Crystallography Open Database

Information card for entry 4109237

Preview

Coordinates	4109237.cif
Original paper (by DOI)	HTML

Structure parameters

Common name	bis-phenyl dirhodium caprolactamate
Chemical name	Bis-phenyl di-rhodium(III) tetra-caprolactamate
Formula	C38 H54 Cl4 N4 O4 Rh2
Calculated formula	C38 H54 Cl4 N4 O4 Rh2
Title of publication	Bis(phenyl)dirhodium(III) Caprolactamate: A Dinuclear Paddlewheel Complex with No Metal-Metal Bond
Authors of publication	Jason M. Nichols; Joffrey Wolf; Peter Zavalij; Bindhu Varughese; Michael P. Doyle
Journal of publication	Journal of the American Chemical Society
Year of publication	2007
Journal volume	129
Pages of publication	3504 - 3505
a	10.977 ± 0.0003 Å
b	13.1258 ± 0.0004 Å
c	16.0022 ± 0.0005 Å
α	78.884 ± 0.001°
β	74.41 ± 0.001°
γ	73.186 ± 0.001°
Cell volume	2109.24 ± 0.11 Å³
Cell temperature	223 ± 2 K
Ambient diffraction temperature	223 ± 2 K
Number of distinct elements	6
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.0361
Residual factor for significantly intense reflections	0.03
Weighted residual factors for significantly intense reflections	0.0661
Weighted residual factors for all reflections included in the refinement	0.0687
Goodness-of-fit parameter for all reflections included in the refinement	1
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
178838 (current)	2016-03-21	cif/4/10/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/10/92.	4109237.cif
120076	2014-07-11	Adding DOIs to range 4/10 structures.	4109237.cif
57992	2012-05-23	cif/ Adding structures of 4109237 via cif-deposit CGI script.	4109237.cif