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Information card for entry 4089322
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| Coordinates | 4089322.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Common name | [Sn{C3H3O(C2H5)}{C(SiMe3)2SiMe2CH2CH2SiMe2C(SiMe3)2}] |
|---|---|
| Formula | C25 H60 O Si6 Sn |
| Calculated formula | C25 H60 O Si6 Sn |
| Title of publication | Reactions of a Highly Crowded Cyclic Stannylene with Iodoalkanes, Enones, and Dienes. Inhibition of Nucleophilic Substitution at Tin(IV) Centers |
| Authors of publication | Asadi, Ashrafolmolouk; Eaborn, Colin; Hill, Michael S.; Hitchcock, Peter B.; Meehan, Margaret M.; Smith, J. David |
| Journal of publication | Organometallics |
| Year of publication | 2002 |
| Journal volume | 21 |
| Journal issue | 12 |
| Pages of publication | 2430 |
| a | 12.42 ± 0.0004 Å |
| b | 13.7856 ± 0.0005 Å |
| c | 20.4785 ± 0.0005 Å |
| α | 90° |
| β | 90° |
| γ | 90° |
| Cell volume | 3506.27 ± 0.19 Å3 |
| Cell temperature | 173 ± 2 K |
| Ambient diffraction temperature | 173 ± 2 K |
| Number of distinct elements | 5 |
| Space group number | 62 |
| Hermann-Mauguin space group symbol | P n a m |
| Hall space group symbol | -P 2c 2n |
| Residual factor for all reflections | 0.0591 |
| Residual factor for significantly intense reflections | 0.0558 |
| Weighted residual factors for significantly intense reflections | 0.128 |
| Weighted residual factors for all reflections included in the refinement | 0.1296 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.26 |
| Diffraction radiation probe | x-ray |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | Yes |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 277856 (current) | 2022-09-15 | cif/ Added space group information derived from the space group operation list using the 'cif_filter' program. |
4089322.cif |
| 247257 | 2020-01-27 | cif/4/08/93/ Corrected a minor typo in the depositor comment in entry 4089322. |
4089322.cif |
| 247256 | 2020-01-27 | cif/4/08/93/ Corrected multiple issues in entry 4089322 that were introduced during the initial deposition process. Due to a CIF syntax error in the original file, several data blocks were incorrectly merged into a single data block. As a result, the deposited data block did not describe a real crystal structure. To correct this, multiple data items had to be replaced or removed altogether. |
4089322.cif |
| 243610 | 2019-11-26 | cif/ Adding structures of 4089321, 4089322 via cif-deposit CGI script. |
4089322.cif |
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Users of the data should acknowledge the original authors of the
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