Crystallography Open Database

Information card for entry 4104457

Preview

Coordinates	4104457.cif
Original paper (by DOI)	HTML

Structure parameters

Common name	HLSi(OH)-Ni(CO)3
Formula	C32 H42 N2 Ni O4 Si
Calculated formula	C32 H42 N2 Ni O4 Si
Title of publication	Diketiminate Silicon(II) and Related NHSi Ligands Generated in the Coordination Sphere of Nickel(0)
Authors of publication	Antje Meltzer; Carsten Präsang; Matthias Driess
Journal of publication	Journal of the American Chemical Society
Year of publication	2009
Journal volume	131
Pages of publication	7232 - 7233
a	8.8617 ± 0.0005 Å
b	20.047 ± 0.0008 Å
c	9.7565 ± 0.0004 Å
α	90°
β	112.839 ± 0.006°
γ	90°
Cell volume	1597.36 ± 0.15 Å³
Cell temperature	150 ± 2 K
Ambient diffraction temperature	150 ± 2 K
Number of distinct elements	6
Space group number	11
Hermann-Mauguin space group symbol	P 1 21/m 1
Hall space group symbol	-P 2yb
Residual factor for all reflections	0.0803
Residual factor for significantly intense reflections	0.0425
Weighted residual factors for significantly intense reflections	0.0895
Weighted residual factors for all reflections included in the refinement	0.0971
Goodness-of-fit parameter for all reflections included in the refinement	0.899
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
178790 (current)	2016-03-21	cif/4/10/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/10/44.	4104457.cif
120076	2014-07-11	Adding DOIs to range 4/10 structures.	4104457.cif
34330	2012-02-24	cif/4/ Reorganising CIF range 4 into a prefix tree.	4104457.cif
29481	2011-11-03	../uploads/cif-deposit/cod/cif Adding structures of 4104457 via cif-deposit CGI script.	4104457.cif