Crystallography Open Database

Information card for entry 4071541

Preview

Coordinates	4071541.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C28 H46 Cl2 N P2 Rh Si
Calculated formula	C28 H46 Cl2 N P2 Rh Si
Title of publication	Oxidative Addition Reactions of Silyl Halides with the (PNP)Rh Fragment
Authors of publication	Gatard, Sylvain; Chen, Chun-Hsing; Foxman, Bruce M.; Ozerov, Oleg V.
Journal of publication	Organometallics
Year of publication	2008
Journal volume	27
Journal issue	23
Pages of publication	6257
a	14.0161 ± 0.0008 Å
b	13.1551 ± 0.0007 Å
c	17.3099 ± 0.001 Å
α	90°
β	100.205 ± 0.003°
γ	90°
Cell volume	3141.2 ± 0.3 Å³
Cell temperature	120 K
Ambient diffraction temperature	120 K
Number of distinct elements	7
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/n 1
Hall space group symbol	-P 2yn
Residual factor for all reflections	0.0551
Residual factor for significantly intense reflections	0.0375
Weighted residual factors for all reflections	0.112
Weighted residual factors for significantly intense reflections	0.0929
Weighted residual factors for all reflections included in the refinement	0.112
Goodness-of-fit parameter for all reflections included in the refinement	0.9152
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
176467 (current)	2016-02-16	cif/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in range 4.	4071541.cif
91935	2013-12-29	cod/ (saulius@koala.ibt.lt) Adding DOIs that could be assigned unambiguously to the rest of COD CIFs.	4071541.cif
47256	2012-03-23	cif/4/ Distributing the new range 4 CIFs into their appropriate prefixed subdirectories.	4071541.cif
43904	2012-03-15	../uploads/cif-deposit/cod/cif Adding structures of 4071541 via cif-deposit CGI script.	4071541.cif