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Information card for entry 4088531
Preview
| Coordinates | 4088531.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C44 H51 K O6 Si |
|---|---|
| Calculated formula | C44 H51 K O6 Si |
| Title of publication | Potassium-Catalyzed Hydrosilylation of Activated Olefins: Evidence for a Silyl Migration Mechanism |
| Authors of publication | Leich, Valeri; Spaniol, Thomas P.; Okuda, Jun |
| Journal of publication | Organometallics |
| Year of publication | 2016 |
| Journal volume | 35 |
| Journal issue | 9 |
| Pages of publication | 1179 |
| a | 9.3694 ± 0.0007 Å |
| b | 24.0129 ± 0.0017 Å |
| c | 19.4552 ± 0.0012 Å |
| α | 90° |
| β | 116.927 ± 0.003° |
| γ | 90° |
| Cell volume | 3902.6 ± 0.5 Å3 |
| Cell temperature | 100 ± 2 K |
| Ambient diffraction temperature | 100 ± 2 K |
| Number of distinct elements | 5 |
| Space group number | 14 |
| Hermann-Mauguin space group symbol | P 1 21/c 1 |
| Hall space group symbol | -P 2ybc |
| Residual factor for all reflections | 0.0592 |
| Residual factor for significantly intense reflections | 0.0393 |
| Weighted residual factors for significantly intense reflections | 0.0775 |
| Weighted residual factors for all reflections included in the refinement | 0.084 |
| Goodness-of-fit parameter for all reflections included in the refinement | 0.907 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 237645 (current) | 2019-11-24 | cif/ Adding structures of 4088531 via cif-deposit CGI script. |
4088531.cif |
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Users of the data should acknowledge the original authors of the
structural data.