Crystallography Open Database

Information card for entry 4110374

Preview

Coordinates	4110374.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C34 H61 Os P Si
Calculated formula	C34 H61 Os P Si
SMILES	[OsH]1234([P](C(C)C)(C(C)C)C(C)C)(=[SiH]c5c(C(C)C)cc(cc5C(C)C)C(C)C)[c]5([c]2([c]1([c]3([c]45C)C)C)C)C
Title of publication	Hydrogen-Substituted Osmium Silylene Complexes: Effect of Charge Localization on Catalytic Hydrosilation
Authors of publication	Paul G. Hayes; Chad Beddie; Michael B. Hall; Rory Waterman; T. Don Tilley
Journal of publication	Journal of the American Chemical Society
Year of publication	2006
Journal volume	128
Pages of publication	428 - 429
a	35.326 ± 0.003 Å
b	9.2322 ± 0.0008 Å
c	24.865 ± 0.002 Å
α	90°
β	120.737 ± 0.001°
γ	90°
Cell volume	6970.2 ± 1 Å³
Cell temperature	135 ± 2 K
Ambient diffraction temperature	135 ± 2 K
Number of distinct elements	5
Space group number	15
Hermann-Mauguin space group symbol	C 1 2/c 1
Hall space group symbol	-C 2yc
Residual factor for all reflections	0.0586
Residual factor for significantly intense reflections	0.0314
Weighted residual factors for significantly intense reflections	0.06
Weighted residual factors for all reflections included in the refinement	0.0643
Goodness-of-fit parameter for all reflections included in the refinement	0.88
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
178874 (current)	2016-03-22	cif/4/11/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/11/03.	4110374.cif
120077	2014-07-12	Adding DOIs to range 4/11 structures.	4110374.cif
59170	2012-06-04	cif/ Adding structures of 4110374 via cif-deposit CGI script.	4110374.cif