Crystallography Open Database

Information card for entry 4086155

Preview

Coordinates	4086155.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C99 H123 Ge2 N2 Si2
Calculated formula	C99 H123 Ge2 N2 Si2
Title of publication	Reactivity of Amido-Digermynes, LGeGeL (L = Bulky Amide), toward Olefins and Related Molecules: Facile Reduction, C‒H Activation, and Reversible Cycloaddition of Unsaturated Substrates
Authors of publication	Hadlington, Terrance J.; Li, Jiaye; Hermann, Markus; Davey, Amelia; Frenking, Gernot; Jones, Cameron
Journal of publication	Organometallics
Year of publication	2015
Journal volume	34
Journal issue	13
Pages of publication	3175
a	22.463 ± 0.005 Å
b	17.179 ± 0.003 Å
c	22.202 ± 0.004 Å
α	90°
β	99.62 ± 0.03°
γ	90°
Cell volume	8447 ± 3 Å³
Cell temperature	123 ± 2 K
Ambient diffraction temperature	123 ± 2 K
Number of distinct elements	5
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/c 1
Hall space group symbol	-P 2ybc
Residual factor for all reflections	0.2362
Residual factor for significantly intense reflections	0.0905
Weighted residual factors for significantly intense reflections	0.1967
Weighted residual factors for all reflections included in the refinement	0.2545
Goodness-of-fit parameter for all reflections included in the refinement	1.004
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
176428 (current)	2016-02-13	Replaced deprecated COD CIF data names with their more modern alternatives. The _cod_cif_authors_sg_Hall and _cod_cif_authors_sg_H-M data items were renamed to _cod_original_sg_symbol_Hall and _cod_cif_authors_sg_H-M respectively.	4086155.cif
152773	2015-08-05	cif/ Adding structures of 4086152, 4086153, 4086154, 4086155, 4086156, 4086157, 4086158, 4086159, 4086160 via cif-deposit CGI script.	4086155.cif