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Information card for entry 4088599
Preview
| Coordinates | 4088599.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C68 H108 Cl2 Li2 N6 O6 Si4 Yb2 |
|---|---|
| Calculated formula | C68 H108 Cl2 Li2 N6 O6 Si4 Yb2 |
| SMILES | c1c2c3c(cccc3)[n]1([Li]1([O]3CCCC3)[O]3CCCC3)[Yb]3(N(c4ccccc4C)[C@@H](C[Si](N3[Si](C)(C)C)(C)C)c3c[n](c4c3cccc4)([Li]3([O]4CCCC4)[O]4CCCC4)[Yb]4(N([C@H]2C[Si](N4[Si](C)(C)C)(C)C)c2ccccc2C)([O]2CCCC2)[Cl]3)([O]2CCCC2)[Cl]1.c1c2c3c(cccc3)[n]1([Li]1([O]3CCCC3)[O]3CCCC3)[Yb]3(N(c4ccccc4C)[C@H](C[Si](N3[Si](C)(C)C)(C)C)c3c[n](c4c3cccc4)([Li]3([O]4CCCC4)[O]4CCCC4)[Yb]4(N([C@@H]2C[Si](N4[Si](C)(C)C)(C)C)c2ccccc2C)([O]2CCCC2)[Cl]3)([O]2CCCC2)[Cl]1 |
| Title of publication | Reactivity of 3-Imino-Functionalized Indoles with Rare-Earth-Metal Amides: Unexpected Substituent Effects on C‒H Activation Pathways and Assembly of Rare-Earth-Metal Complexes |
| Authors of publication | Zhu, Xiancui; Li, Yang; Wei, Yun; Wang, Shaowu; Zhou, Shuangliu; Zhang, Lijun |
| Journal of publication | Organometallics |
| Year of publication | 2016 |
| Journal volume | 35 |
| Journal issue | 11 |
| Pages of publication | 1838 |
| a | 18.1701 ± 0.0009 Å |
| b | 18.4035 ± 0.0009 Å |
| c | 23.7815 ± 0.0012 Å |
| α | 90° |
| β | 90° |
| γ | 90° |
| Cell volume | 7952.4 ± 0.7 Å3 |
| Cell temperature | 293 ± 2 K |
| Ambient diffraction temperature | 293 ± 2 K |
| Number of distinct elements | 8 |
| Space group number | 56 |
| Hermann-Mauguin space group symbol | P c c n |
| Hall space group symbol | -P 2ab 2ac |
| Residual factor for all reflections | 0.0694 |
| Residual factor for significantly intense reflections | 0.0345 |
| Weighted residual factors for significantly intense reflections | 0.0701 |
| Weighted residual factors for all reflections included in the refinement | 0.0848 |
| Goodness-of-fit parameter for all reflections included in the refinement | 0.998 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 237694 (current) | 2019-11-24 | cif/ Adding structures of 4088593, 4088594, 4088595, 4088596, 4088597, 4088598, 4088599, 4088600, 4088601, 4088602, 4088603, 4088604 via cif-deposit CGI script. |
4088599.cif |
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Users of the data should acknowledge the original authors of the
structural data.