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Information card for entry 4070574
Preview
| Coordinates | 4070574.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Common name | Ir2(tfepma)3H4 |
|---|---|
| Formula | C27 H37 F36 Ir2 N3 O12 P6 |
| Calculated formula | C27 H37 F36 Ir2 N3 O12 P6 |
| Title of publication | Intramolecular C−H Bond Activation and Redox Isomerization across Two-Electron Mixed Valence Diiridium Cores |
| Authors of publication | Esswein, Arthur J.; Veige, Adam S.; Piccoli, Paula M. B.; Schultz, Arthur J.; Nocera, Daniel G. |
| Journal of publication | Organometallics |
| Year of publication | 2008 |
| Journal volume | 27 |
| Journal issue | 6 |
| Pages of publication | 1073 |
| a | 11.982 ± 0.004 Å |
| b | 12.206 ± 0.005 Å |
| c | 21.559 ± 0.008 Å |
| α | 80.422 ± 0.033° |
| β | 79.953 ± 0.027° |
| γ | 61.608 ± 0.028° |
| Cell volume | 2718.6 ± 1.9 Å3 |
| Cell temperature | 193 K |
| Ambient diffraction temperature | 193 K |
| Number of distinct elements | 7 |
| Space group number | 2 |
| Hermann-Mauguin space group symbol | P -1 |
| Hall space group symbol | -P 1 |
| Method of determination | powder diffraction |
| Diffraction radiation probe | neutron |
| Diffraction radiation type | neutron |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 176467 (current) | 2016-02-16 | cif/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in range 4. |
4070574.cif |
| 120075 | 2014-07-11 | Adding DOIs to range 4/07 structures. | 4070574.cif |
| 106285 | 2014-03-15 | cod/ (saulius@kolibris) Adding the '_diffrn_radiation_probe neutron' data item to those COD CIFs that declared neuron radiation in their _diffrn_radiation_type data field, and did not have a _diffrn_radiation_probe item yet: codsql 'select file from data where radiation is null and radType like "%neutron%"' -NB \ | codid2file \ | xargs -i sh -c 'test -f {} && ( set -x; echo _diffrn_radiation_probe neutron >> {} )' Two files that had no newlines at the end were fixed manually. |
4070574.cif |
| 47256 | 2012-03-23 | cif/4/ Distributing the new range 4 CIFs into their appropriate prefixed subdirectories. |
4070574.cif |
| 42570 | 2012-03-13 | ../uploads/cif-deposit/cod/cif Adding structures of 4070574 via cif-deposit CGI script. |
4070574.cif |
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Users of the data should acknowledge the original authors of the
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