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Information card for entry 4084050
Preview
| Coordinates | 4084050.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C62 H109 Cl3 N2 P4 Ru2 |
|---|---|
| Calculated formula | C62 H108 Cl3 N2 P4 Ru2 |
| SMILES | [Ru]123([Cl][Ru]4([Cl]1)([Cl]2)[P](C1CCCCC1)(C1CCCCC1)CCCC[P]4(C1CCCCC1)C1CCCCC1)([N]#N)[P](C1CCCCC1)(C1CCCCC1)CCCC[P]3(C1CCCCC1)C1CCCCC1.c1ccccc1 |
| Title of publication | A Stable Silylene in a Reactive Environment: Synthesis, Reactivity, and Silicon Extrusion Chemistry of a Coordinatively Unsaturated Ruthenium Silylene Complex Containing Chloride and η3-P‒C‒P Ligands |
| Authors of publication | Amoroso, Dino; Haaf, Michael; Yap, Glenn P. A.; West, Robert; Fogg, Deryn E. |
| Journal of publication | Organometallics |
| Year of publication | 2002 |
| Journal volume | 21 |
| Journal issue | 3 |
| Pages of publication | 534 - 540 |
| a | 11.622 ± 0.0009 Å |
| b | 13.5699 ± 0.001 Å |
| c | 22.7781 ± 0.0017 Å |
| α | 89.723 ± 0.001° |
| β | 86.837 ± 0.001° |
| γ | 66.508 ± 0.001° |
| Cell volume | 3289 ± 0.4 Å3 |
| Cell temperature | 203 ± 2 K |
| Ambient diffraction temperature | 203 ± 2 K |
| Number of distinct elements | 6 |
| Space group number | 2 |
| Hermann-Mauguin space group symbol | P -1 |
| Hall space group symbol | -P 1 |
| Residual factor for all reflections | 0.0971 |
| Residual factor for significantly intense reflections | 0.0487 |
| Weighted residual factors for significantly intense reflections | 0.0964 |
| Weighted residual factors for all reflections included in the refinement | 0.1059 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.028 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 219035 (current) | 2019-10-02 | cif/4/08/40/ Updated bibliographic information in entries 4084049-4084051. |
4084050.cif |
| 178729 | 2016-03-21 | cif/4/08/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/08/40. |
4084050.cif |
| 120646 | 2014-07-22 | cif/ Adding structures of 4084049, 4084050, 4084051 via cif-deposit CGI script. |
4084050.cif |
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Users of the data should acknowledge the original authors of the
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