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Information card for entry 4074907
Preview
| Coordinates | 4074907.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C93 H177 Cl6 Hf2 N4 O2 Si12 |
|---|---|
| Calculated formula | C93 H177 Cl6 Hf2 N4 O2 Si12 |
| Title of publication | Reduction of Tetravalent Group 4 Metal Complexes Supported by an Extremely Bulky, Unsymmetrically Substituted β-Diketiminato Ligand Leading to the Regioselective CN Bond Cleavage Giving Ring-Contracted Metal-Imido Complexes |
| Authors of publication | Hamaki, Hirofumi; Takeda, Nobuhiro; Tokitoh, Norihiro |
| Journal of publication | Organometallics |
| Year of publication | 2006 |
| Journal volume | 25 |
| Journal issue | 10 |
| Pages of publication | 2457 |
| a | 11.6597 ± 0.0001 Å |
| b | 18.3005 ± 0.0002 Å |
| c | 28.9162 ± 0.0003 Å |
| α | 74.6796 ± 0.0008° |
| β | 82.5888 ± 0.0004° |
| γ | 77.1249 ± 0.0005° |
| Cell volume | 5785.06 ± 0.1 Å3 |
| Cell temperature | 103 ± 2 K |
| Ambient diffraction temperature | 103 ± 2 K |
| Number of distinct elements | 7 |
| Space group number | 2 |
| Hermann-Mauguin space group symbol | P -1 |
| Hall space group symbol | -P 1 |
| Residual factor for all reflections | 0.0242 |
| Residual factor for significantly intense reflections | 0.0204 |
| Weighted residual factors for significantly intense reflections | 0.0464 |
| Weighted residual factors for all reflections included in the refinement | 0.0477 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.069 |
| Diffraction radiation wavelength | 0.71069 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 178638 (current) | 2016-03-21 | cif/4/07/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/07/49. |
4074907.cif |
| 120075 | 2014-07-11 | Adding DOIs to range 4/07 structures. | 4074907.cif |
| 48953 | 2012-03-27 | ../uploads/cif-deposit/cod/cif Adding structures of 4074906, 4074907, 4074908, 4074909, 4074910, 4074911, 4074912 via cif-deposit CGI script. |
4074907.cif |
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Users of the data should acknowledge the original authors of the
structural data.