Crystallography Open Database

Information card for entry 4084843

Preview

Coordinates	4084843.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C39 H45 Cl2 F6 N O3 P Ru Sb
Calculated formula	C39 H45 Cl2 F6 N O3 P Ru Sb
Title of publication	Reactivity of the Chiral Metallic Brønsted Acid [(η6-p-MeC6H4iPr)Ru(κ3P,O,O′-POH)][SbF6]2(POH= (SC1,RC2)-Ph2PC(Ph)HC(OH)HCH2OMe) toward Aldimines
Authors of publication	Pardo, Pilar; Carmona, Daniel; Lamata, Pilar; Rodr\?íguez, Ricardo; Lahoz, Fernando J.; Garc\?ía-Orduña, Pilar; Oro, Luis A.
Journal of publication	Organometallics
Year of publication	2014
Journal volume	33
Journal issue	23
Pages of publication	6927
a	10.2729 ± 0.0005 Å
b	16.6169 ± 0.0008 Å
c	25.1147 ± 0.0012 Å
α	90°
β	99.749 ± 0.005°
γ	90°
Cell volume	4225.3 ± 0.4 Å³
Cell temperature	100 ± 2 K
Ambient diffraction temperature	100 ± 2 K
Number of distinct elements	9
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/c 1
Hall space group symbol	-P 2ybc
Residual factor for all reflections	0.0445
Residual factor for significantly intense reflections	0.0417
Weighted residual factors for significantly intense reflections	0.1012
Weighted residual factors for all reflections included in the refinement	0.1033
Goodness-of-fit parameter for all reflections included in the refinement	1.036
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
178737 (current)	2016-03-21	cif/4/08/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/08/48.	4084843.cif
131496	2015-02-08	cif/ Updating files of 4084843, 4084844 Original log message: Adding full bibliography for 4084843--4084844.cif.	4084843.cif
127758	2014-11-21	cif/ Adding structures of 4084843, 4084844 via cif-deposit CGI script.	4084843.cif