Crystallography Open Database

Information card for entry 4086152

Preview

Coordinates	4086152.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C104 H140 Ge2 N2 Si2
Calculated formula	C104 H140 Ge2 N2 Si2
Title of publication	Reactivity of Amido-Digermynes, LGeGeL (L = Bulky Amide), toward Olefins and Related Molecules: Facile Reduction, C‒H Activation, and Reversible Cycloaddition of Unsaturated Substrates
Authors of publication	Hadlington, Terrance J.; Li, Jiaye; Hermann, Markus; Davey, Amelia; Frenking, Gernot; Jones, Cameron
Journal of publication	Organometallics
Year of publication	2015
Journal volume	34
Journal issue	13
Pages of publication	3175
a	15.3301 ± 0.0004 Å
b	17.3683 ± 0.0006 Å
c	20.0894 ± 0.0005 Å
α	70.038 ± 0.003°
β	72.704 ± 0.002°
γ	70.153 ± 0.003°
Cell volume	4628.3 ± 0.3 Å³
Cell temperature	123 ± 2 K
Ambient diffraction temperature	123 ± 2 K
Number of distinct elements	5
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.1001
Residual factor for significantly intense reflections	0.0894
Weighted residual factors for significantly intense reflections	0.2506
Weighted residual factors for all reflections included in the refinement	0.2599
Goodness-of-fit parameter for all reflections included in the refinement	1.091
Diffraction radiation wavelength	1.54184 Å
Diffraction radiation type	CuKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
176428 (current)	2016-02-13	Replaced deprecated COD CIF data names with their more modern alternatives. The _cod_cif_authors_sg_Hall and _cod_cif_authors_sg_H-M data items were renamed to _cod_original_sg_symbol_Hall and _cod_cif_authors_sg_H-M respectively.	4086152.cif
152773	2015-08-05	cif/ Adding structures of 4086152, 4086153, 4086154, 4086155, 4086156, 4086157, 4086158, 4086159, 4086160 via cif-deposit CGI script.	4086152.cif