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Information card for entry 4105608
Preview
| Coordinates | 4105608.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C33 H50 Cl2 F6 N4 P Rh |
|---|---|
| Calculated formula | C33 H50 Cl2 F6 N4 P Rh |
| Title of publication | Hydrosilylation with Biscarbene Rh(I) Complexes: Experimental Evidence for a Silylene-Based Mechanism |
| Authors of publication | Peter Gigler; Bettina Bechlars; Wolfgang A. Herrmann; Fritz E. Kühn |
| Journal of publication | Journal of the American Chemical Society |
| Year of publication | 2011 |
| Journal volume | 133 |
| Pages of publication | 1589 - 1596 |
| a | 11.6445 ± 0.0004 Å |
| b | 12.6184 ± 0.0004 Å |
| c | 12.7872 ± 0.0004 Å |
| α | 90° |
| β | 97.897 ± 0.002° |
| γ | 90° |
| Cell volume | 1861.07 ± 0.11 Å3 |
| Cell temperature | 173 ± 2 K |
| Ambient diffraction temperature | 173 ± 2 K |
| Number of distinct elements | 7 |
| Space group number | 4 |
| Hermann-Mauguin space group symbol | P 1 21 1 |
| Hall space group symbol | P 2yb |
| Residual factor for all reflections | 0.0336 |
| Residual factor for significantly intense reflections | 0.0295 |
| Weighted residual factors for significantly intense reflections | 0.0691 |
| Weighted residual factors for all reflections included in the refinement | 0.0731 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.092 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 178802 (current) | 2016-03-21 | cif/4/10/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/10/56. |
4105608.cif |
| 132410 | 2015-02-25 | cod/ (robertas@burundukas) Replaced zero-length value of the tag '_chemical_name_systematic' with '?'. codsql 'select file, chemname from data \ where length(chemname) = 0' -NB \ | perl -ne 'print $1."\n" if /\b(\d{7})\s*$/' \ | codid2file \ | xargs perl -0777 -i -pe 's/\b_chemical_name_systematic \K \s*? ( \n ; \s*? \n ; | '\'' \s* '\'' \s*? ) (?=\n) /" " x8 . "?"/ixmse' |
4105608.cif |
| 91935 | 2013-12-29 | cod/ (saulius@koala.ibt.lt) Adding DOIs that could be assigned unambiguously to the rest of COD CIFs. |
4105608.cif |
| 52367 | 2012-04-10 | ../uploads/cif-deposit/cod/cif Adding structures of 4105608 via cif-deposit CGI script. |
4105608.cif |
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