Crystallography Open Database
- COD Home
- Accessing COD Data
- Add Your Data
- Documentation
Information card for entry 4071032
Preview
| Coordinates | 4071032.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Common name | Moris-78 (lipmetox) |
|---|---|
| Formula | C20 H41 Li N4 O Si2 |
| Calculated formula | C20 H41 Li N4 O Si2 |
| SMILES | [Si](N1C(=[N]([Si](C)(C)C)[Li]21[N](CC[N]2(C)C)(C)C)c1ccc(OC)cc1)(C)(C)C |
| Title of publication | N,N′-Bis-Silylated Lithium Aryl Amidinates: Synthesis, Characterization, and the Gradual Transition of Coordination Mode from σ Toward π Originated by Crystal Packing Interactions |
| Authors of publication | Aharonovich, Sinai; Kapon, Moshe; Botoshanski, Mark; Eisen, Moris S. |
| Journal of publication | Organometallics |
| Year of publication | 2008 |
| Journal volume | 27 |
| Journal issue | 8 |
| Pages of publication | 1869 |
| a | 10.708 ± 0.002 Å |
| b | 19.073 ± 0.004 Å |
| c | 13.227 ± 0.003 Å |
| α | 90° |
| β | 96.24 ± 0.02° |
| γ | 90° |
| Cell volume | 2685.4 ± 1 Å3 |
| Cell temperature | 230 ± 1 K |
| Ambient diffraction temperature | 230 ± 1 K |
| Number of distinct elements | 6 |
| Space group number | 14 |
| Hermann-Mauguin space group symbol | P 1 21/n 1 |
| Hall space group symbol | -P 2yn |
| Residual factor for all reflections | 0.0936 |
| Residual factor for significantly intense reflections | 0.0481 |
| Weighted residual factors for significantly intense reflections | 0.1253 |
| Weighted residual factors for all reflections included in the refinement | 0.1351 |
| Goodness-of-fit parameter for all reflections included in the refinement | 0.916 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 178599 (current) | 2016-03-21 | cif/4/07/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/07/10. |
4071032.cif |
| 120075 | 2014-07-11 | Adding DOIs to range 4/07 structures. | 4071032.cif |
| 47256 | 2012-03-23 | cif/4/ Distributing the new range 4 CIFs into their appropriate prefixed subdirectories. |
4071032.cif |
| 43001 | 2012-03-13 | ../uploads/cif-deposit/cod/cif Adding structures of 4071028, 4071029, 4071030, 4071031, 4071032, 4071033, 4071034, 4071035, 4071036, 4071037 via cif-deposit CGI script. |
4071032.cif |
All data in the COD and the database itself are dedicated to the
public domain and licensed under the
CC0
License
.
Users of the data should acknowledge the original authors of the
structural data.