Crystallography Open Database

Information card for entry 4069187

Preview

Coordinates	4069187.cif
Original paper (by DOI)	HTML

Structure parameters

Common name	Hafnium bis(trimethylsilyl)amide chloride THF
Chemical name	Hafnium bis(trimethylsilyl)amide chloride THF
Formula	C16 H44 Cl2 Hf N2 O Si4
Calculated formula	C16 H44 Cl2 Hf N2 O Si4
SMILES	C[Si](C)(C)N([Hf](Cl)(Cl)(N([Si](C)(C)C)[Si](C)(C)C)[O]1CCCC1)[Si](C)(C)C
Title of publication	Synthesis and Characterization of Group 4 Amide Chloride and Amide Imide Complexes
Authors of publication	Yu, Xianghua; Chen, Shu-Jian; Wang, Xiaoping; Chen, Xue-Tai; Xue, Zi-Ling
Journal of publication	Organometallics
Year of publication	2009
Journal volume	28
Journal issue	15
Pages of publication	4269
a	15.925 ± 0.006 Å
b	25.866 ± 0.009 Å
c	13.838 ± 0.005 Å
α	90°
β	93.397 ± 0.006°
γ	90°
Cell volume	5690 ± 4 Å³
Cell temperature	173 ± 2 K
Ambient diffraction temperature	173 ± 2 K
Number of distinct elements	7
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/c 1
Hall space group symbol	-P 2ybc
Residual factor for all reflections	0.0399
Residual factor for significantly intense reflections	0.028
Weighted residual factors for significantly intense reflections	0.0769
Weighted residual factors for all reflections included in the refinement	0.1075
Goodness-of-fit parameter for all reflections included in the refinement	1.11
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
178580 (current)	2016-03-21	cif/4/06/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/06/91.	4069187.cif
91935	2013-12-29	cod/ (saulius@koala.ibt.lt) Adding DOIs that could be assigned unambiguously to the rest of COD CIFs.	4069187.cif
40172	2012-03-07	../uploads/cif-deposit/cod/cif Adding structures of 4069187 via cif-deposit CGI script.	4069187.cif