Crystallography Open Database

Information card for entry 4071406

Preview

Coordinates	4071406.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C41 H51 P Rh Si4
Calculated formula	C41 H51 P Rh Si4
Title of publication	“Synergistic Effects of Two Si−H Groups and a Metal Center” in Transition Metal-Catalyzed Hydrosilylation of Unsaturated Molecules: A Mechanistic Study of the RhCl(PPh3)3-Catalyzed Hydrosilylation of Ketones with 1,2-Bis(dimethylsilyl)benzene
Authors of publication	Sunada, Yusuke; Fujimura, Yoshiki; Nagashima, Hideo
Journal of publication	Organometallics
Year of publication	2008
Journal volume	27
Journal issue	14
Pages of publication	3502
a	9.5341 ± 0.0013 Å
b	38.073 ± 0.004 Å
c	12.292 ± 0.0015 Å
α	90°
β	110.462 ± 0.005°
γ	90°
Cell volume	4180.4 ± 0.9 Å³
Cell temperature	153.1 K
Number of distinct elements	5
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/c 1
Hall space group symbol	-P 2ybc
Residual factor for significantly intense reflections	0.0788
Weighted residual factors for all reflections included in the refinement	0.222
Goodness-of-fit parameter for all reflections included in the refinement	1.001
Diffraction radiation wavelength	0.7107 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
176467 (current)	2016-02-16	cif/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in range 4.	4071406.cif
120075	2014-07-11	Adding DOIs to range 4/07 structures.	4071406.cif
47256	2012-03-23	cif/4/ Distributing the new range 4 CIFs into their appropriate prefixed subdirectories.	4071406.cif
43818	2012-03-15	../uploads/cif-deposit/cod/cif Adding structures of 4071406 via cif-deposit CGI script.	4071406.cif