Crystallography Open Database

Information card for entry 4089131

Preview

Coordinates	4089131.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C24 H58 O Pt Si7
Calculated formula	C24 H58 O Pt Si7
SMILES	[CH2]1=[CH]2[Pt]31([CH2]=[CH]3[Si](C)(C)O[Si]2(C)C)=[Si]1C(CCC1([Si](C)(C)C)[Si](C)(C)C)([Si](C)(C)C)[Si](C)(C)C
Title of publication	A Dialkylsilylene-Pt(0) Complex with a DVTMS Ligand for the Catalytic Hydrosilylation of Functional Olefins
Authors of publication	Iimura, Tomohiro; Akasaka, Naohiko; Iwamoto, Takeaki
Journal of publication	Organometallics
Year of publication	2016
Journal volume	35
Journal issue	24
Pages of publication	4071
a	9.4996 ± 0.0019 Å
b	17.176 ± 0.003 Å
c	21.292 ± 0.004 Å
α	90°
β	90°
γ	90°
Cell volume	3474.1 ± 1.1 Å³
Cell temperature	100 ± 2 K
Ambient diffraction temperature	100 ± 2 K
Number of distinct elements	5
Space group number	19
Hermann-Mauguin space group symbol	P 21 21 21
Hall space group symbol	P 2ac 2ab
Residual factor for all reflections	0.0238
Residual factor for significantly intense reflections	0.0196
Weighted residual factors for significantly intense reflections	0.0394
Weighted residual factors for all reflections included in the refinement	0.0403
Goodness-of-fit parameter for all reflections included in the refinement	0.837
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
238003 (current)	2019-11-24	cif/ Adding structures of 4089131, 4089132 via cif-deposit CGI script.	4089131.cif