Crystallography Open Database

Information card for entry 4087937

Preview

Coordinates	4087937.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C49 H90 Cu2 I2 N6 Si6
Calculated formula	C49 H90 Cu2 I2 N6 Si6
SMILES	C1(c2ccccc2)=[N](C(C)(C)C)[Si](N1C(C)(C)C)(N([Si](C)(C)C)[Si](C)(C)C)[Cu]1[I][Cu]([I]1)[Si]1([N](C(C)(C)C)=C(c2ccccc2)N1C(C)(C)C)N([Si](C)(C)C)[Si](C)(C)C.c1(ccccc1)C
Title of publication	Silicon(II) Bis(trimethylsilyl)amide (LSiN(SiMe3)2, L = PhC(NtBu)2) Supported Copper, Silver, and Gold Complexes
Authors of publication	Khan, Shabana; Ahirwar, Saurabh K.; Pal, Shiv; Parvin, Nasrina; Kathewad, Neha
Journal of publication	Organometallics
Year of publication	2015
Journal volume	34
Journal issue	22
Pages of publication	5401
a	34.742 ± 0.005 Å
b	11.2775 ± 0.0015 Å
c	31.977 ± 0.003 Å
α	90°
β	90.37 ± 0.006°
γ	90°
Cell volume	12528 ± 3 Å³
Cell temperature	200 ± 2 K
Ambient diffraction temperature	200 ± 2 K
Number of distinct elements	6
Space group number	15
Hermann-Mauguin space group symbol	C 1 2/c 1
Hall space group symbol	-C 2yc
Residual factor for all reflections	0.1186
Residual factor for significantly intense reflections	0.0911
Weighted residual factors for significantly intense reflections	0.1826
Weighted residual factors for all reflections included in the refinement	0.1963
Goodness-of-fit parameter for all reflections included in the refinement	1.159
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
237139 (current)	2019-11-24	cif/ Adding structures of 4087937 via cif-deposit CGI script.	4087937.cif