Crystallography Open Database

Information card for entry 4109241

Preview

Coordinates	4109241.cif
Original paper (by DOI)	HTML

Structure parameters

Common name	dirhodium caprolactamate acetonitrile
Chemical name	Di-rhodium tetra-caprolactamate tetra-acetonitrile
Formula	C32 H52 N8 O4 Rh2
Calculated formula	C32 H52 N8 O4 Rh2
Title of publication	Bis(phenyl)dirhodium(III) Caprolactamate: A Dinuclear Paddlewheel Complex with No Metal-Metal Bond
Authors of publication	Jason M. Nichols; Joffrey Wolf; Peter Zavalij; Bindhu Varughese; Michael P. Doyle
Journal of publication	Journal of the American Chemical Society
Year of publication	2007
Journal volume	129
Pages of publication	3504 - 3505
a	9.371 ± 0.0008 Å
b	15.8919 ± 0.0013 Å
c	23.994 ± 0.002 Å
α	90°
β	97.408 ± 0.002°
γ	90°
Cell volume	3543.4 ± 0.5 Å³
Number of distinct elements	5
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/c 1
Hall space group symbol	-P 2ybc
Suboptimal structure of	4109238
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
215354 (current)	2019-05-21	cif/ Removed the _cod_suboptimal_structure data item in preparation for its deprecation. The fact that the structure is a suboptimal one should be derived from the presence of the _cod_related_optimal_struct data item.	4109241.cif
212007	2018-11-16	cif/ Replacing the long forms of the _cod_related_optimal_structure data names with its shorter equivalent that are formally defined in the 'cif_cod' dictionary in entry 4109241.	4109241.cif
178838	2016-03-21	cif/4/10/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/10/92.	4109241.cif
120076	2014-07-11	Adding DOIs to range 4/10 structures.	4109241.cif
57996	2012-05-23	cif/ Adding structures of 4109241 via cif-deposit CGI script.	4109241.cif