	646
a	23.6397 ± 0.0004 Å
b	11.3979 ± 0.0002 Å
c	27.0463 ± 0.0004 Å
α	90°
β	107.421 ± 0.002°
γ	90°
Cell volume	6953.2 ± 0.2 Å³
Cell temperature	150 ± 2 K
Ambient diffraction temperature	150 ± 2 K
Number of distinct elements	6
Space group number	13
Hermann-Mauguin space group symbol	P 1 2/n 1
Hall space group symbol	-P 2yac
Residual factor for all reflections	0.0393
Residual factor for significantly intense reflections	0.0266
Weighted residual factors for significantly intense reflections	0.0511
Weighted residual factors for all reflections included in the refinement	0.0536
Goodness-of-fit parameter for all reflections included in the refinement	0.931
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
178574 (current)	2016-03-21	cif/4/06/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/06/84.	4068464.cif
91935	2013-12-29	cod/ (saulius@koala.ibt.lt) Adding DOIs that could be assigned unambiguously to the rest of COD CIFs.	4068464.cif
39777	2012-03-07	../uploads/cif-deposit/cod/cif Adding structures of 4068462, 4068463, 4068464 via cif-deposit CGI script.	4068464.cif