Crystallography Open Database

Information card for entry 4089721

Preview

Coordinates	4089721.cif
Original paper (by DOI)	HTML

Structure parameters

Common name	[Sn(Et)(O2CCF3){C(SiMe3)2SiMe2CH2CH2SiMe2C(SiMe3)2}]
Formula	C24 H57 F3 O2 Si6 Sn
Calculated formula	C24 H53.88 F3 O2 Si6 Sn
Title of publication	Reactions of a Highly Crowded Cyclic Stannylene with Iodoalkanes, Enones, and Dienes. Inhibition of Nucleophilic Substitution at Tin(IV) Centers
Authors of publication	Asadi, Ashrafolmolouk; Eaborn, Colin; Hill, Michael S.; Hitchcock, Peter B.; Meehan, Margaret M.; Smith, J. David
Journal of publication	Organometallics
Year of publication	2002
Journal volume	21
Journal issue	12
Pages of publication	2430
a	34.0509 ± 0.0009 Å
b	9.3173 ± 0.0001 Å
c	22.2269 ± 0.0006 Å
α	90°
β	90°
γ	90°
Cell volume	7051.8 ± 0.3 Å³
Cell temperature	173 ± 2 K
Ambient diffraction temperature	173 ± 2 K
Number of distinct elements	6
Space group number	33
Hermann-Mauguin space group symbol	P n a 21
Hall space group symbol	P 2c -2n
Residual factor for all reflections	0.0523
Residual factor for significantly intense reflections	0.0408
Weighted residual factors for significantly intense reflections	0.0878
Weighted residual factors for all reflections included in the refinement	0.0932
Goodness-of-fit parameter for all reflections included in the refinement	1.017
Diffraction radiation probe	x-ray
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
247258 (current)	2020-01-27	cif/ Adding structures of 4089717, 4089718, 4089719, 4089720, 4089721 via cif-deposit CGI script.	4089721.cif