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Information card for entry 4102507
Preview
| Coordinates | 4102507.cif |
|---|---|
| Original paper (by DOI) | HTML |
| External links | PubChem |
| Common name | ToMZnN(SiHMe2)2 |
|---|---|
| Chemical name | tris(4,4-dimethyl-2-oxazolinyl)phenylborato tetramethyldisilazato zinc |
| Formula | C28.5 H47 B N4 O3 Si2 Zn |
| Calculated formula | C28.5 H47 B N4 O3 Si2 Zn |
| Title of publication | Conversion of a Zinc Disilazide to a Zinc Hydride Mediated by LiCl |
| Authors of publication | Debabrata Mukherjee; Arkady Ellern; Aaron D. Sadow |
| Journal of publication | Journal of the American Chemical Society |
| Year of publication | 2010 |
| Journal volume | 132 |
| Pages of publication | 7582 - 7583 |
| a | 9.9164 ± 0.0007 Å |
| b | 15.0927 ± 0.001 Å |
| c | 24.2345 ± 0.0016 Å |
| α | 97.893 ± 0.001° |
| β | 98.38 ± 0.001° |
| γ | 106.934 ± 0.001° |
| Cell volume | 3370.3 ± 0.4 Å3 |
| Cell temperature | 153 ± 2 K |
| Ambient diffraction temperature | 153 ± 2 K |
| Number of distinct elements | 7 |
| Space group number | 2 |
| Hermann-Mauguin space group symbol | P -1 |
| Hall space group symbol | -P 1 |
| Residual factor for all reflections | 0.0671 |
| Residual factor for significantly intense reflections | 0.0431 |
| Weighted residual factors for significantly intense reflections | 0.105 |
| Weighted residual factors for all reflections included in the refinement | 0.1161 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.021 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | Yes |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 301832 (current) | 2025-08-20 | Add cross-references to PubChem compounds in COD range 4/10/ Each referenced PubChem compound corresponds to the full crystal structure. |
4102507.cif |
| 176467 | 2016-02-16 | cif/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in range 4. |
4102507.cif |
| 120076 | 2014-07-11 | Adding DOIs to range 4/10 structures. | 4102507.cif |
| 34330 | 2012-02-24 | cif/4/ Reorganising CIF range 4 into a prefix tree. |
4102507.cif |
| 25388 | 2011-09-11 | ../uploads/cif-deposit/cod/cif Adding structures of 4102507 via cif-deposit CGI script. |
4102507.cif |
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Users of the data should acknowledge the original authors of the
structural data.