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Information card for entry 4070735
Preview
| Coordinates | 4070735.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C54 H110 Al2 Li2 N2 O4 Si4 |
|---|---|
| Calculated formula | C54 H110 Al2 Li2 N2 O4 Si4 |
| SMILES | [AlH]1(N(C([Si](C)(C)C)[Si](C)(C)C)c2c(cccc2C(C)C)C(C)C)[H][Li]([O]2CCCC2)([O]2CCCC2)[H][AlH](N(C([Si](C)(C)C)[Si](C)(C)C)c2c(cccc2C(C)C)C(C)C)[H][Li]([O]2CCCC2)([O]2CCCC2)[H]1 |
| Title of publication | Synthesis and Characterization of the Monomeric Vicinal Dianion Li~2~(THF)~3~[ArNC(SiMe~3~)~2~] and the Aluminum and Lithium Derivatives of the Amido Ligand [ArNCH(SiMe~3~)~2~]^-^ |
| Authors of publication | Cheng, Xiaoyan; Zhang, Jianying; Song, Haibin; Cui, Chunming |
| Journal of publication | Organometallics |
| Year of publication | 2008 |
| Journal volume | 27 |
| Journal issue | 4 |
| Pages of publication | 678 - 682 |
| a | 13.225 ± 0.002 Å |
| b | 17.355 ± 0.003 Å |
| c | 14.27 ± 0.003 Å |
| α | 90° |
| β | 95.577 ± 0.002° |
| γ | 90° |
| Cell volume | 3259.7 ± 1 Å3 |
| Cell temperature | 113 ± 2 K |
| Ambient diffraction temperature | 113 ± 2 K |
| Number of distinct elements | 7 |
| Space group number | 14 |
| Hermann-Mauguin space group symbol | P 1 21/n 1 |
| Hall space group symbol | -P 2yn |
| Residual factor for all reflections | 0.0689 |
| Residual factor for significantly intense reflections | 0.0562 |
| Weighted residual factors for significantly intense reflections | 0.1312 |
| Weighted residual factors for all reflections included in the refinement | 0.1392 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.072 |
| Diffraction radiation wavelength | 0.7107 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 209848 (current) | 2018-08-17 | cif/4/ Updating bibliography in entries 4070735-4070739, 4083494. Marking entry 4083494 as a duplicat of entry 4070735. |
4070735.cif |
| 178596 | 2016-03-21 | cif/4/07/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/07/07. |
4070735.cif |
| 120075 | 2014-07-11 | Adding DOIs to range 4/07 structures. | 4070735.cif |
| 102833 | 2014-02-24 | cif/4 Fixing several formula and Z values. |
4070735.cif |
| 47256 | 2012-03-23 | cif/4/ Distributing the new range 4 CIFs into their appropriate prefixed subdirectories. |
4070735.cif |
| 42663 | 2012-03-13 | ../uploads/cif-deposit/cod/cif Adding structures of 4070735 via cif-deposit CGI script. |
4070735.cif |
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Users of the data should acknowledge the original authors of the
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