Crystallography Open Database

Information card for entry 4079341

Preview

Coordinates	4079341.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C30 H36 Au Cl P2 Si2
Calculated formula	C30 H36 Au Cl P2 Si2
SMILES	[Au]1(Cl)[P](C[Si]([Si](C)(C)C[P]1(c1ccccc1)c1ccccc1)(C)C)(c1ccccc1)c1ccccc1
Title of publication	Gold-Mediated Insertion of Oxygen into Silicon‒Silicon Bond: An Original Au(I)/Au(III) Redox Sequence
Authors of publication	Gualco, Pauline; Ladeira, Sonia; Miqueu, Karinne; Amgoune, Abderrahmane; Bourissou, Didier
Journal of publication	Organometallics
Year of publication	2012
Journal volume	31
Journal issue	17
Pages of publication	6001
a	10.5602 ± 0.0002 Å
b	16.2529 ± 0.0003 Å
c	36.3419 ± 0.0007 Å
α	90°
β	90°
γ	90°
Cell volume	6237.5 ± 0.2 Å³
Cell temperature	193 ± 2 K
Ambient diffraction temperature	193 ± 2 K
Number of distinct elements	6
Space group number	19
Hermann-Mauguin space group symbol	P 21 21 21
Hall space group symbol	P 2ac 2ab
Residual factor for all reflections	0.0618
Residual factor for significantly intense reflections	0.0408
Weighted residual factors for significantly intense reflections	0.0676
Weighted residual factors for all reflections included in the refinement	0.0734
Goodness-of-fit parameter for all reflections included in the refinement	1.025
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
178682 (current)	2016-03-21	cif/4/07/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/07/93.	4079341.cif
91935	2013-12-29	cod/ (saulius@koala.ibt.lt) Adding DOIs that could be assigned unambiguously to the rest of COD CIFs.	4079341.cif
72405	2013-01-21	cif/ Adding structures of 4079340, 4079341 via cif-deposit CGI script.	4079341.cif