Crystallography Open Database

Information card for entry 4073822

Preview

Coordinates	4073822.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C23 H48 Cl N Os P2
Calculated formula	C23 H48 Cl N Os P2
SMILES	[Os]123(Cl)[P](C[C@@H](N(C=2)C)[C@H]3CC[P]1(C(C)(C)C)C(C)(C)C)(C(C)(C)C)C(C)(C)C
Title of publication	Chiral Hydride and Dihydrogen Pincer-Type Complexes of Osmium
Authors of publication	Kuznetsov, Vladimir F.; Gusev, Dmitry G.
Journal of publication	Organometallics
Year of publication	2007
Journal volume	26
Journal issue	23
Pages of publication	5661
a	14.7843 ± 0.0003 Å
b	12.3934 ± 0.0003 Å
c	14.952 ± 0.0003 Å
α	90°
β	98.7963 ± 0.0013°
γ	90°
Cell volume	2707.4 ± 0.1 Å³
Cell temperature	150 ± 1 K
Ambient diffraction temperature	150 ± 1 K
Number of distinct elements	6
Space group number	4
Hermann-Mauguin space group symbol	P 1 21 1
Hall space group symbol	P 2yb
Residual factor for all reflections	0.0554
Residual factor for significantly intense reflections	0.0406
Weighted residual factors for significantly intense reflections	0.0835
Weighted residual factors for all reflections included in the refinement	0.0909
Goodness-of-fit parameter for all reflections included in the refinement	1.03
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
178627 (current)	2016-03-21	cif/4/07/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/07/38.	4073822.cif
120075	2014-07-11	Adding DOIs to range 4/07 structures.	4073822.cif
47256	2012-03-23	cif/4/ Distributing the new range 4 CIFs into their appropriate prefixed subdirectories.	4073822.cif
46562	2012-03-21	../uploads/cif-deposit/cod/cif Adding structures of 4073822 via cif-deposit CGI script.	4073822.cif