Crystallography Open Database

Information card for entry 4115708

Preview

Coordinates	4115708.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C40 H31 B F20 P2 W
Calculated formula	C41 H29 B F20 P2 W
Title of publication	High Oxidation-State (Formally d0) Tungsten Silylene Complexes via Double Si-H Bond Activation
Authors of publication	Benjamin V. Mork; T. Don Tilley
Journal of publication	Journal of the American Chemical Society
Year of publication	2001
Journal volume	123
Pages of publication	9702 - 9703
a	15.2193 ± 0.0002 Å
b	15.9706 ± 0.0002 Å
c	17.2664 ± 0.0003 Å
α	90°
β	96.322 ± 0.001°
γ	90°
Cell volume	4171.27 ± 0.11 Å³
Cell temperature	153.2 K
Ambient diffraction temperature	153.2 K
Number of distinct elements	6
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/c 1
Hall space group symbol	-P 2ybc
Residual factor for all reflections	0.0668
Residual factor for significantly intense reflections	0.0415
Weighted residual factors for all reflections	0.05
Weighted residual factors for significantly intense reflections	0.0449
Goodness-of-fit parameter for all reflections included in the refinement	1.393
Diffraction radiation wavelength	0.7107 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
176467 (current)	2016-02-16	cif/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in range 4.	4115708.cif
120077	2014-07-12	Adding DOIs to range 4/11 structures.	4115708.cif
69430	2012-12-14	cif/ Adding structures of 4115708 via cif-deposit CGI script.	4115708.cif