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Information card for entry 4088452
Preview
| Coordinates | 4088452.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Chemical name | bis(dimethylphosphinomethane)iron dinitrogen dimer |
|---|---|
| Formula | C24.566 H61.633 Fe2 N2 P8 |
| Calculated formula | C24.566 H61.632 Fe2 N2 P8 |
| Title of publication | A Tertiary Carbon‒Iron Bond as an FeICl Synthon and the Reductive Alkylation of Diphosphine-Supported Iron(II) Chloride Complexes to Low-Valent Iron |
| Authors of publication | Tondreau, Aaron M.; Scott, Brian L.; Boncella, James M. |
| Journal of publication | Organometallics |
| Year of publication | 2016 |
| Journal volume | 35 |
| Journal issue | 11 |
| Pages of publication | 1643 |
| a | 9.2918 ± 0.0013 Å |
| b | 9.614 ± 0.0013 Å |
| c | 23.399 ± 0.003 Å |
| α | 90.684 ± 0.002° |
| β | 90.764 ± 0.003° |
| γ | 115.56 ± 0.002° |
| Cell volume | 1885.2 ± 0.4 Å3 |
| Cell temperature | 105 K |
| Ambient diffraction temperature | 105.29 K |
| Number of distinct elements | 5 |
| Space group number | 2 |
| Hermann-Mauguin space group symbol | P -1 |
| Hall space group symbol | -P 1 |
| Residual factor for all reflections | 0.1052 |
| Residual factor for significantly intense reflections | 0.0996 |
| Weighted residual factors for significantly intense reflections | 0.2696 |
| Weighted residual factors for all reflections included in the refinement | 0.2798 |
| Goodness-of-fit parameter for all reflections included in the refinement | 0.9984 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | Yes |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 237585 (current) | 2019-11-24 | cif/ Adding structures of 4088449, 4088450, 4088451, 4088452, 4088453, 4088454, 4088455, 4088456 via cif-deposit CGI script. |
4088452.cif |
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Users of the data should acknowledge the original authors of the
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