Crystallography Open Database

Information card for entry 4121855

Preview

Coordinates	4121855.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	Ge6 H186 K22 Na10 O337 W56 Zr24
Calculated formula	Ge6 K22 Na10 O298 W56 Zr24
Title of publication	Synergistic Combination of Multi-Zr(IV) Cations and Lacunary Keggin Germanotungstates Leading to a Gigantic Zr24-Cluster-Substituted Polyoxometalate.
Authors of publication	Huang, Ling; Wang, Sa-Sa; Zhao, Jun-Wei; Cheng, Lin; Yang, Guo-Yu
Journal of publication	Journal of the American Chemical Society
Year of publication	2014
Journal volume	136
Journal issue	21
Pages of publication	7637 - 7642
a	17.1764 ± 0.0004 Å
b	20.7259 ± 0.0006 Å
c	23.1192 ± 0.0005 Å
α	67.465 ± 0.002°
β	76.759 ± 0.002°
γ	73.217 ± 0.002°
Cell volume	7212.6 ± 0.3 Å³
Cell temperature	293 ± 2 K
Ambient diffraction temperature	293 ± 2 K
Number of distinct elements	7
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.0635
Residual factor for significantly intense reflections	0.0498
Weighted residual factors for significantly intense reflections	0.1222
Weighted residual factors for all reflections included in the refinement	0.1311
Goodness-of-fit parameter for all reflections included in the refinement	1.059
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
176467 (current)	2016-02-16	cif/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in range 4.	4121855.cif
115826	2014-06-05	cif/ Updating files of 4121855 Original log message: Adding full bibliography for 4121855.cif.	4121855.cif
113989	2014-05-20	cif/ Adding structures of 4121855 via cif-deposit CGI script.	4121855.cif