Crystallography Open Database

Information card for entry 4103142

Preview

Coordinates	4103142.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C33 H55 B F4 N5 O P2 Rh
Calculated formula	C33 H55 B F4 N5 O P2 Rh
Title of publication	Intramolecular Hydroamination of Unbiased and Functionalized Primary Aminoalkenes Catalyzed by a Rhodium Aminophosphine Complex
Authors of publication	Lisa D. Julian; John F. Hartwig
Journal of publication	Journal of the American Chemical Society
Year of publication	2010
Journal volume	132
Pages of publication	13813 - 13822
a	19.3079 ± 0.0012 Å
b	16.9887 ± 0.0011 Å
c	24.5185 ± 0.0017 Å
α	90°
β	104.227 ± 0.005°
γ	90°
Cell volume	7795.8 ± 0.9 Å³
Cell temperature	193 ± 2 K
Ambient diffraction temperature	193 ± 2 K
Number of distinct elements	8
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/c 1
Hall space group symbol	-P 2ybc
Residual factor for all reflections	0.2036
Residual factor for significantly intense reflections	0.0762
Weighted residual factors for significantly intense reflections	0.1877
Weighted residual factors for all reflections included in the refinement	0.2532
Goodness-of-fit parameter for all reflections included in the refinement	0.989
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
176432 (current)	2016-02-14	cif/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries.	4103142.cif
120076	2014-07-11	Adding DOIs to range 4/10 structures.	4103142.cif
34330	2012-02-24	cif/4/ Reorganising CIF range 4 into a prefix tree.	4103142.cif
26097	2011-09-19	../uploads/cif-deposit/cod/cif Adding structures of 4103142 via cif-deposit CGI script.	4103142.cif