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Information card for entry 4068768
Preview
| Coordinates | 4068768.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C106 H136 O2 P4 Rh2 |
|---|---|
| Calculated formula | C106 H136 O2 P4 Rh2 |
| SMILES | [Rh]123([Rh]4([P](=C5C(=C(C5=[P]4c4c(cc(cc4C(C)(C)C)C(C)(C)C)C(C)(C)C)c4ccccc4)c4ccccc4)c4c(cc(cc4C(C)(C)C)C(C)(C)C)C(C)(C)C)(C2=O)C3=O)[P](=C2C(=C(C2=[P]1c1c(cc(cc1C(C)(C)C)C(C)(C)C)C(C)(C)C)c1ccccc1)c1ccccc1)c1c(cc(cc1C(C)(C)C)C(C)(C)C)C(C)(C)C |
| Title of publication | Synthesis, Structures, and Reactions of Dirhodium Complexes Bearing a 1,2-Diphenyl-3,4-diphosphinidenecyclobutene Ligand (DPCB) |
| Authors of publication | Okazaki, Masaaki; Hayashi, Akito; Fu, Ching-Feng; Liu, Shiuh-Tzung; Ozawa, Fumiyuki |
| Journal of publication | Organometallics |
| Year of publication | 2009 |
| Journal volume | 28 |
| Journal issue | 3 |
| Pages of publication | 902 |
| a | 23.782 ± 0.005 Å |
| b | 28.125 ± 0.006 Å |
| c | 34.019 ± 0.008 Å |
| α | 90° |
| β | 110.534 ± 0.003° |
| γ | 90° |
| Cell volume | 21309 ± 8 Å3 |
| Cell temperature | 173 ± 2 K |
| Ambient diffraction temperature | 173 ± 2 K |
| Number of distinct elements | 5 |
| Space group number | 15 |
| Hermann-Mauguin space group symbol | C 1 2/c 1 |
| Hall space group symbol | -C 2yc |
| Residual factor for all reflections | 0.2073 |
| Residual factor for significantly intense reflections | 0.17 |
| Weighted residual factors for significantly intense reflections | 0.3018 |
| Weighted residual factors for all reflections included in the refinement | 0.3222 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.338 |
| Diffraction radiation probe | x-ray |
| Diffraction radiation wavelength | 0.7107 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 178577 (current) | 2016-03-21 | cif/4/06/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/06/87. |
4068768.cif |
| 91935 | 2013-12-29 | cod/ (saulius@koala.ibt.lt) Adding DOIs that could be assigned unambiguously to the rest of COD CIFs. |
4068768.cif |
| 39965 | 2012-03-07 | ../uploads/cif-deposit/cod/cif Adding structures of 4068764, 4068765, 4068766, 4068767, 4068768 via cif-deposit CGI script. |
4068768.cif |
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