Crystallography Open Database

Information card for entry 4104972

Preview

Coordinates	4104972.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C61.8 H49.8 N2 P Rh Si
Calculated formula	C61.8 H49.8 N2 P Rh Si
Title of publication	High Oxidation State Rhodium and Iridium Bis(silyl)dihydride Complexes Supported by a Chelating Pyridyl-Pyrrolide Ligand
Authors of publication	Jennifer L. McBee; Jose Escalada; T. Don Tilley
Journal of publication	Journal of the American Chemical Society
Year of publication	2009
Journal volume	131
Pages of publication	12703 - 12713
a	35.521 ± 0.006 Å
b	12.568 ± 0.002 Å
c	25.217 ± 0.004 Å
α	90°
β	99.028 ± 0.002°
γ	90°
Cell volume	11118 ± 3 Å³
Cell temperature	149 ± 2 K
Ambient diffraction temperature	149 ± 2 K
Number of distinct elements	6
Space group number	15
Hermann-Mauguin space group symbol	C 1 2/c 1
Hall space group symbol	-C 2yc
Residual factor for all reflections	0.0844
Residual factor for significantly intense reflections	0.0778
Weighted residual factors for significantly intense reflections	0.2301
Weighted residual factors for all reflections included in the refinement	0.2413
Goodness-of-fit parameter for all reflections included in the refinement	1.152
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
176467 (current)	2016-02-16	cif/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in range 4.	4104972.cif
120076	2014-07-11	Adding DOIs to range 4/10 structures.	4104972.cif
34330	2012-02-24	cif/4/ Reorganising CIF range 4 into a prefix tree.	4104972.cif
30149	2011-11-09	../uploads/cif-deposit/cod/cif Adding structures of 4104972 via cif-deposit CGI script.	4104972.cif