Crystallography Open Database

Information card for entry 4069673

Preview

Coordinates	4069673.cif
Original paper (by DOI)	HTML

Structure parameters

Common name	Ru=SiHMesF
Formula	C26 H36 F9 P Ru Si
Calculated formula	C26 H36 F9 P Ru Si
SMILES	[RuH]1234([P](C)(C(C)C)C(C)C)(=[SiH]c5c(C(F)(F)F)cc(cc5C(F)(F)F)C(F)(F)F)[c]5([c]3([c]2(C)[c]4([c]15C)C)C)C
Title of publication	Synthesis, Structure, and Reactivity of Neutral Hydrogen-Substituted Ruthenium Silylene and Germylene Complexes
Authors of publication	Hayes, Paul G.; Waterman, Rory; Glaser, Paul B.; Tilley, T. Don
Journal of publication	Organometallics
Year of publication	2009
Journal volume	28
Journal issue	17
Pages of publication	5082
a	19.5557 ± 0.0016 Å
b	8.733 ± 0.0007 Å
c	34.735 ± 0.003 Å
α	90°
β	100.308 ± 0.002°
γ	90°
Cell volume	5836.3 ± 0.8 Å³
Cell temperature	152 ± 2 K
Ambient diffraction temperature	152 ± 2 K
Number of distinct elements	6
Space group number	15
Hermann-Mauguin space group symbol	C 1 2/c 1
Hall space group symbol	-C 2yc
Residual factor for all reflections	0.0522
Residual factor for significantly intense reflections	0.0406
Weighted residual factors for significantly intense reflections	0.1011
Weighted residual factors for all reflections included in the refinement	0.1062
Goodness-of-fit parameter for all reflections included in the refinement	1.033
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
178585 (current)	2016-03-21	cif/4/06/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/06/96.	4069673.cif
91935	2013-12-29	cod/ (saulius@koala.ibt.lt) Adding DOIs that could be assigned unambiguously to the rest of COD CIFs.	4069673.cif
40383	2012-03-07	../uploads/cif-deposit/cod/cif Adding structures of 4069671, 4069672, 4069673, 4069674, 4069675 via cif-deposit CGI script.	4069673.cif