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Information card for entry 4109583
Preview
| Coordinates | 4109583.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Chemical name | trans-1,2-Bis{bis[bis(trimethylsilyl)methyl]isopropylsilyl}- 3,4-dimethyl-1,2-disilacyclobutene |
|---|---|
| Formula | C38 H98 Si12 |
| Calculated formula | C38 H98 Si12 |
| Title of publication | Reactivity of a Disilyne RSi\τbSiR (R = SiiPr[CH(SiMe3)2]2) toward π-Bonds: Stereospecific Addition and a New Route to an Isolable 1,2-Disilabenzene |
| Authors of publication | Rei Kinjo; Masaaki Ichinohe; Akira Sekiguchi; Nozomi Takagi; Michinori Sumimoto; Shigeru Nagase |
| Journal of publication | Journal of the American Chemical Society |
| Year of publication | 2007 |
| Journal volume | 129 |
| Pages of publication | 7766 - 7767 |
| a | 11.879 ± 0.0003 Å |
| b | 16.205 ± 0.0006 Å |
| c | 29.367 ± 0.0009 Å |
| α | 90° |
| β | 90.886 ± 0.002° |
| γ | 90° |
| Cell volume | 5652.4 ± 0.3 Å3 |
| Cell temperature | 120 ± 0.1 K |
| Ambient diffraction temperature | 120 ± 0.1 K |
| Number of distinct elements | 3 |
| Space group number | 9 |
| Hermann-Mauguin space group symbol | C 1 c 1 |
| Hall space group symbol | C -2yc |
| Residual factor for all reflections | 0.0412 |
| Residual factor for significantly intense reflections | 0.0381 |
| Weighted residual factors for significantly intense reflections | 0.0965 |
| Weighted residual factors for all reflections included in the refinement | 0.0992 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.021 |
| Diffraction radiation wavelength | 0.7107 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 178841 (current) | 2016-03-21 | cif/4/10/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/10/95. |
4109583.cif |
| 120076 | 2014-07-11 | Adding DOIs to range 4/10 structures. | 4109583.cif |
| 58360 | 2012-05-28 | cif/ Adding structures of 4109583 via cif-deposit CGI script. |
4109583.cif |
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Users of the data should acknowledge the original authors of the
structural data.