Crystallography Open Database

Information card for entry 4071853

Preview

Coordinates	4071853.cif
Original paper (by DOI)	HTML

Structure parameters

Common name	13
Formula	C25 H30 N4 O2 Si
Calculated formula	C25 H29.5 N4 O2 Si
Title of publication	Hydride Migration from Silicon to an Adjacent Unsaturated Imino Carbon: Intramolecular Hydrosilylation
Authors of publication	Kertsnus-Banchik, Evgenia; Kalikhman, Inna; Gostevskii, Boris; Deutsch, Zvicka; Botoshansky, Mark; Kost, Daniel
Journal of publication	Organometallics
Year of publication	2008
Journal volume	27
Journal issue	20
Pages of publication	5285
a	14.293 ± 0.002 Å
b	10.3528 ± 0.0016 Å
c	15.528 ± 0.003 Å
α	90°
β	99.007 ± 0.003°
γ	90°
Cell volume	2269.4 ± 0.6 Å³
Cell temperature	273 ± 2 K
Ambient diffraction temperature	273 ± 2 K
Number of distinct elements	5
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/n 1
Hall space group symbol	-P 2yn
Residual factor for all reflections	0.0923
Residual factor for significantly intense reflections	0.0521
Weighted residual factors for significantly intense reflections	0.1243
Weighted residual factors for all reflections included in the refinement	0.1433
Goodness-of-fit parameter for all reflections included in the refinement	1.04
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
178607 (current)	2016-03-21	cif/4/07/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/07/18.	4071853.cif
91935	2013-12-29	cod/ (saulius@koala.ibt.lt) Adding DOIs that could be assigned unambiguously to the rest of COD CIFs.	4071853.cif
47256	2012-03-23	cif/4/ Distributing the new range 4 CIFs into their appropriate prefixed subdirectories.	4071853.cif
44079	2012-03-15	../uploads/cif-deposit/cod/cif Adding structures of 4071848, 4071849, 4071850, 4071851, 4071852, 4071853, 4071854 via cif-deposit CGI script.	4071853.cif