Crystallography Open Database

Information card for entry 4107738

Preview

Coordinates	4107738.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C26 H31 Cl N3 O1.5 Rh2
Calculated formula	C26 H30 Cl N3 O1.5 Rh2
Title of publication	Deprotonation Induced Ligand-to-Metal Electron Transfer: Synthesis of a Mixed-Valence Rh(-I,I) Dinuclear Compound and Its Reaction with Dioxygen
Authors of publication	Cristina Tejel; Miguel A. Ciriano; M. Pilar del Río; Fieke van den Bruele; Dennis G. H. Hetterscheid; Nearchos Tsichlis i Spithas; Bas de Bruin
Journal of publication	Journal of the American Chemical Society
Year of publication	2008
Journal volume	130
Pages of publication	5844 - 5845
a	8.8928 ± 0.0009 Å
b	11.4651 ± 0.0012 Å
c	13.0649 ± 0.0013 Å
α	68.666 ± 0.002°
β	80.702 ± 0.002°
γ	84.965 ± 0.002°
Cell volume	1223.9 ± 0.2 Å³
Cell temperature	100 ± 2 K
Ambient diffraction temperature	100 ± 2 K
Number of distinct elements	6
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.0719
Residual factor for significantly intense reflections	0.0432
Weighted residual factors for significantly intense reflections	0.0871
Weighted residual factors for all reflections included in the refinement	0.0967
Goodness-of-fit parameter for all reflections included in the refinement	1.034
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
176467 (current)	2016-02-16	cif/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in range 4.	4107738.cif
120076	2014-07-11	Adding DOIs to range 4/10 structures.	4107738.cif
55887	2012-05-07	cif/ Adding structures of 4107738 via cif-deposit CGI script.	4107738.cif