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Information card for entry 4074799
Preview
| Coordinates | 4074799.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C43 H97 N8 O2 Si4 Sm2 |
|---|---|
| Calculated formula | C40 H90 N8 O2 Si4 Sm2 |
| SMILES | N([Si](C)(C)C)([Si](C)(C)C)[Sm]12([O](C)[Sm]3(=C4N(C=CN4CCN3C(C)(C)C)C(C)(C)C)(N([Si](C)(C)C)[Si](C)(C)C)[O]2C)=C2N(C=CN2CCN1C(C)(C)C)C(C)(C)C |
| Title of publication | Deprotonation of N-Heterocyclic Carbenes to Afford Heterobimetallic Organolanthanide Complexes |
| Authors of publication | Arnold, Polly L.; Liddle, Stephen T. |
| Journal of publication | Organometallics |
| Year of publication | 2006 |
| Journal volume | 25 |
| Journal issue | 6 |
| Pages of publication | 1485 - 1491 |
| a | 26.899 ± 0.007 Å |
| b | 11.136 ± 0.003 Å |
| c | 21.979 ± 0.006 Å |
| α | 90° |
| β | 112.692 ± 0.004° |
| γ | 90° |
| Cell volume | 6074 ± 3 Å3 |
| Cell temperature | 150 ± 2 K |
| Ambient diffraction temperature | 150 ± 2 K |
| Number of distinct elements | 6 |
| Space group number | 15 |
| Hermann-Mauguin space group symbol | C 1 2/c 1 |
| Hall space group symbol | -C 2yc |
| Residual factor for all reflections | 0.0536 |
| Residual factor for significantly intense reflections | 0.0298 |
| Weighted residual factors for significantly intense reflections | 0.068 |
| Weighted residual factors for all reflections included in the refinement | 0.0739 |
| Goodness-of-fit parameter for all reflections included in the refinement | 0.948 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 209805 (current) | 2018-08-16 | cif/4/ Updating bibliography in entries 4060868-4060870, 4074797-4074799. Marking entries 4060868-4060870 as duplicates of entries 4074797-4074799. |
4074799.cif |
| 178636 | 2016-03-21 | cif/4/07/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/07/47. |
4074799.cif |
| 120075 | 2014-07-11 | Adding DOIs to range 4/07 structures. | 4074799.cif |
| 48830 | 2012-03-27 | ../uploads/cif-deposit/cod/cif Adding structures of 4074797, 4074798, 4074799 via cif-deposit CGI script. |
4074799.cif |
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