Crystallography Open Database

Information card for entry 4115748

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Structure parameters

Formula	C24 H33 F4 K N2 O6 Si
Calculated formula	C24 H33 F4 K N2 O6 Si
SMILES	[K+].[Si]1(F)(F)(F)(F)[N](=Nc2c1cccc2)c1ccccc1.O1CCOCCOCCOCCOCCOCC1
Title of publication	Reversible Photocontrol of the Coordination Number of Silicon in a Tetrafluorosilicate Bearing a 2-(Phenylazo)phenyl Group
Authors of publication	Naokazu Kano; Fuminori Komatsu; Takayuki Kawashima
Journal of publication	Journal of the American Chemical Society
Year of publication	2001
Journal volume	123
Pages of publication	10778 - 10779
a	9.334 ± 0.0002 Å
b	16.319 ± 0.0008 Å
c	18.148 ± 0.0008 Å
α	90°
β	90°
γ	90°
Cell volume	2764.33 ± 0.19 Å³
Cell temperature	150.1 K
Number of distinct elements	7
Space group number	19
Hermann-Mauguin space group symbol	P 21 21 21
Hall space group symbol	P 2ac 2ab
Residual factor for significantly intense reflections	0.045
Weighted residual factors for all reflections included in the refinement	0.145
Goodness-of-fit parameter for all reflections included in the refinement	0.99
Diffraction radiation wavelength	0.7107 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
301833 (current)	2025-08-20	Add cross-references to PubChem compounds in COD range 4/11/ Each referenced PubChem compound corresponds to the full crystal structure.	4115748.cif
176467	2016-02-16	cif/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in range 4.	4115748.cif
120077	2014-07-12	Adding DOIs to range 4/11 structures.	4115748.cif
69472	2012-12-18	cif/ Adding structures of 4115748 via cif-deposit CGI script.	4115748.cif