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Information card for entry 4104462
Preview
| Coordinates | 4104462.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C29 H37 I N4 Pt2 Si |
|---|---|
| Calculated formula | C29 H37 I N4 Pt2 Si |
| SMILES | [Pt]1([Pt]2(I)([n]3ccccc3c3[n]2cccc3)(C)C)([n]2ccccc2c2[n]1cccc2)(C#C[Si](C)(C)C)(C)C |
| Title of publication | Binuclear Intermediates in Oxidation Reactions: [(Me3SiC\τbC)Me2(bipy)Pt-PtMe2(bipy)]+ in the Oxidation of PtIIMe2(bipy) (bipy = 2,2'-Bipyridine) by IPh(C\τbCSiMe3)(OTf) (OTf = Triflate) |
| Authors of publication | Allan J. Canty; Michael G. Gardiner; Roderick C. Jones; Thomas Rodemann; Manab Sharma |
| Journal of publication | Journal of the American Chemical Society |
| Year of publication | 2009 |
| Journal volume | 131 |
| Pages of publication | 7236 - 7237 |
| a | 8.25 ± 0.0009 Å |
| b | 9.685 ± 0.0009 Å |
| c | 21.036 ± 0.0013 Å |
| α | 96.373 ± 0.005° |
| β | 98.346 ± 0.006° |
| γ | 101.48 ± 0.003° |
| Cell volume | 1612.7 ± 0.3 Å3 |
| Cell temperature | 100 ± 2 K |
| Ambient diffraction temperature | 100 ± 2 K |
| Number of distinct elements | 6 |
| Space group number | 2 |
| Hermann-Mauguin space group symbol | P -1 |
| Hall space group symbol | -P 1 |
| Residual factor for all reflections | 0.0301 |
| Residual factor for significantly intense reflections | 0.0296 |
| Weighted residual factors for significantly intense reflections | 0.0787 |
| Weighted residual factors for all reflections included in the refinement | 0.0791 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.065 |
| Diffraction radiation wavelength | 0.77487 Å |
| Diffraction radiation type | Synchrotron |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 178790 (current) | 2016-03-21 | cif/4/10/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/10/44. |
4104462.cif |
| 120076 | 2014-07-11 | Adding DOIs to range 4/10 structures. | 4104462.cif |
| 34330 | 2012-02-24 | cif/4/ Reorganising CIF range 4 into a prefix tree. |
4104462.cif |
| 29486 | 2011-11-03 | ../uploads/cif-deposit/cod/cif Adding structures of 4104462 via cif-deposit CGI script. |
4104462.cif |
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Users of the data should acknowledge the original authors of the
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